• Journal of Sensor Science and Technology
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• v.13 no.5
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• pp.356-362
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• 2004

In this study, we developed the measuring system based on light addressable potentiometric sensor for the quantitative analysis of penicillin that is very important element in medicine and pharmacy, clinic. It is investigated the response characteristics by enzyme reaction with penicillinase. First, the surface pre-treatment process of the $Si_{3}N_{4}$ was established. The coupling agent was made using self assembled monolayer method and it was confirmed the immobilization process by AFM. Also, as the measuring system, potentiostat, signal processing part etc. was made by Lab VIEW software, it was reduced detecting time as well as simplifying the system. Fabricated device was shown excellent pH response characteristics, 57 mV/ pH in the range of pH $2{\sim}11$. The response characteristics was 60 mV/decade in the range of $0.1{\sim}10{\;}mM$.

• Restorative Dentistry and Endodontics
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• v.9 no.1
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• pp.101-106
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• 1983

It was the purpose of this study to investigate the fracture mode of dental amalgam by observing the crack propagation, and to relate this to the microstructure of the amalgam. Caulk 20th Century Regular, Caulk Spherical, Dispersalloy, and Tytin amalgam alloys were used for this study. After each amalgam alloy and Hg measured exactly by the balance was triturated by the mechanical amalgamator (Capmaster, S.S. White), the triturated mass was inserted into the cylindrical metal mold which was 4 mm in diameter and 12 mm in height and was pressed by the Instron Universal Testing Machine at the speed of 1mm/min with 120Kg. The specimen removed from the mold was stored in the room temperature for a week. This specimen was polished with the emery papers from #100 to #200 and finally on the polishing cloth with 0.06${\mu}Al_2O_3$ powder suspended in water. The specimen was placed on the Instron testing machine in the method similar to the diametral tensile test and loaded at the crosshead speed of 0.05mm/min. The load was stopped short of fracture. The cracks on the polished surface of specimen was examined with scanning electron microscope (JSM-35) and analyzed by EPMA (Electron probe microanalyzer). The following results were obtained. 1. In low copper lathe-cut amalgam, the crack went through the voids and ${\gamma}_2$ phase, through the ${\gamma}_1$ phase around the ${\gamma}$ particles. 2. In low copper spherical amalgam, it was observed that the crack passed through the ${\gamma}_2$ and ${\gamma}_1$ phase, and through the boundary between the ${\gamma}_1$ and ${\gamma}$ phase. 3. In high copper dispersant (Dispersalloy) amalgam, the crack was found to propagate at the interface between the ${\gamma}_1$ matrix and reaction ring around the dispersant (Ag-Cu) particles, and to pass through the Ag-Sn particles. 4. In high copper single composition (Tytin) amalgam, the crack went through the ${\gamma}_1$ matrix between ${\eta}$ crystals, and through the unreacted alloy particle (core).

• Journal of the Korean Society of Safety
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• v.23 no.1
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• pp.66-71
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• 2008

A new route to phthalocyanine complexes were developed to synthesize these products by fusion in the absence of solvent. This new method of synthesis without using solvent has advantages over the conventional synthetic methods since there are no risk of explosion and formation of harmful vapor from organic solvent. Reaction of PcFe with axial ligands such as $PcFe(4-VP)_2$[Pc: Phthalocyanine, 4-VP: 4-Vinylpyridine] and $PcFe(VIM)_2$[VIM: 1-Vinylimidazole] afforded powderlike, pure dark greenish blue colored products. The resulted products are soluble in $CH_2Cl_2$ and found to be complexes of the type $PcFeL_2$. Spectral properties were studied with ATR-FTIR and UV/Vis. Thermal and electrical characterization was also performed. Phthalocyanine complexes exhibit useful properties such as UV/Vis blocking, antistatic characteristics and excellent thermal stability and we anticipate various applicability in numerous products.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.6
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• pp.473-480
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• 2013

Researches for various lunar landing technologies are in progress for the lunar exploration program planned for early 2020s in Korea. This paper shows the integrated simulation for safe lunar landing guidance/control system in powered descent phase. Generally, the lunar lander uses on/off(bang-bang) controller to control the RCS jet thrusters instead of proportional controller. In this paper, the on/off controller using phase-plane switching function, and thruster selection algorithm to control sixteen thrusters are applied. Also additional guidance commands are calculated by a proposed fuzzy logic guidance algorithm. The simulation results show that lunar lander can follow a reference trajectory which is generated by optimization method, then land on the surface safely.

