• Title/Summary/Keyword: reactive product

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Dyeing and Fastness Properties of Oak Veneer Dyed with Vinyl Sulfone Type Reactive Dyes (비닐술폰형 반응성 염료를 이용한 오크 무늬목의 염색성 및 견뢰도 특성)

  • Cho, Hang Sung;Shim, Euijin
    • Textile Coloration and Finishing
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    • v.34 no.4
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    • pp.234-240
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    • 2022
  • Use of processed timber can help reduce environmental damage and the economic burden of resources (important problems with use of raw timber) and can meet the needs of various fields where the sensibility of raw timber is required. Veneer wood is positioned as a high-value-added product due to its luxury and beauty, and it is used in various fields as a building-related material, such as interior decoration, furniture, flooring, building interior materials, and lumber. Dyeing is necessary to enhance the aesthetic appearance of this pattern and to expand its use. Therefore, in this study, we compared and analyzed the dye ability of oak-patterned materials with reactive dyes, and evaluated their performance as interior materials. As a result, the oak pattern was dyed with 9 kinds of reactive dyes and a comparative analysis was performed. The most suitable conditions are 50℃, 2 hours, and 0.5% o.w.f. In addition, evaluating resilience to daylight, resilience to rubbing, fire resistance, and flame retardance, yielded results suitable for use as an interior material. In this study, the dyeability of veneer dyed under various conditions using reactive dyes was compared and analyzed the performance as an interior material was evaluated.

Acrolein, A Reactive Product of Lipid Peroxidation, Induces Oxidative Modification of Cytochrome c

  • Kang, Jung Hoon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3295-3300
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    • 2013
  • Acrolein (ACR) is a well-known carbonyl toxin produced by lipid peroxidation of polyunsaturated fatty acids, which is involved in the pathogenesis of neurodegenerative disorders such as Alzheimer's disease (AD). In Alzheimer's brain, ACR was found to be elevated in hippocampus and temporal cortex where oxidative stress is high. In this study, we evaluated oxidative modification of cytochrome c occurring after incubation with ACR. When cytochrome c was incubated with ACR, protein aggregation increased in a dose-dependent manner. The formation of carbonyl compounds and the release of iron were obtained in ACR-treated cytochrome c. Reactive oxygen species scavengers and iron specific chelator inhibited the ACR-mediated cytochrome c modification and carbonyl compound formation. Our data demonstrate that oxidative damage of cytochrome c by ACR might induce disruption of cyotochrome c structure and iron mishandling as a contributing factor to the pathology of AD.

E-Catalog process of Product Line (프로덕트 라인을 적용한 전자 카달로그 작업 프로세스)

  • 박옥자;유철중;장옥배;신현철
    • Proceedings of the Korean Information Science Society Conference
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    • 2004.10b
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    • pp.430-432
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    • 2004
  • 본 논문에서는 프로덕트 라인 개념을 활용하여 전자 카달로그 운영 프로세스를 구축하고자 한다. 전자 카달로그는 reactive approach(1)방법으로 프로덕트 라인 개발에 접근하여 기본적인 핵심적이고 표준적인 프로세스만 우선적으로 정의하여 각 세부항목을 명시하고 이를 기반으로 프로세스의 기능을 확장하고자 한다 FORM 방법론에서 제안한 휘처 모델링 방법을 통해 얻어진 공통점과 차이점을 이용하여 scoping을 수행하였으며 이를 기반으로 필수 프로세스와 지원 프로세스로 분류하였다. 전자 카달로그 표준안에서 제안한 비즈니스 프로세스, 표준안 보고서, 프로세스 관리 계획 등을 기본 자료로 하여 각 애플리케이션에 적합한 product가 만들어지도록 production plan을 수립하였다.

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Reactive Extrusion of Starch-g-Polyacrylonitrile in the Preparation of Absorbent Materials

