• Transactions of the Korean Society of Automotive Engineers
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• v.6 no.6
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• pp.218-225
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• 1998

FTIR spectroscopy, useful technology for simultaneous and continuous measurement of the various components of the automotive exhaust gas, is utilized to investigate catalytic reaction charactristics of methane and a few unregulated exhaust emissions of NGV. Major findings are (1) catalytic reaction characteristics of methane measured in unsteady states of varying temperature are similar to those measured in steady states, (2) about 24 % of NO was oxidized to $NO_2$ as soon as they encounter catalysts, (3) study of formaldehyde suffers from difficulties in measurement due to the proximity in wavenumber of formaldehyde and methane, and requires an analyzer of higher resolution and accuracy than used in this study.

• Analytical Science and Technology
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• v.19 no.3
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• pp.203-210
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• 2006

The determination of trace selenium in milk powder has been studied by octopole reaction cell(ORC)-ICP-MS. The interferences by polyatomic ions and other concomitant molecular species could be removed remarkably by using $H_2$ as reaction gas in ORC. Compared to the normal mode (no cell gas), the $H_2$ cell gas mode improved the accuracy and precision. The quantitative result was average 102.7% and it was slightly higher than certified standard value of milk powder and the RSD was 7.6%.

• Journal of the Korean Institute of Gas
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• v.21 no.3
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• pp.1-8
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• 2017

The purpose of this study is to suggest the rupture disk design(size) and application at the two phase(gas-liquid) flow by runaway reaction at batch reactor. The definition of runaway reaction is abnormally exothermic reaction by the uncontrolled cooling water or deviated operating condition. As a result, the temperature of reactor is rapidly increasing. The causes of runaway reaction are either self-heating reaction or sleeper reaction. General methods of rupture disk size or safety valve are not suitable in the runaway reaction, because of temperature and pressure increasing rapidly in the reactor and the phases of relieving fluid is 2-phase flow. This study case of the reactor incident, the depressurization system such as safety valve and vent installed, however, the system did not relieved the pressure of reactor suitably. The orifice size of the safety valve were designed too small because the size had not been considered the phenomena and character of reaction. The batch reactor design should be considered by referring to the possibility of runaway reaction proposed in this study and the size of rupture disk design method considering 2-phase flow.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.91.1-91.1
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• 2010

The Reforming system is an effective method to generate hydrogen which uses for fuel cell system. The purpose of this study is to present characteristics of an autothermal reformer at various operating conditions and to investigate ideal conditions for reforming efficiency. Dominant chemical reactions are Full Combustion, Steam Reforming reaction, Water-Gas Shift reaction and Direct Steam Reforming reaction. Operating parameters of the autothermal reformer are inlet temperature, Oxygen to Carbon Ratio, Steam to Carbon Ratio and Gas Hourly Space Velocity. Autothermal reformer is filled with catalysis of a packbed-bed type. Using numerical approach, we have investigated on various reaction conditions.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.09a
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• pp.103-106
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• 2001

A remediation technology consisting of biodegradation and a modified Fenton reaction was developed to degrade mixtures of polycyclic aromatic hydrocarbons (PAHs) at a former manufactured gas plant (MGP) site. The original Fenton reaction (i.e., $H_2O$$_2$ + Fe$^{2+}$) was modified to be biocompatible by using ferric ions and chelating agents such as catechol and gallic acid. The modified reaction was effective in degrading PAHs at near neutral pH and thus was compatible with biodegradation. By the combined treatment of the modified Fenton reaction and biodegradation, more than 98% of 2- or 3-ring hydrocarbons and between 70 and 85% of 4- or 5-ring compounds were degraded in the MGP soil, while maintaining its pH about 6.6.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.156.2-156.2
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• 2011

본 연구에서는 일단 수성가스전이반응 (Single stage water gas shift reaction)을 위해 높은 활성을 가진 백금 담지 촉매를 함침법 (Incipient wetness impregnation method)으로 제조하여 높은 공간 속도 (Gas hourly space velocity) $45,515h^{-1}$에서 담체에 따른 촉매 활성을 평가하였다. 담체는 $CeO_2$, $ZrO_2$, MgO, MgO-$Al_2O_3$ (MgO = 30 wt%) 그리고 $Al_2O_3$를 사용하였으며 백금의 담지량은 1 wt%로 고정하였다. BET, XRD, TPR, CO-chemisorption 분석을 통하여 담체의 구조적 특성이 촉매 활성에 미치는 영향에 대하여 조사하였다.