• Journal of Sensor Science and Technology
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• v.27 no.5
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• pp.345-351
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• 2018

We employed an unprecedented technique to synthesize porous $WO_3@SnO_2$ nanofibers exhibiting core-shell and fiber-in-tube configurations. Firstly, 2-methylimidazole was uniformly incorporated in as-spun nanofibers containing ammonium metatungstate hydrate and the sacrificial polymer (polyacrylonitrile). Secondly, the 2-methylimidazole on the surfaces of nanofibers was complexed with tin(II) chloride ($SnCl_2$) via simple impregnation of the as-spun nanofibers in ethanol containing tin(II) chloride dihydrate ($SnCl_2{\cdot}2H_2O$). The presence of vacant p-orbitals in tin (Sn) and the nucleophilic nitrogen on the imidazole ring allowed for the reaction between $SnCl_2$ and 2-methylimidazole, forming adducts on the surfaces of the as-spun nanofibers. The calcination of these nanofibers resulted in porous $WO_3@SnO_2$ nanofibers with a higher surface area ($55.3m^2{\cdot}g^{-1}$) and a better response to 1-5 ppm of acetone than pristine $SnO_2$ NFs synthesized using a similar method. An improved response to acetone was achieved upon functionalization of the $WO_3@SnO_2$ nanofibers with catalytic palladium nanoparticles. This work demonstrates the potential application of $WO_3@SnO_2$ nanofibers as sensing layers for chemiresistive sensory devices for the detection of acetone in exhaled breath.

• Environmental Engineering Research
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• v.16 no.3
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• pp.121-129
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• 2011

The completely mixed flow and plug flow (CAP) water quality model was developed for streams with discontinuous flows, a condition that often occurs in low base flow streams with in-stream hydraulic structures, especially during dry seasons. To consider the distinct physical properties of each reach effectively, the CAP model stream network can include both plug flow (PF) segments and completely mixed flow (CMF) segments. Many existing water quality models are capable of simulating various constituents and their interactions in surface water bodies. More complicated models do not necessarily produce more accurate results because of problems in data availability and uncertainties. Due to the complicated and even random nature of environmental forcing functions, it is not possible to construct an ideal model for every situation. Therefore, at present, many governmental level water quality standards and decisions are still based on lumped constituents, such as the carbonaceous biochemical oxygen demand (CBOD), the total nitrogen (TN) or the total phosphorus (TP). In these cases, a model dedicated to predicting the target concentration based on available data may provide as equally accurate results as a general purpose model. The CAP model assumes that its water quality constituents are independent of each other and thus can be applied for any constituent in waters that follow first order reaction kinetics. The CAP model was applied to the Geum River in Korea and tested for CBOD, TN, and TP concentrations. A trial and error method was used for parameter calibration using the field data. The results agreed well with QUAL2EU model predictions.

• 한국연소학회:학술대회논문집
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• 2002.06a
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• pp.123-132
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• 2002

A numerical study was conducted to investigate the combustion phenomena of normal start and unstart processes based on ISL's RAMAC 30 experiments with different diluent amounts and fill pressures in a ram accelerator. The initial projectile launching speed was 1.8 km/s which corresponded to the superdetonative speed of the stoichiometric $H_2/O_2$ mixture diluted with 5 $CO_2$ or 4 $CO_2$. Experiments with same condition except for projectile surface material demonstrated that ignition was successful with an aluminum projectile, but no combustion was observed in case of a steel projectile. In this study, it was found that neither shock nor viscous heating was sufficient to ignite the mixture at a low speed of 1.8 km/s, as was found in the experiments using a steel projectile. However, we could succeed in igniting the mixtures by imposing a minimal amount of additional heat to the combustor section and simulate the normal start and unstart processes found in the experiments with an aluminum projectile. For the numerical simulation of supersonic combustion, multi-species Navier-Stokes equations coupled with a Baldwin-Lomax turbulence model and detailed chemistry reaction equations of $H_2/O_2/CO_2$ suitable for high-pressure gaseous combustion were considered. The governing equations were discretized by a high order accurate upwind scheme and solved in a fully coupled manner with a fully implicit, time accurate integration method. The numerical results matched almost exactly to the experimental results. As a result, it was found that the normal start and unstart processes depended on the strength of gas mixture, development of shock-induced combustion wave stabilized by the first separation bubble, and its size and location.

