• 한국수소및신에너지학회논문집
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• 제21권5호
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• pp.425-434
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• 2010

Integrated gasification combined cycle (IGCC) is an efficient and environment-friendly power generation system which is capable of burning low-ranked coals and other renewable resources such as biofuels, petcokes and residues. In this study some process modeling on a conceptual entrained flow gasifier was conducted using the ASPEN Plus process simulator. This model is composed of three major steps; initial coal pyrolysis, combustion of volatile components, and gasification of char particles. One of the purposes of this study is to develop an effective and versatile simulation model applicable to numerous configurations of coal gasification systems. Our model does not depend on the hypothesis of chemical equilibrium as it can trace the exact reaction kinetics and incorporate the residence time calculation of solid particles in the reactors. Comparisons with previously reported models and experimental results also showed that the predictions by our model were pretty reasonable in estimating the products and the conditions of gasification processes. Verification of the accuracy of our model was mainly based upon how closely it predicts the syngas composition in the gasifier outlet. Lastly the effects of change oxygen are studied by sensitivity analysis using the developed model.

• 한국환경과학회지
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• 제17권12호
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• pp.1343-1351
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• 2008

The activated sludge obtained from wastewater coke oven plant was immobilized by entrapment with polyethylene glycol (PEG). The effects of several factors on the biodegradation of $CN^-$ from. synthetic wastewater were investigated using batch and continuous reactors. The degradation rate of $CN^-$ increased with increasing of the immobilized bead volume in the reactor. Approximately 7.65mg/L of $NH_4-N$ was produced upon the degradation of 35mg/L of $CN^-$. When high concentrations of the toxic cyanide complex were used in the testing of cyanide degradation, the free activated sludge could be inhibited more than that of the immobilized activated sludge. When the phenol concentration was higher than 400mg/L in the synthetic wastewater, approximately 98.4% of $CN^-$ was removed within 42 hours by the immobilized activated sludge. However, the cyanide was not completely degraded by the tree activated sludge. This indicates that high phenol concentrations can act as a toxic factor for the free activated sludge. A $CN^-$ concentration of less than 1mg/L was achieved by the immobilized sludge at the loading rate of 0.025kg $CN^-/m^3-d$. Moreover, it was found that the HRT should be kept for 48 hours in order to obtain stable treatment conditions.

• 한국환경보건학회지
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• 제31권2호
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• pp.160-164
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• 2005

This study was performed to evaluate the effects of washing food wastes before aerobic composting on temperature, pH and salinity, and the effects of washing after composting on salinity of sample mixtures. Weight ratios of food wastes to water in washing were 1:0(Control), 1:1(W-1), 1:2(W-2), 1:3(W-3) and 1:0(N-4), respectively. Ratios of food wastes to wood chips in reactor of Control, W-1, W-2, W-3 and N-1 were $5\;kg:0\iota,\;5\;kg:5\iota,\;5\;kg:5\iota,\;5\;kg:5\iota\;and\;5\;kg:5\iota$, respectively. Reactors were operated for 24 days with 1 hour stirring by 1 rpm and 2 hours of forced aeration per day. The increase in the ratio of water to food wastes resulted in the increase of the maximum reaction temperature and the shortening of the high temperature reaction period. The increase in the ratio of water to food wastes also resulted in faster reaching to the lowest pH and then to the steady state of pH 9.0. The final salinities of Control, N-1, W-1, W-2 and W-3 were $1.04\%,\;0.92\%,\;0.78\%,\;0.64\%\;and\;0.53\%$, respectively. The salinities of the N-l samples which were washed by the weight ratios (water:N-l) of 1:1, 2:1 and 3:1 after composting were $0.72\%,\;0.61\%\;and\;0.51\%$, respectively. Therefore, washing food wastes before aerobic composting is more efficient method than that after aerobic composting.

• 한국환경보건학회지
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• 제31권2호
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• pp.99-106
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• 2005

