• Title/Summary/Keyword: reactivity

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The development of a fuel lifecycle reactivity control strategy for a generic micro high temperature reactor

  • Seddon Atkinson;Takeshi Aoki
    • Nuclear Engineering and Technology
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    • v.56 no.3
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    • pp.785-792
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    • 2024
  • This article provides an overview of the design methodology used to develop a conceptual set of reactivity control mechanism of a micro reactor based on the U-Battery. The U-Battery is based on remote deployment and therefore it is favourable to provide a long fuel lifecycle. This is achieved by implementing a high fissile loading content, which proves challenging when considering reactivity control methods. This article follows the design methodology used to overcome these issues, with an emphasis on a new concept of a moveable moderator which utilises the size of the U-Battery as a small reduction in moderation provides a significant reduction in reactivity. The latest work on this project sees the moveable moderator investigated during a depressurised loss of forced coolant accident, where a reduction of moderator volume increases the maximum fuel temperature experienced. The overall conclusion is that the maximum fuel temperature is not significantly increased (4 K) due to the central reflector region relatively lower volumetric heat capacity compared to that of whole core. However, a small temperature increase is observed immediately after the transient due to the central reflector removal because it reaches energy equilibrium with the fuel region faster.

Analysis of Safety Regulation and Chemical Reactivity of Hypergolic Propellant (접촉점화성 추진제 안전기준 및 상호반응성 분석)

  • Eungwoo Lee;Ahntae Shin;Sangyeon Cho;Byeongmun Park
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.108-115
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    • 2023
  • Although hydrazine is an excellent liquid propellant, caution is required during storage and handling due to its high toxicity and reactivity. Safety guidelines should be established in consideration of the chemical reactivity by unintended leakage. In this study, the status of hydrazine facilities at launch site and safety standards for storing and handling were investigated and then, the reactivity between chemicals and hydrazine was analyzed. As a result of the analysis, hydrazine has reactivity with the exception of fuel oil. This paper emphasizes the imperative nature of constructing a dedicated hydrazine storage facility. Ensuring compatibility between hydrazine and the materials used in storage containers and handling equipment is crucial to prevent undesired reactions that could compromise safety. It was intended to be used as basic data to secure the range safety when handling hydrazine.

Evaluation of reactor pulse experiments

  • I. Svajger;D. Calic;A. Pungercic;A. Trkov;L. Snoj
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1165-1203
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    • 2024
  • In the paper we validate theoretical models of the pulse against experimental data from the Jozef Stefan Institute TRIGA Mark II research reactor. Data from all pulse experiments since 1991 have been collected, analysed and are publicly available. This paper summarizes the validation study, which is focused on the comparison between experimental values, theoretical predictions (Fuchs-Hansen and Nordheim-Fuchs models) and calculation using computational program Improved Pulse Model. The results show that the theoretical models predicts higher maximum power but lower total released energy, full width at half maximum and the time when the maximum power is reached is shorter, compared to Improved Pulse Model. We evaluate the uncertainties in pulse physical parameters (maximum power, total released energy and full width at half maximum) due to uncertainties in reactor physical parameters (inserted reactivity, delayed neutron fraction, prompt neutron lifetime and effective temperature reactivity coefficient of fuel). It is found that taking into account overestimated correlation of reactor physical parameters does not significantly affect the estimated uncertainties of pulse physical parameters. The relative uncertainties of pulse physical parameters decrease with increasing inserted reactivity. If all reactor physical parameters feature an uncorrelated uncertainty of 10 % the estimated total uncertainty in peak pulse power at 3 $ inserted reactivity is 59 %, where significant contributions come from uncertainties in prompt neutron lifetime and effective temperature reactivity coefficient of fuel. In addition we analyse contribution of two physical mechanisms (Doppler broadening of resonances and neutron spectrum shift) that contribute to the temperature reactivity coefficient of fuel. The Doppler effect contributes around 30 %-15 % while the rest is due to the thermal spectrum hardening for a temperature range between 300 K and 800 K.

