• Title/Summary/Keyword: reaction degree

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Evaluation of Groundwater Quality in Crystalline Bedrock Site for Disposal of Radioactive Waste (방사성폐기물 처분을 위한 결정질 기반암의 지하수 수질 평가)

  • Lee, Jeong-Hwan;Jung, Haeryong;Cheong, Jae-Yeol;Park, Joo-Wan;Yun, Si-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.4
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    • pp.275-286
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    • 2014
  • This study evaluated the evolution stage and origin of chemical components of 12 boreholes at crystalline bedrock using multivariate statistical and groundwater quality analyses. Groundwater types are mostly belonged to Na(Ca)-$HCO_3$ and Ca-$HCO_3$ types, indicating that directly reaction of cation exchange ($Ca^{2+}{\rightarrow}Na^+$) prevailed. The degree of groundwater evolution is included the range from low to intermediate stage based on field and laboratory analytical conditions. As a result of multivariate statistical analysis, a typical indicator of groundwater contamination, $NO_3$-, has the positive correlation with $Na^+$ and $Cl^-$. The origin of sea spary ($Cl^-$) has the positive correlation with $Na^+$, $SO{_4}^{2-}$, $Mg^{2+}$, and $K^+$, while not correlation with $Ca^{2+}$, $Fe^{2+}$, $HCO_3{^-}$, $F^-$, and $SiO_2$. The concentration of $Cl^-$ and $NO_3{^-}$ belongs to general quality of groundwater and not exceeds over the Korean standard for drinking water. And the negative values of saturation index of minerals are calculated with chemical components in groundwater. Therefore, most of chemical components of groundwater in the study area are originated from natural process between rock and groundwater, whereas some of components are derived from sea spary and anthropogenic sources related to agricultural activities.

A Comparative Analysis of Comments Before and After the Controversy Over the 'Back Advertisng' of Influencers : Focused on LDA and Word2vec (인플루언서의 '뒷광고' 논란 전,후에 대한 댓글 비교 분석:LDA와 Word2vec을 중심으로)

  • Cha, Young-Ran
    • The Journal of the Korea Contents Association
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    • v.20 no.10
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    • pp.119-133
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    • 2020
  • Recently, as famous YouTubers produce and broadcast videos that receive sponsorship and advertising such as indirect advertising (PPL), a so-called 'back advertising' controversy continues, and not only famous YouTubers but also entertainers are caught up in the issue. It is causing confusion among the public in Korea. This study attempts to find out the public's reaction before and after the controversy of 'back advertising' by YouTubers through comment analysis. Specifically, among text analysis using R programs, we intend to analyze the issue through various methods such as word cloud, qgraph analysis, LDA, and word2vec analysis, a deep learning technique. The target of the analysis was to analyze the channels of three YouTubers who belonged to the controversy of the 'back advertising' YouTuber and uploaded the 'Apology video'. The 5 most recent videos of Muk-bang YouTuber Moon Bok-hee, who has a similar content disposition to SussTV's Han Hye-yeon stylist, which was controversial, and Yang Pang, a YouTuber who showed various contents (August 09, 2020) Criterion and her first 5 videos uploaded were reviewed. As a result of the study, most of the comments that showed positive reactions before the controversy, but after the controversy, it was found that negative reactions accounted for most of the comments. Therefore, this study examines the degree of change of the public about influencers through comments after the controversy over 'back advertising' through various analysis using R program. This research also devises various measures to prevent the occurrence of back advertising of influencers in the future.

Study on the Physical Properties of Alkoxysilane-based Stone Consolidants with Different Hydrolysis (알콕시 실란계 석조문화재 강화제의 가수 분해도에 따른 특성 연구)

  • Park, Soung-Jin;Won, Jong-Ok;Kim, Jeong-Jin;Do, Jin-Young;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.27 no.2
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    • pp.201-209
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    • 2011
  • While consolidants based on tetraethoxysilane (TEOS) have been widely used for the consolidation of decaying stone heritages, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force. We have prepared new TEOS-based consolidants containing flexible (3-glycidoxypropyl) trimethoxysilane (GPTMS) in order to reduce capillary force development during gel drying. In this study, we have prepared TEOS/GPTMS-based consolidants containing ETEOS in order to improve the surface hydrophobisity. The physical properties of the TEOS/GPTMS/ETEOS solution with different hydrolysis were compared with those of the commercial products Wacker OH$^{(R)}$. The contact angle of the surface increased with the addition of the ETEOS, which is higher than that of Wacker OH$^{(R)}$. The sol-gel mechanism was manipulated by the degree of hydrolysis as well as the amount of ETEOS. The properties and the applicability of the developed consolidants for the decayed Korean granites are also investigated.