The removals of organic matter, nitrogen and phosphate in wastewater were investigated with Sequencing Batch Reactor (SBR). Glucose and sodium acetate were Used for organic carbon source so as to know nutrient removal efficiency in proportion to MLSS concentration. In the case of glucose, the COD removal rate was $74\%,\;41\%\;and\;66\%$ in MLSS 5000, 3000 and 1000, respectively. On equal terms, the BOD was $57\%,\;21\%\;and\;38\%$, the T-N was $24\%,\;13\%\;and\;44\%$, and the T-P was $12\%,\;21\%\;and\;33\%$. As a result, the removal rate of organic materials showed the finest remove when MLSS was 5000, but the nutrient removal rate appeared as was best when MLSS was 1000. In the case of sodium acetate, the COD removal rate was $83\%,\;81\%\;and\;86\%$ in MLSS 5000, 3000 and 1000, respectively. On equal terms, the BOD was appeared by $76\%,\;82\%\;and\;92\%$, the T-N $57\%,\;42\%\;and\;78\%$, and the T-P $48\%,\;52\%\;and\;38\%$. As a result, organic and T-N removal rates were best when MLSS was 1000. But, the T-P removal rates were best when MLSS was 3000. Glucose was shown fast removal in reaction beginning, but screened by more efficient thing though sodium acetate removes organic matter, nitrogen and phosphate. Form of floc was ideal in all reactors regardless of carbon source and MLSS concentration. And its diameter was about $200\~500{\mu}m$.

• 한국환경보건학회지
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• 제31권4호
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• pp.340-348
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• 2005

Laboratory scale experiments were conducted to compare the performance of two types of sequencing batch reactor(SBR) systems, anoxic-oxic-anoxic-oxic $((AO)_2)$ SBR and anoxic-oxic-anoxic $(A_2O)$ SBR on the biological nitrogen and phosphorus removal. Also, the profiles of DO and pH in reactors were used to monitor the biological nutrient removal in two SBRs. The break point in the pH and DO curves at the oxic period coincided with the end of nitrifying activity at about 1 h 30 min in oxic phase, and the change in pH appears to be related to nitrate concentration. The TOC removal efficiency in $A_2O$ SBR was higher than that in $(AO)_2$ SBR. The denitrification was completed at the influent period. The 2nd non-aeration and aeration periods were not necessary for the nitrogen and phosphorus removal because of the low influent TOC concentration in this study. The release and uptake of phosphorus in $AO_2$ SBR was much higher than that in $(AO)_2SBR.$ In order to uptake more phosphorus, the 1st aeration period in $A_2O$ SBR should be prolonged.

• 한국환경보건학회지
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• 제22권4호
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• pp.82-90
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• 1996

This study was performed to find the optimum mixing ratio of paper waste in composting of mixture of swine feces and newspaper. Using the experimental setting of aeration rate which was found in the experiment carried out priorly, and moisture contents reported in other literature, just the initial C:N ratios were differentiated by mixing different amount of newspaper with the same amount of swine feces. This study was carried out by operating 4 experimental cornposting reactors of bench scale for 3 weeks. The followings are the conclusions that were derived from this study. 1. During composting reaction, the C:N ratio of each cornposter was decreased. Degree of decrease was in order of run 3, run 2, run 4, and run 1 of which initial C:N ratio was 30, 25, 35, and 20 respectively. All of the final composts were found to be completed composting reaction. 2. Ash contents of each reactor increased rapidly in order of run 3, run 2, run 4, and run 1. The absolute values of quadratic effect coefficients of each second order regression function was 0.059, 0.038, 0.032, and 0.030 respectively. Ash contents evolution trend had a linear correlation with the C:N ratio trend. (r=-0.96932, p<0.05) 3. The range of highest temperatures reached during composting was 47.2-53.5$\circ$C. Those were not significantly different from one another. Thermophilic temperatures were maintained in the range of 48-108 hours. 4. Contents of heavy metal detected in the final compost were lower than those of Korean and European standards. 5. Concentration range of Nitrogen in the final compost was 1.11-2.27%, and that of phosphorus was 8.40-10.70 mg/kg. 6. The optimum C:N ratio which has been proposed without the consideration of types of bulking agents should be re-examined. Biodegradabilities of each bulking agents was thought to be important factor when determining the optimum initial C:N ratio for cornposting.

• 한국환경보건학회지
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• 제37권3호
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• pp.226-233
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• 2011

Exactly 25 years after the Chernobyl nuclear disaster, 11th of March 2011 the Fukushima nuclear accident occurred in Japan and was ranked at level 7 same to the Chernobyl. A Korean and Japanese joint civil survey was conducted around Fukushima on April 13-17. The radiation survey data clearly shows a large hotspot area between 20 km and 50 km radius north and west direction from the accident reactors, with the highest radiation recorded being 55.64 ${\mu}Sv/hr$ in the air, 99.89 ${\mu}Sv/hr$ in the surface air, and 36.16 ${\mu}Sv/hr$ in a car, respectively. 3.65 ${\mu}Sv/hr$ in the air and 6.89 ${\mu}Sv/hr$ in the surface air were detected at the playground of an elementary school in Fukushima City. Spring came with full cherry blossoms in Fukushima, but it was silent spring of radiation contamination. Interviews with Fukushima nuclear refugees reveal serious problems about Japanese nuclear safety systems, such as there was no practical evacuation drill within 1-10 km and no plan at all for 10-30 km areas. Several reforms items for Korean nuclear safety system can be suggested: minimization of accident damage, clear separation of regulatory and safety bureaus with a new and independent administrating agency, community participation and agreement regarding the safety system and levels, which is the major concern of 80% Korean. To tackle threats of nuclear disaster in neighboring nations like China, a new position entitled 'Ambassador for nuclear safety diplomacy' is highly necessary. The nuclear safety of Korea should no longer be the monopoly of those nuclear engineers and limited technocrats criticized as a 'nuclear mafia'.

