• Journal of Energy Engineering
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• v.7 no.1
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• pp.73-80
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• 1998

Zinc titanate sorbents were prepared and regeneration of used sorbents for high temperature desulfurization of fuel gases was studied. Zn/Ti molar ratio of prepared sorbents was 1.5 and quartz fixed-bed reactors with 1 cm and 3 cm diameters were used. Regeneration of zinc titanate sorbents at high temperature is exothermic reaction; that brings about deterioration of sorbents. Therefore, we experimented regeneration reaction of zinc titanate sorbents for the purpose of obtaining the most suitable regeneration conditions by changing experimental parameters such as reaction temperature, oxygen concentration, flow rate and steam content. $H_2S$ and $SO_2$ breakthrough curves were obtained during desulfurization-regeneration. Also, properties of the sorbents before and after regeneration were analyzed using SEM, XRD, Hg-porosimetry and BET method. From such results, we obtained the most suitable regeneration conditions including regeneration temperature of 650$^{\circ}$C, $O_2$ content of 5% and steam content of 10% in the gas stream.

• Ecology and Resilient Infrastructure
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• v.5 no.3
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• pp.174-179
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• 2018

$TiO_2$-embedded expanded polystyrene (TiEPS) balls with powdered $TiO_2$ particles embedded on the surface of EPS were developed, and the growth inhibition of Chlorella ellipsoidea, a green algae, was evaluated. The experiment was conducted using four reactors with various conditions of (A) natural sunlight, (B) natural sunlight + TiEPS balls, (C) dark, and (D) dark + TiEPS balls on the roof of the building during five days. Based on the analysis of cell number, cell morphology, concentrations of chlorophyll-a and phaeopigments, both surface reactions in heterogeneous photocatalysis and light shielding could inhibit the growth of C. ellipsoidea. The highly reactive hydroxyl radicals ($OH{\cdot}$) from TiEPS balls degraded the lipid cell membrane through the peroxidation reaction with the light shielding, eventually resulting in cell inactivation. Although dominant inhibitory effects on the growth of C. ellipsoidea were ambiguous, TiEPS balls were feasible to prevent and inhibit the excessive growth of algae in eutrophic water body.

• Journal of the korean society of oceanography
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• v.33 no.1-2
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• pp.35-40
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• 1998

In February and April 1997, three temporary interruptions of electric power production at the Uljin Nuclear Power Plant in the east coast of Korea were caused by the malfunction of the cool-ing-water supply unit. The clogging of the drum screens inside the unit caused by the surface swarm of the euphausiid Euphausia pacifica Hansen might be responsible for the malfunction. These incidents were of particular interest since such interruption of reactors' operation by krill swarms had not previously been reported. Using samples caught by the drum screens inside the cooling water-supply unit, we investigated the population structure of surface swarms. One occasion of nighttime and three occasions of daytime surface swarms were found in February and April 1997, respectively. The foreguts of more than 60% of E. pacifica in nighttime surface swarm were in full condition. This evidence suggests that E. pacifica aggregates to the surface water at night for feeding. In daytime surface swarms consisting of mature E. pacifica, however, foreguts in full condition were only found in less than 10eio of krill examined, suggesting that daytime surface swarms are closely related to breeding activity. During the study period, the growth rate of mature females was more than twice higher than that of mature males. Analyses of the sex-ratio and length-frequency data show a decrease in the portion of males with increasing size. There was a decline in the number of males of 19 mm in length. Energy loss during spermatophore transfer may result in the death of male E. pacifica, as found in male E. superba.

