• Bulletin of the Korean Chemical Society
• /
• v.32 no.10
• /
• pp.3696-3701
• /
• 2011

The single-crystal structure of partially dehydrated partially $Mg^{2+}$-exchanged zeolite Y, ${\mid}Mg{30.5}Na_{14}(H_2O)_{2.5}{\mid}$ [$Si_{117}Al_{75}O_{384}$]-FAU per unit cell, ${\alpha}$ = 25.5060(1) ${\AA}$, dehydrated at 723 K and $1{\times}10^{-4}$ Pa, has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd$\bar{3}$ m at 100(1) K. The structure was refined using all intensities to the final error indices (using only the 561 reflections with $F_{\circ}$ > $4{\sigma}(F_{\circ})$) $R_1$ = 0.0377 (Based on F) and $R_2$ = 0.1032 (Based on $F^2$). About 30.5 $Mg^{2+}$ ions per unit cell are found at four different crystallographic sites. The 14 $Mg^{2+}$ ions occupy at site I at the center of double 6-ring (Mg-O = 2.231(3) ${\AA}$, O-Mg-O = $89.15(11)^{\circ}$ and $90.85(11)^{\circ}$). Four $Mg^{2+}$ ions are found at site I' in the sodalite cavity; the $Mg^{2+}$ ions are recessed 1.22 ${\AA}$ into the sodalite cavity from their 3-oxygen plane (Mg-O = 2.20(3) ${\AA}$ and O-Mg-O = $92.3(14)^{\circ}$). Site II' positions (opposite single 6-rings in the sodalite cage) are occupied by 2.5 $Mg^{2+}$ ions, each coordinated to an $H_2O$ molecule (Mg-O = 2.187(20) ${\AA}$ and O-Mg-O = $114.2(16)^{\circ}$). The 10 $Mg^{2+}$ ions are nearly three-quarters filled at site II in the supercage, being recessed 0.12 ${\AA}$ into the supercage (Mg-O = 2.123(4) A and O-Mg-O = $119.70(19)^{\circ}$). About 14 $Na^+$ ions per unit cell are found at one crystallographic site; the $Na^+$ ions are located at site II in the supercage (Na-O = 2.234(7) ${\AA}$ and O-Mg-O = $110.5(4)^{\circ}$).

• Bulletin of the Korean Chemical Society
• /
• v.28 no.1
• /
• pp.41-48
• /
• 2007

Large colorless single crystals of sodium zeolite X, stoichiometry |Na80 |[Si112Al80O384]-FAU, with diameters up to 200 μm and Si/Al = 1.41 have been synthesized from gels with the composition of 2.40SiO2 : 2.00NaAlO2 : 7.52NaOH : 454H2O : 5.00TEA. One of these, a colorless octahedron about 200 μm in cross-section has been treated with aqueous 0.1 M KNO3 for the preparation of K+-exchanged zeolite X. The crystal structure of |K80|[Si112Al80O384]-FAU per unit cell, a = 24.838(4) A, dehydrated at 673 K and 1 × 10-6 Torr, has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd at 294 K. The structure was refined using all intensities to the final error indices (using only the 707 reflections for which Fo > 4σ (Fo)) R1 = 0.075 (based on F) and R2 = 0.236 (based on F2). About 80 K+ ions per unit cell are found at an unusually large number of crystallographically distinct positions, eight. Eleven K+ ions are at the centers of double 6-rings (D6Rs, site I; K-O = 2.492(6) A and O-K-O (octahedral) = 88.45(22)o and 91.55(22)o). Site-I' position (in the sodalite cavities opposite D6Rs) is occupied by five K+ ions per unit cell; these K+ ions are recessed 1.92 A into the sodalite cavities from their 3-oxygen planes (K-O = 2.820(19) A, and O-K-O = 78.6(6)o). Twety-three K+ ions are found at three nonequivalent site II (in the supercage) with occupancies of 5, 9, and 9 ions; these K+ ions are recessed 0.43 A, 0.75 A, and 1.55 A, respectively, into the supercage from the three oxygens to which it is bound (K-O = 2.36(13) A, 2.45(13) A, and 2.710(13) A, O-K-O = 116.5(20)o, 110.1(17)o, and 90.4(6)o, respectively). The remaining sixteen, thirteen, and twelve K+ ions occupy three sites III' near triple 4-rings in the supercage (K-O = 2.64(3) A, 2.94(3) A, 2.73(5) A, 2.96(6) A, 3.06(4) A, and 3.08(3) A).

• Korean Chemical Engineering Research
• /
• v.60 no.2
• /
• pp.313-319
• /
• 2022

AlGaN/GaN based HfO₂ MOSHEMT (metal oxide semiconductor high electron transistor) with different gate recess depth was simulate to demonstrate a successful normally-off operation of the transistor. Three types of the HEMT structures including a conventional HEMT, a gate-recessed HEMT with 3 nm thick AlGaN layer, and MIS-HEMT without AlGaN layer in the gate region. The conventional HEMT showed a normally-on characteristics with a drain current of 0.35 A at V_G = 0 V and V_DS = 15 V. The recessed HEMT with 3 nm AlGaN layer exhibited a decreased drain current of 0.15 A under the same bias condition due to the decrease of electron concentration in 2DEG (2-dimensional electron gas) channel. For the last HEMT structure, distinctive normally- off behavior of the transistor was observed, and the turn-on voltage was shifted to 0 V.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.20 no.3
• /
• pp.17-24
• /
• 2016

