• Title/Summary/Keyword: reactive product

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Nonlinear Model Based Control of Two-Product Reactive Distillation Column

  • Lee, In-Beum;Han, Myung-Wan
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.50.3-50
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    • 2001
  • Nonlinear feedback control scheme for reactive distillation column has been proposed. The proposed control scheme is derived in the framework of Nonlinear Internal Model Control. The product compositions and liquid and vapor flow rates in sections of the reactive distillation column are estimated from selected tray temperature measurements by an observer. The control scheme is applied to example reactive distillation column in which two products are produced in a single column and the reversible reaction A + B = C + D occurs. The relative volatilities are favorable for reactive distillation so that the reactants are intermediated boilers between the light product C and the heavy product D. Ideal physical properties, kinetics and ...

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Effect of Fineness Modulus of Reactive Aggregate on Alkali Silica Reaction

  • Jun, Ssang-Sun;Jin, Chi-Sub
    • International Journal of Concrete Structures and Materials
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    • v.4 no.2
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    • pp.119-125
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    • 2010
  • In this study, the effects of the fineness modulus of reactive aggregate on ASR expansion and ASR products have been investigated. The reactive aggregate used was metamorphic aggregate originated from Korea. ASR tests were conducted according to accelerated mortar bar test. The morphology and chemical composition of products formed in mortar bars, 5 years after the mortar bar test had been performed, were studied by scanning electron microscopy equipped with energy dispersive spectroscopy. Test results indicated that ASR expansion of mortar bars decrease in linear proportion to the fineness modulus of reactive aggregate. SEM images indicated that mortar bars showed reactive products formed in cement paste, within air voids and within cracks through particles except for the mortar bar with the fineness modulus of 3.25. The EDS analysis of the reactive products showed presence of silica, calcium and sodium, typical of ASR product composition.

A Study on the Decoupled Control of the Active and Reactive Power using Instantaneous Power Control Theory (순시전력 제어 이론을 이용한 유/무효전력의 독립제어에 관한 연구)

  • Kim, Eung-Sang;Kim, Ji-Won;Kim, Yeong-Cheol
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.48 no.6
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    • pp.678-682
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    • 1999
  • In this paper, we propose the algorithm which can control active power and reactive power independently in Battery Energy Storage System. The proposed algorithm is based on the instantaneous power theory that the inner product of the voltage vector and current vector represents the active power and the cross product of those represents the reactive power, and it can control active power and reactive power independently. To verify the validity of the proposed algorithm, we make model of the real power system in th KERI and simulate this algorithm. As a result of this simulation, we verified that the proposed algorithm can control active power and reactive power independently.

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Recent Advances and Trends in Reactive Polyurethane Adhesives

  • Krebs, Michael
    • Journal of Adhesion and Interface
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    • v.7 no.4
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    • pp.53-59
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    • 2006
  • The paper highlights technical advances and introduces recent innovations such as smart curing laminating adhesives for flexible packaging with low migration rates of aromatic isocyanates and amines. Latent reactive one-part systems on the basis of surface deactivated solid isocyanates open up new dimensions for heat setting adhesives and waterborne PU dispersions. The new generation of Purmelt Micro Emission adhesives contains less than 0.1% of MDI monomer, thereby drastically reducing the emission of hazardous isocyanate vapors during processing and setting a significantly improved technical standard in occupational safety. Once again, polyurethane adhesives have demonstrated their unique ability to adapt to new process, product, safety and environmental requirements.

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Modification and inactivation of Cu,Zn-superoxide dismutase by the lipid peroxidation product, acrolein

  • Kang, Jung Hoon
    • BMB Reports
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    • v.46 no.11
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    • pp.555-560
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    • 2013
  • Acrolein is the most reactive aldehydic product of lipid peroxidation and is found to be elevated in the brain when oxidative stress is high. The effects of acrolein on the structure and function of human Cu,Zn-superoxide dismutase (SOD) were examined. When Cu,Zn-SOD was incubated with acrolein, the covalent crosslinking of the protein was increased, and the loss of enzymatic activity was increased in a dose-dependent manner. Reactive oxygen species (ROS) scavengers and copper chelators inhibited the acrolein-mediated Cu,Zn-SOD modification and the formation of carbonyl compound. The present study shows that ROS may play a critical role in acrolein-induced Cu,Zn-SOD modification and inactivation. When Cu,Zn-SOD that has been exposed to acrolein was subsequently analyzed by amino acid analysis, serine, histidine, arginine, threonine and lysine residues were particularly sensitive. It is suggested that the modification and inactivation of Cu,Zn-SOD by acrolein could be produced by more oxidative cell environments.