• Journal of Korean Society on Water Environment
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• v.18 no.4
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• pp.379-386
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• 2002

In this study, estimation model for iron compound originated from upflow, anaerobic fixed bed reactor, which treats sewage domestic wastewater, was developed. The estimation model was formulated by a mathematical expression which was based on the mass balance. Below the HRT of 60 minute, sulfide concentration combining with iron $FeS_2$ is the highest because the maximum sulfate consumption rate $V_{maxS}$ and half-saturation constant of sulfate $K_{mS}$ exert an important effect on the estimation model as temperature was increased. But increment of $FeS_2$ concentration is weakened above the HRT of 60 minutes and represent the lowest value at the HRT of 108 minutes. It implies that liquid phase distribution ratio of sulfide ${\alpha}r$ becomes lower as temperature was increased. While phosphorus concentration combining with iron $Fe_3(PO_4)_3$ is increased as HRT and temperature are increased, which is affected by phosphorus removal rate constant $k_p$. As the result of estimating the iron concentrations of corrosion by the model, the concentration of iron corrosion is higher than any other at the HRT of 108 minute and $20^{\circ}C$. The predicted values were compared with measured ones at different HRT(13.5, 27, 54, 108 min) and temperature(20, 25, $30^{\circ}C$). The experimental data could be fitted with the simulated curves. Therefore, the mathematical expression could be applicable to design full-scale wastewater treatment plants.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.6
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• pp.815-824
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• 2011

In this study, a non-thermal plasma system was employed to simultaneously remove odorous compounds and organic sludge. The system consisted of two reactors; the first one was the non-thermal plasma reactor where ozone was produced by the plasma reaction and the ozone oxidized hydrogen sulfide, the model odorous compound, and then the ozone-laden gas stream was introduced to the second reactor where wasted sludge was disintegrated and solubilized by ozone oxidation. In this study, the gas retention time (GRT) and the hydraulic retention time (HRT) were changed in the two-reactor system, and the effects of GRT and HRT on reduction efficiencies of odor and sludge were determined. As the GRT increased, the ozone concentration increased resulting in an increasing efficiency of hydrogen sulfide removal. However, the overall ozone loading rate to the second sludge reactor was the same at any GRT, which resulted in an insignificant change in sludge reduction rate. When HRTs in the sludge reactor were 1, 2, 4 hours, the sludge reduction rates were approximately 30% during the four-hour operation, while the rate increased to 70% at the HRT of 6 hours. Nevertheless, at HRTs greater than 4 hours, the solubilization efficiency was not proportionally increased with increasing specific input energy, indicating that an appropriate sludge retention time needs to be applied to achieve effective solubilization efficiencies at a minimal power consumption for the non-thermal plasma reaction.

• Journal of Environmental Health Sciences
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• v.24 no.2
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• pp.9-19
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• 1998

Laboratory experiments were carried out to investigate the performance of anaerobic sequencing batch reactor(ASBR) for digestion of a municipal sludge. Each cycle of the ASBR comprised feeding, two-or three-day reaction, one-day thickening, and withdrawal. The reactors were operated at an HRT of 10days and 5days with an equivalent organic loading rate of 0.8-1.54 gVS/l/d, 1.81-3.56 gVS/l/d at 35$\circ$C, respectively. Solids accumulation was remarkable in the ASBR during start-up period, and directly affected by settleable solids in the feed sludge. Floatation thickening occured in the ASBRs, and Solids profiles at the end of thickening step dramatically changed at solid-liquid interface. Slight difference in solids concentrations was observed within thickened sludge bed. Efficiencies through floatation thickening were comparable to that of additional thickening of the completely mixed control reactor. Average solids concentrations in the ASBRs were 2.2-2.6 times higher than that in the control throughout the total operation period. The dehydrogenase activity had a strong correlation with the solids concentration. Organics removals based on clarified effluent of the ASBRs were consistently above 86%. Remarkable increase in equivalent gas production of 27-52% was observed at the ASBRs compared with the control though the control and ASBRs showed similiar effluent quality. Thus, digestion of a municipal sludge was possible using the ASBR in spite of high concentration of solids in the sludge.