Relationship between Bronchial Sensitivity and Bronchial Reactivity in Asthma (기관지천식 환자에서 기관지 감수성과 기관지 반응성에 관한 연구)

  • Seo, Ki-Youl;Chang, Jung-Hyun;Cheon, Seon-Hee
    • Tuberculosis and Respiratory Diseases
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    • v.45 no.2
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    • pp.341-350
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    • 1998
  • Background: Airway hyperreponsiveness is a cardinal feature of asthma. It consists of both an increased sensitivity of the airways, as indicated by a smaller concentration of a constrictor agonist needed to initiate the brochoconstrictor response and an increased reactivity, increments in response induced subsequent doses of constrictor, as manifested by slopes of the dose-response curve. The purpose of this study is to observe the relationship between bronchial sensitivity and reactivity in asthmatic subjects. Method: Inhalation dose-response curves using methacholine were plotted in 56 asthmatic subjects. They were divided into three groups(mild, moderate and severe) according to clinical severity of bronchial asthma. PC20 were determined from the dose-response curve as the provocative concentration of the agonist causing a 20% fall in FEVl. PC40 were presumed or determined from the dose response curve, using the PC20 and the one more dose after PC20. Reactivity was calculated from the dose-response curve regression line, connecting PC20 with PC40. Results: PC20 were 1.83mg/ml in mild group, 0.96mg/ml in moderate, and 0.34mg/ml in severe. PC40 were 7.l7mg/ml in mild group, 2.34mg/ml in moderate, and 0.75mg/ml in severe. Reactivity were $24.7{\pm}17.06$ in mild group, $46.1{\pm}22.l0$ in moderate, and $59.0{\pm}5.82$ in severe. There was significant negative correlation between PC20 and reactivity (r= -0.70, P<0.01). Conclusion: Accordingly, there was significant negative correlation between bronchial sensitivity and brochial reactivity in asthmatic subjects. However, in some cases, there were wide variations in terms of the reactivity among the subjects who have similar sensitivity. So both should be assessed when the bronchial response tor bronchoconstrictor agonists is measured.

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A Study on the Reactivity Effect due to Expansion of Diagrid and Pad (Diagram와 Pad의 팽창에 의한 반응도 효과에 대한 연구)

  • Young In Kim;Keun Bae Oh;Kun Jong Yoo;Mann Cho
    • Nuclear Engineering and Technology
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    • v.16 no.2
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    • pp.70-79
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    • 1984
  • With the help of the nuclear computational system for a large LMFBR (KAERI-26 group cross section library/1DX/2DB), the reactivity coefficients for the diagrid expansion and the pad expansion at the beginning of cycle of the equilibrium core of SUPER-PHENIX I are calculated and reviewed. the core is described using R-Z geometry model, and a two-dimensional multigroup diffusion theory is used. For reference cases, reactivity calculations for radial and axial uniform expansion are performed, and also calculated are reactivity variations due to changes in material density and core volume. The reactivity coefficient for the diagrid expansion is calculated to be -0.553pcm/mil. The temperature coefficient corresponding to the above value is -1.0766pcm/$^{\circ}C$ and is well in accord with the French datum of -1.09pcm/$^{\circ}C$ within 1.2% difference. With the use of 4he calculational method for the diagrid expansion effect, reactivity calculations for the pad expansion bringing about nonuniform expansion are performed, which show that the calculational method is very useful in the analysis of the pad expansion effect. The reactivity coefficients for the pad expansion are calculated to be -0.2743 pcm/mil and -0.2786pcm1mi1 for the averaged expansion model and for the integrated pancake model, respectively. Under the assumption of the free expanding core the temperature reactivity coefficients for each model are obtained to be -0.5766pcm/$^{\circ}C$ and -0.5858pcm/$^{\circ}C$, both of which agree with the French datum of -0.574pcm/$^{\circ}C$ within 2% difference.