  • Yoon, Kee-Jong;Carr, M.E.;Bagley, E.B.
    • Proceedings of the Korean Fiber Society Conference
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    • 1990.06b
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    • pp.8-8
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    • 1990
  • A new method for the graft polymerization of acrylonitrile onto starch is presented. Graft polymerization of acrylonitrile onto starch and the subsequent hydrolysis in sodium hydroxide solution to prepare absorbents is well known. This process has been utilized to produce the commercial product, Super Slurper. In a typical batch process, ~5% starch in water mixture is gelatinized at $95^{\circ}C$ under stirring for 1 hour then cooled to room temperature. The graft polymerization itself is carried out for approximately 2 hours at $25~30^{\circ}C$ on the gelatinized starch by eerie ion initiation. In this study, graft polymerization of acrylonitrile onto starch via a reactive extrusion process which is a continuous, efficient process is described. Initial concentration of starch in water is 35% and the reaction temperatures are between $50~80^{\circ}C$. However, the most significant difference in the reactive extrusion process is the short time in which the graft polymerization takes place. Preliminary results on the properties of graft polymerization products obtained from the reactive extrusion process are compared to those obtained from the batch process as well as the absorbency of the hydrolyzed samples. Absorbent material has also been prepared by sequential grafting and saponification in the extruder followed by a 2 hour heat treatment of the extrudate in an air circulated oven at $100^{\circ}C$.

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Neuroprotective mechanism of corydaline in glutamate-induced neurotoxicity in HT22 cells

  • Baskar Selvaraj;Dae Won Kim;Ki-Yeon Yoo;Keunwan Park;Thi Thu Thuy Tran;Jae Wook Lee;Heesu Lee
    • International Journal of Oral Biology
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    • v.49 no.1
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    • pp.10-17
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    • 2024
  • Glutamate-mediated oxidative stress causes neuronal cell death by increasing intracellular Ca2+ uptake, reactive oxidative species (ROS) generation, mitogen-activated protein kinase (MAPK) activation, and translocation of apoptosis-inducing factor (AIF) to the nucleus. In the current study, we demonstrated that corydaline exerts potent neuroprotective effects against glutamate-induced neurotoxicity. Treatment with 5 mmol/L glutamate increased cellular Ca2+ influx, ROS generation, MAPK activation, and AIF translocation. In contrast, corydaline treatment decreased cellular Ca2+ influx and ROS generation. Western blot analysis revealed that glutamate-mediated MAPK activation was attenuated by corydaline treatment. We further demonstrated that corydaline treatment inhibited the glutamate-mediated translocation of AIF to the nucleus. We propose that corydaline is a promising lead structure for the development of safe and effective neuroprotectants.

The Longitudinal Relationships between Infant's Negative Emotionality, Mother's Reactive Parenting, and Infant's Problem-solving Ability (영아의 부정적 정서성, 어머니의 반응적 양육, 영아의 문제해결력의 종단적 관련성)

  • Jeon, Ran Yeung;Kim, Hee Hwa
    • Korean Journal of Childcare and Education
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    • v.11 no.5
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    • pp.39-54
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    • 2015
  • The purpose of this research is to examine the causal relationships between an infant's negative emotionality, the mother's reactive parenting, and the infant's problem-solving ability. This research used a Panel Study with Korean Children's 1st-3rd year data, and the subjects were 1789 infants and their mothers. To process the results, descriptive statistics, reliability verification, Pearson's product moment correlation analysis, and path analysis were conducted. The results of this research are as follows: First, the infant's negative emotionality had significant negative effects on the mother's reactive parenting. Second, the mother's reactive parenting had significant positive effects on the infant's problem-solving ability. Third, the infant's negative emotionality had indirect effects on the problem-solving ability. Through the results of this research, it could be interpreted that the path, the infant's negative emotionality, which is a personal factor, and the mother's reactive parenting, which is an environmental factor, had effects on the infant's problem solving ability. Furthermore, basic data to explore the ways of promoting the infant's problem solving ability could be introduced.

Realtime Compensation of PCC Voltage Variation by Injection of Required Reactive Power in a Grid Connected Variable Speed Wind Turbine (계통 연계형 가변속 풍력발전기의 무효전력 주입을 통한 PCC 전압 변동량 실시간 보상)

  • Im, Ji-Hoon;Song, Seung-Ho
    • The Transactions of the Korean Institute of Power Electronics
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    • v.15 no.1
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    • pp.69-74
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    • 2010
  • In a grid connected variable speed wind turbine, the PCC voltage and the wind power fluctuate as the wind velocity changed. And this voltage variation is changed due to location of PCC. This paper calculate the value of PCC voltage variation which is proportional to the product of the line impedance from the ideal generator to the PCC and the wind turbine output current. And to reduce this PCC voltage variation, this paper calculate the required reactive power analytically using the vector diagram method. Output reactive current is changed, if the reactive current is limited by inverter capacity or grid code have the margin of voltage variation. If the grid connected inverter is controlled by proposed algorithm, the PCC voltage variation is minimized though the wind turbine output change at random. To verify calculated voltage variation and required reactive power, this paper utilized Matlab and PSCAD/EMTDC simulation and real small wind turbine and power system in Sapsido, island in the Yellow Sea.