Sensorless Control of a Permanent Magnet Synchronous Motor based on an Instantaneous Reactive Power in the Field-Weakening Region (약계자 영역에서의 순시무효전력을 이용한 PMSM의 센서리스 제어)

  • Lee Jeong-Hum;Kim Young-Seok;Choi Yang-Kwang
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.54 no.2
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    • pp.71-80
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    • 2005
  • This paper presents the position sensorless vector control of a cylindrical permanent magnet synchronous motor(PMSM) in the field weakening region. The position sensorless algorithm using an instantaneous reactive power of the PMSM is proposed. An instantaneous reactive power can be obtained from the vector product of rotor currents and back emf of the PMSM. Back emf includes the information of rotor speed. So the estimated speed can be yielded from the voltage equation of the PMSM. In other words, the estimated speed is compensated by using an instantaneous reactive power. To extend the speed range of the PMSM in the constant horsepower region, the field weakening control is applied. The proposed algorithm is not affected by mechanical motor parameters because the mechanical equation is not used. The effectiveness of the proposed algorithm is verified by the experimental results.

Design of TAME Process using a Commercial Design Software (상업용 설계 프로그램을 이용한 TAME 공정의 설계)

  • Hwang, Kyu Suk;Lee, Moon Yong;Kim, Young Han
    • Korean Chemical Engineering Research
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    • v.45 no.1
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    • pp.52-56
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    • 2007
  • Though a reactive distillation column reduces energy requirement and gives easy separation of azeotropic mixture to result in wide practical applications in field, its design is difficult. On the other hand, a commercial design software used largely in chemical process design and performance evaluation can solve the problem, but the addition of reaction into the tray is not simple. In this study the addition is implemented to make the process simulation available, and it is utilized in the design of a TAME process to find the following design guidelines. The addition of reactive trays gives more composition elevation than the composition decrease from the reduction of the trays, and the increase of non-reactive trays does not improve product quality. The elevation of reboiler heat duty lowers the product quality by the reduction of residence time in reactive tray and conversion.

Canonical Sampling Method for Initial Conditions for Reactive Flux Calculations Using Nose-Hoover Chains

  • Lee, Song-Hi;Pak, Young-Shang
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.533-538
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    • 2004
  • Canonical sampling method has been presented to generate the initial conditions for reactive flux studies of organic reactions in water. Velocity Verlet version of Nose-Hoover chain dynamics algorithm has been employed to sample the initial conditions according to canonical distribution. The unstable normal mode of a transition state has been introduced to define a dividing plane separating reactant and product regions in reaction processes. This method has been implemented and tested for the case iels-Alder reaction of methyl vinyl ketone (MVK) and cyclopentadiene (CPD) in water, providing a reliable tool for further reactive flux molecular dynamics studies in condensed media.

A Fuzzy Agent System to Control the State Transition for an Autonomous Decision Making on Taxi Driving (택시 운행 중 상태변화에 대한 자율적 의사결정을 위한 퍼지 에이전트)

  • Lim, Chun-Kyu;Kang, Byung-Wook
    • The KIPS Transactions:PartB
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    • v.12B no.4 s.100
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    • pp.413-420
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    • 2005
  • In this paper, we apply software agents, which use fuzzy logic and make autonomous decisions according to state transitions, to car driving environment. We carry out an experiment on artificial intelligent car driving in terms of real-time reactive agents. Inference techniques for constructing real-time reactive agents consider the settings with max-product inference, n-fuzzy rules, and n-associatives ($A_l,\;B_l),\;{\ldots}(A_n,\;B_n$). Then we perform defuzzification processes, extract a central value, and work out inference processes.

An innovative method for determining the diffusion coefficient of product nuclide

  • Chen, Chih-Lung;Wang, Tsing-Hai
    • Nuclear Engineering and Technology
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    • v.49 no.5
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    • pp.1019-1030
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    • 2017
  • Diffusion is a crucial mechanism that regulates the migration of radioactive nuclides. In this study, an innovative numerical method was developed to simultaneously calculate the diffusion coefficient of both parent and, afterward, series daughter nuclides in a sequentially reactive through-diffusion model. Two constructed scenarios, a serial reaction (RN_1 ${\rightarrow}$ RN_2 ${\rightarrow}$ RN_3) and a parallel reaction (RN_1 ${\rightarrow}$ RN_2A + RN_2B), were proposed and calculated for verification. First, the accuracy of the proposed three-member reaction equations was validated using several default numerical experiments. Second, by applying the validated numerical experimental concentration variation data, the as-determined diffusion coefficient of the product nuclide was observed to be identical to the default data. The results demonstrate the validity of the proposed method. The significance of the proposed numerical method will be particularly powerful in determining the diffusion coefficients of systems with extremely thin specimens, long periods of diffusion time, and parent nuclides with fast decay constants.