The reacting flows of gaseous hydrogen/liquid oxygen 2D coaxial shear injector with varying recess length are numerically analyzed. The standard ${\kappa}-e$ model and laminar flamelet model are adopted for the steady turbulent combustion with the ideal and real gas equations. As the recess length increases, the recirculating region in the combustion chamber expands and the vorticity is intensified. Also, the variations of temperature, products, and pressure are strongly related to the recess length. The results show that an efficient combustor can be obtained by the introduction of the recessed injector.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2009.11a
• /
• pp.82-85
• /
• 2009

In the development of Liquid Rocket Engine(LRE) systems, it is essential to understand the spray characteristics which influence mainly the performance and the stability of combustion. The injectors for this study have a recessed Liquid-swirl/Gas-centered jet coaxial type. For the similarity with actual conditions, the experimental conditions are calculated by using the momentum ratio as a matching parameter, and the stimulants of fuel and oxidizer are gaseous nitrogen and water respectively. The spray fields were measured by means of a photographic technique. Moreover, an effect of the momentum ratio has been investigated.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.24 no.2
• /
• pp.83-93
• /
• 2020

Dynamic pressure transducer needs to be flush-mounted on hardware due to frequency response characteristics of pressure transmission system. However, it is sometimes necessary to be mounted in recessed configuration due to insufficient space for sensor installation and for protection of sensor from thermal damage. Dynamic response characteristics should be considered due to distortion of original dynamic pressure signal in the pressure transmission system. In this study, small perturbation model and 2nd order reduced model were compared with experiments and a guideline for selecting a frequency response model was suggested.

• 한국정보통신설비학회:학술대회논문집
• /
• 2006.08a
• /
• pp.193-196
• /
• 2006

In this paper, two $4{\times}4$ rectangular patch array antennas operated at 20 GHz are implemented for the satellite communication. Two $2{\times}2$ sub-arrays are designed and used for the design of $4{\times}4$ patch array. The sixteen patch antennas and microstrip feeding line are printed on the single-layered substrate. The spacing between the array elements is chosen to be $0.736{\lambda}$. The HPBW(Half Power Beam Width) of the $4{\times}4$ microstrip patch array is 17.01 degrees in the E-plane and 17.71 degrees in the H-plane with a gain of 11.6dB in the experimental results. The HPBW of the recessed $4{\times}4$ microstrip patch array is 18.66 degrees in E-plane and 17.12 degrees in the H-plane with a gain of 12.55dB in the experimental results.

• Journal of the Korea Furniture Society
• /
• v.27 no.2
• /
• pp.104-110
• /
• 2016

The aim of this study is to develop and suggest the handle for lockers according to the design process which are used for keeping of student's personal stuffs such as books, writing implements and gym uniform in elementary, middle and high school and university as well. This includes the design development for ILGUMTUR which is specialized for office furniture, but does not own the intellectual property right yet. The design concept based on the domestic locker market survey is recessed handle at low- to intermediate price and it's material should be plastic what is solid and light. The lock system should be constructed by molding process and the name plate can be exchanged every time the owner of locker changes. Contrary to the right angle of it's external appearance, the handle of the locker is designed to be softly round and the simplicity is pursued for an easy production. On the basis of this design concept the sketch has been drawn and upgraded in full by 3D-rendering. Then the mock-up has been completed by 3D printer and ILGUMTUR has obtained a patent for the locking system based on the rotation of 2 circles.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.23 no.4
• /
• pp.893-898
• /
• 1996

The occlusal disharmonies resulted from labially protruded or malpositioned teeth can damage the periodontium and induce the non-inflammatory gingival recession. For these cases, a conservative approach was performed by improving oral hygiene and correcting the axial and positional status of the gingivally recessed teeth and removing the prematurely contacted areas. In some cases, rapid remission of tooth mobility and gradual decrease of gingival recession was observed just after start of treatment. In cases of gingival recession in permanent lower incisors of the children with mixed dentition, the treatment of choice is non-surgical conservative approaches. In cases when the gingival inflammation can be controlled through reinforcing the oral hygiene, when attached gingiva have a potential to increase in width through growth (not more than 1 year after eruption or not yet arrived at adult level), and when the recession can be corrected by moving the teeth from labial cortical plate through orthodontic treatment, the conservative measures would be the first choice. On the contrary, when recession has exceeded beyond the level of CEJ, when the gingival inflammation existed with the cause of poor oral hygiene, when the attached gingiva have little potential to increase (for example, more than 8 years after eruption), and when the conservative measures yielded no benefit after 4-8 weeks of treatment, the surgical approaches should be sought.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.19 no.12
• /
• pp.2468-2478
• /
• 1994

A hybrid finite element method is presented for a characterization of scattering an radiation properties of microstrip patch and arrays residing in a cavity recessed in a ground plane. The technique combines the finite element and boundary integral methods to formulate a system for the solution of fields at the aperture and the scattering field and radar cross sections at free space. By virture of the finite element method, the proposed technique is applicable to patch antennas and arrays residing on or embeded in a layered dielectric loss/lossless substrate and is also capable of treating various feed configuration. Several numerical results are presented demonstrating the validity, efficiency and capability of the technique.