Chemical Quality Evaluation of Commercial Infant Formulas (시판 조제 분유의 화학적 품질 평가)

  • 한정은;홍윤호
    • Food Science of Animal Resources
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    • v.21 no.1
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    • pp.56-63
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    • 2001
  • In this study, three domestic and one foreign formulas for the infants up to 5 month old were examined to detect chemical changes such as pH, reactive sulfhydryl groups(RSH) content, 5-hydroxymethylfurfral(HMF) content, available lysine content, electrophoresis, and surface color caused by heat treatment for long term storage. In the SDS-polyacrylamide gel electrophoresis, A and B products showed similar pattern, while C product had a clearly distinguishable $\beta$-lacto-globulin band, but in casein, only D product showed a few strong casein band. RSH content, which indicate the extent of whey protein denaturation, ranged from 4.40 to 5.93 mmole/g protein. HMF content. which indicate the extent of Maillard reaction, ranged from 192 to 432 $\mu$mole/100g in formulas. B product showed the highest RSH and HMF content. Available lysine content ranged from 31 to 46 mg/g protein. Among them D product contain the highest available lysine content and others showed no significant difference. In conclusion, the domestic infant formulas showed higher RSH and HMF content than the foreign product and the available lysine content of the domestic products were lower than of the foreign product.

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Entrainer Enhanced Reactive Distillation for Production of Butyl Acetate: Experimental Investigation in Pilot-Scale (부틸 아세테이트 생산을 위한 외부 공비제 첨가 반응증류: 파일럿 규모 실험을 통한 연구)

  • Yang, Jeongin;Lim, Honggyu;Lim, Sungkyu;Baek, Gayoung;Han, Myungwan
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.698-705
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    • 2016
  • Butyl acetate is produced from acetic acid and butanol via an esterification reaction in reactive distillation (RD). The product, butyl acetate, has been used as an internal entrainer until now. In this case, butyl acetate and water are removed at the top of column and separated into two different phases (organic and aqueous phases) after condensation, and butyl acetate rich organic phase is refluxed into the RD. This method makes butyl acetate remain high at the reactive zone, leading to lower equilibrium conversion and product yield. We introduced an extraneous entrainer to solve the problem. The extraneous entrainer forms a new azeotrope with water. The proposed process provides lower concentration of butyl acetate in the reactive zone than conventional RD processes using an internal entrainer. We compared the yield and production rate of butyl acetate between the proposed and conventional processes through pilot-scale experiments. Experimental and simulation results showed that the proposed process was more efficient than conventional process using internal entrainer.

Upregulation of Heme Oxygenase-1 as an Adaptive Mechanism against Acrolein in RAW 264.7 Macrophages

  • Lee, Nam-Ju;Lee, Seung-Eun;Park, Cheung-Seog;Ahn, Hyun-Jong;Ahn, Kyu-Jeung;Park, Yong-Seek
    • Molecular & Cellular Toxicology
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    • v.5 no.3
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    • pp.230-236
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    • 2009
  • Acrolein, a known toxin in cigarette smoke, is the most abundant electrophilic $\alpha$, $\beta$-unsaturated aldehyde to which humans are exposed in a variety of environmental pollutants, and is also product of lipid peroxidation. Increased unsaturated aldehyde levels and reduced antioxidant status plays a major role in the pathogenesis of various diseases such as diabetes, Alzheimer's and atherosclerosis. The findings reported here show that low concentrations of acrolein induce heme oxygenase-1 (HO-1) expression in RAW 264.7 macrophages. HO-1 induction by acrolein and signal pathways was measured using reverse transcription-polymerase chain reaction, Western blot and immunofluorescence staining analyses. Inhibition of extracellular signal-regulated kinase activity significantly attenuated the induction of HO-1 protein by acrolein, while suppression of Jun N-terminal kinase and p38 activity did not affect induction of HO-1 expression. Moreover, rottlerin, an inhibitor of protein kinase $\delta$, suppressed the upregulation of HO-1 protein production, possibly involving the interaction of NF-E2-related factor 2 (Nrf2), which has a key role as a HO-1 transcription factor. Acrolein elevated the nuclear translocation of Nrf2 in nuclear extraction. The results suggest that RAW 264.7 may protect against acrolein-mediated cellular damage via the upregulation of HO-1, which is an adaptive response to oxidative stress.