Molecular Structural Properties of Chindo Black Rice Starch (진도산 검정쌀 전분의 분자구조적 특성)

  • Park, Jong-Hoon;Oh, Keum-Soon;Kang, Kil-Jin;Kim, Kwan
    • Applied Biological Chemistry
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    • v.43 no.4
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    • pp.241-246
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    • 2000
  • In order to investigate structural properties of Chindo black rice(grown in Chindo, Chonnam) starch and its amylopectin, Chindo black rice was investigated in comparison to Shinsun waxy rice. The maximum absorbance wave and intrinsic viscosity of Chindo black rice starch and Shinsun waxy rice starch were 523 nm, 521 nm and 183 ml/g, 178 ml/g, respectively. ${\beta}-amylolysis$ limit(%) of Chindo black rice and Shinsun waxy rice starch were 62.8% and 60.3%, respectively. Chindo black rice was determined to be a waxy rice due to the results of iodine reaction and elution profile on Sephroce CL-2B. The chain of amylopectins in Chindo black rice distributed fraction 1$(F_1)$ of above degree of polymerization$({\overline{DP}})$ 55, fraction 2$(F_2)$ of ${\overline{DP}} $40{\sim}50$ and fraction 3$(F_3)$ of ${\overline{DP}} $15{\sim}20$, and the ratio of $F_3$ to $F_2$ for Chindo black rice was higher than that for Shinsun waxy rice. The super long chain of amylopectin in Chindo black rice was consisted much more than that of Shinsun waxy rice. ${\beta}-limit$ dextrins in Chindo black rice amylopectin distributed $F_1$ of above ${\overline{DP}} 55, $F_2$ of ${\overline{DP}} $30{\sim}45$ and $F_3$ of ${\overline{DP}} $10{\sim}20$. Little difference was shown between elution patterns of the pullulanase treated ${\beta}-limit$ dextrins of Chindo black rice amylopectin and Shinsun waxy rice amylopectin. These results suggest that Chindo black rice starch was similar to Shinsun waxy rice starch.

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Toxicological and Electrophysiological Activities of Pyrethroids between Larvae of Diamondback Moth, plutella xylostella and Beet Armyworm, Spodoptera exigua (배추좀나방과 파밤나방의 pyrethroids약제에 대한 감수성 및 전기적 신경 반응 비교)

  • Ham, Sun-Hee;Ahn, Hee-Geun;Yang, Jeong-Oh;Yoon, Chang-Mann;Kim, Gil-Hah
    • The Korean Journal of Pesticide Science
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    • v.13 no.3
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    • pp.197-202
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    • 2009
  • Based on the insecticidal efficacy by insecticide treatment methods, neurophysiological responses were compared with the larvae of diamondback moth (DBM) and beet armyworm (BAW) using pyrethroids working on nervous system. By body spray method, all pyrethroids were showed lower insecticidal activity below 50% on the larvae of DBM and BAW. By leaf dipping method, DBM larvae were showed the insecticidal activity as 100% at 50 ppm deltamethrin, 80.0% at fenvalervate and 63.3% at permethrin. However, BAW larvae were showed lower insecticidal activity as similar as control in all concentration. In order to examine electrophysiological response on nervous system on DBM and BAW larvae when treated three insecticides, we investigated the voltage and reaction degree. The voltage of DBM were responded as high as $10^{-7}M$ in deltamethrin, $10^{-5}M$ in fenvalerate and $10^{-3}M$ in permethrin. However, those of BAW were showed dull responses with small variation of voltage to all three insecticides.