• KEPCO Journal on Electric Power and Energy
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• 제1권1호
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• pp.1-8
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• 2015

When the line and switchgear of the substation system are disconnected, ferro-resonance can occur. This happens even if the capacitive reactance and inductive reactance are not equal, which are not common resonance conditions. Resonance conditions vary depending on the busbar configuration environment. Although the damping resistance method applying the existing saturable reactor to cope with ferro-resonance has been successfully applied on site, there can be loss of normal function during long-term operation. The reason is because the rise in the operating frequency of saturable reactors means the saturation number is increased. Therefore, it can no longer function as saturable reactor since the resistor having inadequate capacity is burned out. To address this problem, in this paper, an EMTP-based simulation test was performed by designing and applying a dual reactor method, which adds an extended divergence reactor to the 1st side of the VT. The test result confirms that when the divergence reactor is inserted, the voltage and current values obtained at the 1st side and 2nd side of the VT as well as current values of divergence reactor part were stabilized from the transient phenomena and return to normal values. When compared with existing measures, although this method is similar in adding having a reactor added to a system regarding ferro-resonance, it has the advantage of being able to prevent ferro-resonance in advance since the reactor is added before the system is saturated. In addition, because it does not use damping resistance, it can extend the equipment life and stabilize its operation. Therefore, there are a lot of differences in terms of its operating characteristics and achivement of goal between the conventional method and new divergence reactor method.

• 조명전기설비학회논문지
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• 제22권12호
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• pp.142-149
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• 2008

본 논문은 비열평형 플라즈마와 촉매를 이용하여 트리클로로에틸렌의 효과적인 분해방법을 제안하였다. 이를 위하여 이산화망간과 알루미나 펠렛을 플라즈마 리액터 내부에 충진한 리액터를 설계하였다. 이산화망간 충진 리백터를 이용할 경우에는 산소를 포함한 가스중의 방전에 의해 발생된 오존이 촉매 표면에서 분해되는 동안에 발생된 산소원자 라디칼에 의하여 TCE의 분해율이 향상됨을 알 수 있었다. 그리고 알루미나를 충진한 경우에는 TCE DCAC로 산화되었으며, COx 및 $Cl_2$와 같은 저분자상으로 많이 분해되지 않았다. 그러나 알루미나 충진 리액터에 의한 플라즈마 처리된 가스를 리액터 후단에 설치한 이산화망간 촉매를 통과시킴에 의하여 분해율이 매우 향상됨을 알 수 있었다. 따라서, 플라즈마 프로세스에 이산화망간을 응용함에 의하여 오존 분해에 따른 촉매 표면의 산소원자 라디칼에 의하여 TCE 및 분해 생성물(DCAC)를 효율적으로 분해하는 것이 가능하다.

• KSBB Journal
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• 제15권1호
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• pp.88-95
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• 2000

5%(w/v)의 설탕과 2.5%(w/v)의 녹말로 구성된 혼합기질용액을 1.5 mL/min으로 공급하였을 때 dextransucrase와 $\alpha$-amylase의 혼합효소를 함께 고정화한 비드를 이용한 방법이 두 효소를 띠로 고정화한 비드를 혼합한 방법보다 올리고당 수율이 충전형 반응기에서는 12%, 교반형 반응기에서는 11% 높았다. 혼합효소를 함께 고정화한 비드를 200시간 이상 사용하였을 경우 교반식 반응기에서는 파괴되었으나, 충전형 반응기에서는 안전하였다. 따라서 올리고당을 연속적으로 생산하는데는 충전형 반응기가 더 적합하였다. 충치균인 S. mutans를 새로운 구조의 올리고당이 함유된 배치에서 배양하였을 때 pH가 5이하로 떨어지지 않았다. 식중독균인 S. aureus를 새로운 구조의 올리고당이 첨가된 배치에서 배양한 결과, glucose와 설탕이 첨가된 배치보다 균 성장정도가 현저히 떨어졌다.