• Environmental Engineering Research
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• v.21 no.3
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• pp.291-296
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• 2016

Application of photocatalytic nanoparticles has been recently gaining an increased attention as air purifying material for sustainable urban development. The present work reports the photocatalytic removal of gaseous phase nitrogen oxides ($NO_x$) using $TiO_2$-coated zeolite to be applied as a filter media for the urban green infrastructure such as raingardens. The $TiO_2$-coated zeolite was synthesized by simple wet chemistry method and tested in a continuous-flow photo-reactor for its removal efficiency of $NO_x$ under different conditions of the weight percentage of $TiO_2$ coated on the zeolite, and gas retention time. The removal efficiency of $NO_x$ in general increased as the weight percentage of $TiO_2$ coated on the zeolite increased up to 15-20%. Greater than 90% of $NO_x$ was removed at a retention time of one minute using the $TiO_2$-coated zeolite ($TiO_2$ weight percentage = 20%). Overall, $TiO_2$-coated zeolite showed greater efficiency of $NO_x$ removal compared to $TiO_2$ powder probably by providing additional reaction sites from the porous structure of zeolite. It was presumed that the degradation of $NO_x$ is attributed to both the physical adsorption and photocatalytic oxidation that could simultaneously occur at the catalyst surface.

• Resources Recycling
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• v.24 no.5
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• pp.3-14
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• 2015

This study investigated that status of domestic and international furnace desulfurization and desulfurization characteristics of limestone for fluidized bed use depending on the technology for CFBC one of the CCPs. Limestone-based desulfurizing agent is one of the superior elements which are optimal at around $850-950^{\circ}C$ on high temperature desulfurization. And effectiveness of desulfurization process can be determined by the desulfurization experiment method such as diffusion reaction of the diaphragm of the absorber surface, the size of the particles, the pores of the quantity, size and structure. And, desulfurization efficiency depending on geological and crystallographic properties and calcination process of limestone needs additional research in the future.

• The Journal of Korean Academy of Orthopedic Manual Physical Therapy
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• v.8 no.2
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• pp.57-71
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• 2002

Cervical pain is a rapid increase that is owing to a flexion-extension whiplash injury, unappropriated posture, chronical repetition injury from abdominal position of head and neck, excessive repeating work, chronical deficiency of excercise. Because of that is bring about muscle unbalance, tightness of cervical extensor muscle, weakness of cervical deep flexor muscles, instability of cervical region and reduction of proprioceptive sensor. Recent the role of muscle is more emphasized for preservation of sine stabilization. And cognition of integrated muscular system, importance for the operation and relation is increased to maintain stability of the motor system and pertinent function. Therefore we are going to introduce the sling exercise and stabilization exercise method for advanced efficient of cervical and upper limb and for the muscle strengthening to importance cervical stabilization through neurological program as control the reaction of cervical stabilization. Sling exercise therapy(SET) concept consists of a system of diagnosis and treatment. The system of diagnosis involves testing the muscle's tolerance through progressive loading in open and close kinetic chains. The SET system contains elements such as relaxation, increasing the range of movement, traction, training the stabilizing musculature, sensory-motor exercises, training in open and close kinetic chains, dynamic training of the mobilizing musculature, cardiovascular exercise, group exercise, personal exercise at home Sensory-motor training is an essential element of the SET concept. The emphasis is on closed kinetic chain exercise on an unstable surface, there by achieving optimum stimulation of the sensory-motor apparatus.