• Journal of Hydrogen and New Energy
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• v.26 no.4
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• pp.339-346
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• 2015

The synthesis of Fischer-Tropsch (FT) oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. This studied catalyst was prepared Cobalt-supported alumina and silica by the incipient wet impregnation of the nitrates of cobalt, promoter and organic solvent with supports. Cobalt catalysts were calcined at $350^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has been carried out under $450^{\circ}C$ for 24h, FT reaction of the catalyst has been carried out at GHSV of 4,000/hr under $200^{\circ}C$ and 20atm. From these experimental results, we have obtained the results as following; In case of $SiO_2$ catalysts, the activity of 12wt% $Cobalt-SiO_2$ synthesized by organic solvent was about 2 or 3 times higher than the activity of 12wt% $Cobalt-SiO_2$ catalyst synthesized without organic solvent. In particular, the activity of the $Cobalt-SiO_2$ catalyst prepared in the presence of an organic solvent P was two to three times higher than that of the $Cobalt-SiO_2$ catalyst prepared without the organic solvent. Effect of Cr and Cu metal as a promoter was found little. 200 h long-term activity test was performed with a $Co/SiO_2$ catalyst prepared in the presence of an organic solvent of Glyoxal solution.

• Journal of Hydrogen and New Energy
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• v.25 no.2
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• pp.114-121
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• 2014

The synthesis of Fischer-Tropsch oil is the catalytic hydrogenation of CO to give a range of products, which can be used for the production of high-quality diesel fuel, gasoline and linear chemicals. Our cobalt catalyst was prepared Co/alumina, Co/silica and Co/titania by the incipient wetness impregnation of the nitrates of cobalt with supports. Co-based catalysts was calcined at $400^{\circ}C$ before being loaded into the FT reactors. After the reduction of catalyst has carried out under $450^{\circ}C$, FT reaction of the catalyst has carried out at GHSV of 4,000 under $200^{\circ}C$ and 20atm. From test results, the order of increasing activity for the catalyst was Co/alumina > Co/silica > Co/titania. When the content of Co metal such as 5, 12, 20 and 30wt% was changed, an CO conversion increased as the content of Co metal increased. The activity of catalyst has obtained the best value at 12wt% Co content.

• Journal of Hydrogen and New Energy
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• v.24 no.2
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• pp.128-135
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• 2013

The nuclear fuel cycle plant is composed of various subsystems such as a fuel storage and delivery system (SDS), a tokamak exhaust processing system, a hydrogen isotope separation system, and a tritium plant analytical system. Korea is sharing in the construction of the International Thermonuclear Experimental Reactor (ITER) fuel cycle plant with the EU, Japan, and the US, and is responsible for the development and supply of the SDS. Hydrogen isotopes are the main fuel for nuclear fusion reactors. Metal hydrides offer a safe and convenient method for hydrogen isotope storage. The storage of hydrogen isotopes is carried out by absorption and desorption in a metal hydride bed. These reactions require heat removal and supply respectively. Accordingly, the rapid storage and delivery of hydrogen isotopes are enabled by a rapid cooling and heating of the metal hydride bed. In this study, we designed and manufactured a vertical-type hydrogen isotope storage bed, which is used to enhance the cooling performance. We present the experimental details of the cooling performances of the bed using various cooling parameters. We also present the modeling results to estimate the heat transport phenomena. We compared the cooling performance of the bed by testing different cooling modes, such as an isolation mode, a natural convection mode, and an outer jacket helium circulation mode. We found that helium circulation mode is the most effective which was confirmed in our model calculations. Thus we can expect a more efficient bed design by employing a forced helium circulation method for new beds.

• Journal of Electrical Engineering and Technology
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• v.10 no.3
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• pp.719-728
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• 2015

This paper presents the results of field tests on Voltage Management System (VMS) using hybrid voltage control, which utilizes coordinated controls of various reactive power resources such as generators, FACTS and switched shunt devices to regulate the pilot bus voltage in a voltage control area. It also includes the results of performance test on RTDS-based test bed in order to validate the VMS before installing it in Jeju power system. The main purpose of the system is adequately to regulate the reactive power reserve of key generators in a normal condition with coordination of discrete shunt devices such as condensers and reactors so that the reserves can avoid voltage collapse in emergency state in Jeju system. Field tests in the automatic mode of VMS operation are included in steady-states and transient states. Finally, by the successful operation of VMS in Jeju power system, the VMS is proved to effectively control system voltage profiles in steady-state condition, increase system MVAR reserves and improve system reliability for pre- and post-contingency.