Effects of Chemical Surface Modification of Carbon Black on Vulcanization and Mechanical Properties of Styrene-Butadiene Rubber Compound (SBR 컴파운드의 가황 및 기계적 성질에 미치는 카본블랙 표면의 화학적 개질의 영향)

  • Rhee, John-M.;Kim, Wan-Doo;Kaang, Shin-Young;Chang, Young-Wook;Park, Soo-Jin;Nah, Chong-Woon
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.44-51
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    • 2001
  • To see the effect of chemical surface modification, the carbon black surfaces were treated with three types of chemicals (KOH, $H_3PO_4$, and benzene). Vulcanization and mechanical properties of a styrene-butadiene rubber (SBR) were investigated depending on the chemical treatments. The surface free energy increased considerably with the treatments by both the acid (HCB) and base (KCB), but only a slight increase was observed for benzene treatment(BCB). The BCB showed the highest level of the London dispersive component. The vulcanization reaction was found to be faster in the order of KCB-SBR> BCB-SBR> VCB-SBR(virgin) > HCB-SBR. The difference in minimum and maximum torque of rheocurve, representing the degree of crosslinking, was found to be higher for the BCB-SBR compared to those of VCB-SBR, KCB-SBR, and HCB-SBR. The BCB-SBR and KCB-SBR showed the improved tensile and dynamic mechanical properties. A linear relationship was found to exist between the London dispersive component of surface free energy and mechanical properties.

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Prevalence of dog erythrocyte antigen 1, determined via immunochromatography, in domestic dogs in Korea (면역 크로마토그래피법을 이용한 국내 반려견의 Dog erythrocyte antigen 1 분포도 조사 연구)

  • Kim, Eunju;Choe, Changyong;Yoo, Jae Gyu;Oh, Sang-Ik;Jung, Younghun;Cho, Ara;Kim, Suhee;Do, Yoon Jung
    • Korean Journal of Veterinary Research
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    • v.58 no.2
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    • pp.81-85
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    • 2018
  • Blood group determination in dogs is an important factor in transfusion medicine to minimize immediate or delayed adverse reactions after red blood cells transfusion in small animal clinics. Dog erythrocyte antigen (DEA) 1 is the most important blood type due to its high degree of antigenicity causing acute transfusion adverse reactions. The aim of this study was to investigate the prevalence of DEA 1 in various dog breeds in Korea. As a result of testing 592 blood samples from more than 35 dog breeds, DEA 1 blood typing for each breed showed that 57.8% of Malteses, 63.3% of Poodles, 76.2% of Mastiff-like dogs, 72.5% of Pomeranians, 47.7% of Shih Tzus, 70.3% of mixed breeds, 60.0% of Yorkshire Terriers, and 71.4% of Beagles were DEA 1-positive. Miniature Schnauzers and Jindo breeds had a significantly high prevalence (100%) of DEA 1-positive dogs compared to that in other small breed dogs. This is the first report of immunochromatography-detected DEA 1 prevalence in various domestic dog breeds. Although additional studies need clarifying the potential blood transfusion risks in domestic breed dogs with DEA 1, the results of this study may be useful when selecting a blood donor.

EXPRESSION OF TGF-α AND TGF-β (구강암 발생 과정에서 TGF-α 및 TGF-β 발현에 관한 연구)