• Environmental Engineering Research
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• v.10 no.3
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• pp.122-130
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• 2005

Gasification of carbonaceous wastes such as shredded tire, waste lubricating oil, plastics, and powdered coal initiates a single-stage reforming reactor(reformer) Without catalyst and a syngas burner. Syngas is combusted with $O_2$ gas in the syngas burner to produce $H_2O\;{and}\;CO_2$ gas with exothermic heat. Reaction products are introduced into the reforming reactor, reaction heat from syngas burner elevates the temperature of reactor above $1,200^{\circ}C$, and hydrogen gas fraction reaches 65% of the product gas output. Reactants and heat necessary for the reaction are provided through the syngas burner only. Neither $O_2$ gas nor steam is injected into the reforming reactor. Multiple syngas burners may be connected to the reforming reactor in order to increase the syngas output, and the product syngas is recycled into syngas burner.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.4
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• pp.327-333
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• 2023

The water gas shift reaction was carried out using the commercial catalyst pellet and the simulated gases expected to occur from waste plastic gasification. In the water gas shift reaction, the high temperature shift reaction and the low temperature shift reaction were continuously performed with CO:H₂O ratio of 1:2, 1:2.5, and 1:3, and the CO conversion and H₂ increase rate were evaluated. The H₂ increase rate increased in order to CO:H₂O ratio of 1:3 > CO:H₂O ratio of 1:2.5 > CO:H₂O ratio of 1:2. The CO conversion showed a high value of more than 97% at each CO:H₂O ratio. The water gas shift reaction at a CO:H₂O ratio of 1:3 showed the highest H2 increase rate and CO conversion.

• Journal of the Ergonomics Society of Korea
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• v.31 no.3
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• pp.463-467
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• 2012

This study aims to empirically investigate population stereotype of burner-control linkage of four-stove gas range for Koreans. Background: The previous studies' results for gas range stereotypes were different depending upon methods adopted, i.e., whether using questionnaires, computer simulation or physical models. It is known that the physical model experiment should not be methodologically replaced by the computer simulation or paper-and-pencil tests. Stereotype of gas range for Koreans was surveyed based on questionnaires, but has not been dealt with by using physical models. Method: An experiment was conducted to investigate stereotype of four-burner gas range, in which 32 subjects participated and a real gas range available in the market was bought and used. Four types of burner-control linkage were used as independent variable, and reaction time as dependent variable. Results: ANOVA revealed that four types of burner-control linkage and subjects' gender were not significant on reaction time. Duncan's multiple range test showed that reaction times for type III was significantly lower than those for the other three types of burner-control linkage(${\alpha}$=0.05). Conclusion: It is concluded based on the results of this study that stereotype of gas range for Koreans is type III. This is in agreement with results of existing studies using questionnaire survey, while different from those based on physical models. Application: The results of this study would be useful as an ergonomic guideline when designing gas ranges or similar equipments for minimizing operation errors.

• Aerospace Engineering and Technology
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• v.8 no.2
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• pp.122-126
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• 2009

KSLV(Korea Space Launch Vehicle)-I is designed as a launch vehicle to enter a 100 kg-class satellite to the LEO(Low-Earth Orbit). Attitude angles of the upper-stage, including roll, pitch and yaw are controlled by cold gas thruster system using nitrogen gas. To verify the flow rate of the gas charging system and to prepare a nitrogen gas charging scenario, the development of a gas charging simulator for RCS(Reaction Control System) is required. This paper describes the orifice design, development, and test of the gas charging simulator for RCS of KSLV-I.