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Clinical Impact of Bronchial Reactivity and Its Relationship with Changes of Pulmonary Function After Asthmatic Attack Induced by Methacholine (기관지 반응성의 임상적 의의 및 메타콜린으로 유도된 천식 발작시 폐기능 변화와의 관계)

  • Ryu, Yon-Ju;Choi, Young-Ju;Kwak, Jae-Jin;Lee, Ji-A;Nam, Seung-Hyun;Park, Chang-Han;Chaon, Saon-Hee
    • Tuberculosis and Respiratory Diseases
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    • v.52 no.1
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    • pp.24-36
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    • 2002
  • Background: Bronchial reactivity is known to be a component of airway hyperresponsiveness, a cardinal feature of asthma, with bronchial sensitivity, and is increments in response to induced doses of bronchoconstrictors as manifested by the steepest slope of the dose-response curve. However, there is some controversy regarding methods of measuring bronchial reactivity and clinical impact of such measurements. The purpose of this study was to evaluate the clinical significance and assess the clinical use by analyzing the relationship of the bronchial sensitivity, the clinical severity and the changes in pulmonary function with bronchial reactivity. Method: A total of 116 subjects underwent a methacholine bronchial provocation test. They were divided into 3 groups : mild intermittent, mild persistent, moderate and cough asthma. Severe patients were excluded. Methacholine PC20 was determined from the log dose-response curve and PC40 was determined by one more dose inhalation after PC20. The steepest slope of log dose-response curve, connecting PC20 with PC40, was used to calculate the bronchial reactivity. Body plethysmography and a single breath for the DLCO were done in 43 subjects before and after methacholine test. Results: The average bronchial reactivity was 38.0 in the mild intermittent group, 49.8 in the mild persistent group, 61.0 in the moderate group, and 41.1 in the cough asthma group. There was a weak negative correlation between PC20 and bronchial reactivity. A heightened bronchial reactivity tends to produce an increased clinical severity in patients with a similar bronchial sensitivity and basal spirometric pulmonary function. There were significant correlations between the bronchial reactivity and the initial pulmonary function before the methacholine test in the order of sGaw, Raw, $FEV_1$/FVC, MMFR. There were no correlations between the bronchial sensitivity and the % change in the pulmonary function parameters after the methacholine test. However, there were significant correlations between the bronchial reactivity and the PEF, $FEV_1$, DLCO. Conclusion: There was weak significant negative correlation between the bronchial reactivity and the bronchial sensitivity, and the bronchial reactivity closely reflected the severity of the asthma. Accordingly, measuring both the bronchial sensitivity and the bronchial reactivity can be of assistance in assessing of the ongoing disease severity and in monitoring the effect of therapy.

Factors Affecting Reactivity of Various Phenolic Compounds with the Folin-Ciocalteu Reagent (다양한 페놀성 물질과 Folin-Ciocalteu 시약의 반응성에 미치는 영향 요인 평가)

  • Hong, Jung-Il;Kim, Hyun-Jung;Kim, Ji-Yun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.2
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    • pp.205-213
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    • 2011
  • The Folin-Ciocalteu (F-C) reagent has been extensively used for quantifying total phenolic contents in many different types of food materials. Since several different procedures of the assay methods using the F-C reagent have been applied, we investigated changes in reactivity of various phenolic compounds with the F-C reagent under three different assay conditions and factors affecting reactivity. Among 10 standard compounds tested, compounds with high hydroxyl density (number of -OH/molecular weight) showed a largely different response according to addition sequence of the F-C reagent or $Na_2CO_3$. Preincubation in $Na_2CO_3$ significantly reduced the reactivity of the phenolic compounds bearing galloyl moiety (e.g. gallic acid, tannic acid, and epigallocatechin-3-gallate) with the F-C reagent, while monophenol compounds including ferulic acid and sinapinic acid were more stable as compared to diphenols. There was little change in response to the F-C reagent of all phenolic compounds incubated in acidic pH; their reactivity except ferulic acid was reduced significantly when incubated in neutral or alkaline pH. Changes in reactivity of gallic acid incubated in $Na_2CO_3$ or neutral/alkaline pH conditions were the most prominent. $H_2O_2$ generated from phenolic compounds did not affect the reaction with the F-C reagents. The present results suggest that reactivity of different phenolic compounds with F-C reagent was affected considerably by different procedures of the assay, and the total phenolic contents could be fluctuated according to standard compounds and assay scheme.