  • Yang, Hee-Chang;Lee, Dong-Keun;Kim, Eun-Cheol
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.19 no.4
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    • pp.414-434
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    • 1997
  • Though many genetic and epigenetic alterations have been identified in hamster oral carcinogenesis model, there is no information about the possible role of transforming growth factor related with oral cancer. The purpose of this paper was to find the expression patterns of transforming growth factor alpha and beta during the stages of complete oral carcinogenesis model in hamster. 0.5% 9, 10-dimethyl-1, 2-benzanthracene(DMBA) in mineral oil was topically applied to the buccal pouch of 75 hamster three times a week during the experimental periods. The experimental animals were subdivided into two groups of control and experiment. Only the mineral oil was applied to the control group. 0.5% DMBA in mineral oil was applied to the experimental groups of 6, 8, 10, 12, 14, 16, 18 and 20 weeks. The expression of the $TGF-{\alpha}$ and $TGF-{\beta}$ protein were evaluated by the distribution and intensity of positive cells during the carcinogenesis using the immunohistochemical study. The following results were obtained ; 1. The buccal pouch epithelium of hamster was histologically changed to the dysplasia at 6, 8, 10 weeks, carcinoma in situ at 12 weeks, and squamous cell carcinoma at 14 weeks. 2. The expression of the $TGF-{\alpha}$ was restricted to the parabasal and basal layers of the normal and dysplastic mucosa, but those positive cells were extended to the spinous layers of the epithelium in the carcinoma. 3. The degree of $TGF-{\alpha}$ expression was markedly decreased in the carcinoma at 16, 18, 20. The strong positive staining in the center of cancer islands and weak positive staining in periphery of tumor were seen at the stage of squamous cell carcinoma. 4. The positive index of the $TGF-{\alpha}$ had a tendency to increase with DMBA- applied time. There was a statistically significant difference between 12, 18, 20 experimental group and control group (p<0.05). 5. The expression of the $TGF-{\beta}$ was shown at the cytoplasm of all control and experimental groups, and the parabasal and basal layers of the normal and dyslastic mucosa, but it was shown at the basal layers of the epithelium in the carcinoma. 6. $TGF-{\beta}$ was expressed diffusely at 16, 18, 20 experimental group. The strong positive staining in the center of cancer islands and positive staining in periphery of tumor were seen at the stage of squamous cell carcinoma. From the above findings, the expression of $TGF-{\alpha}$ and ${\beta}$ in oral carcinogenesis model seems to have two formal stages, the first being an overexpression step as reaction to uncontrolled growth and the second being one in which external protein accumulate in the surrounding stroma and intracytoplasm. Overexpression of $TGF-{\alpha}$ and ${\beta}$ may have important cooperative roles for the promotion of cancer and factor of prognosis.

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Studies on the Preparation of Pheasant Meat Extracts by Protease (효소에 의한 꿩고기 가수분해물의 제조)

  • Jeong, Jae-Hong;Kim, Ki-Jun;Lee, Gyu-Hee;Lee, Seuk-Keun;Oh, Man-Jin
    • Korean Journal of Agricultural Science
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    • v.25 no.1
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    • pp.107-117
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    • 1998
  • Ths studies was carried out to investigate the processing possibility of pheasant meat extracts treated with proteases. The crude protein, aminonitrogen, degree of hydrolysis, yield and amino acid composition of pheasant meat extracts when it was treated with proteases at various temperature and reaction time were analyzed. The crude protein contents of pheasant meat extracts processed in $130^{\circ}C$ were more than when it was done in $100^{\circ}C$, but the contents of aminonitrogen were not quite different between two processing temperature. The content of crude protein and aminonitrogen when pheasant meat was hydrolyzed with protease NP and prozyme A. The yields of pheasant meat extracts, when pheasant meat were treated at $100^{\circ}C$ and $130^{\circ}C$, were from 2.24 to 7.10% and from 5.51 to 10.45%, respectively. And the yield of extraction depended on extraction temperature, kinds of enzyme, amount of enzyme, extraction time. The content of aminonitrogen in pheasant meat extracts treated with enzyme was much higher than any other treatments. And it depended on amount of enzyme, extraction time and temperature. The amount of the amino acids in pheasant meat extracts treated by protease NP were eminently higher than by heat at $100^{\circ}C$ or $130^{\circ}C$.

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A Fundamental Experiment on Preventing Frost Damage at Early Age of Mortar in Low Temperature using Reduction Slag (환원슬래그를 사용한 모르타르의 저온에서의 초기동해 방지에 관한 기초적 실험)

  • Min, Tae-Beom;Mun, Young-Bum;Kim, Hyeong-Cheol;Choi, Hyun-Kuk;Kim, Jae-Young;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.1
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    • pp.1-7
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    • 2016
  • In this research, it used cement powder and reduction slag, which generates high hydration heat in hydration reaction without heat cure below $-5^{\circ}C$ degree. Purpose of final research is preventing freezing and thawing by making the compressive strength 5MPa in 3days below zero temperature due to own heat of concrete. and it is the result of physical characteristic and thermal property evaluation of reduction slag. Because reduction slag generates high hydration heat, compressive strength development is excellent. By generating highly hydration heat by $C_{12}A_7$ and $C_3A$ in reduction slag, compressive strength is developed in low temperature. In case of displacing only reduction slag without $SO_3$, it is indicated that quick-setting occurs by shortage of $SO_3$. For preventing quick-setting, gypsum is used essentially. According to this research result, in case of using reduction slag and gypsum as a ternary system, compressive strength developed 5MPa in 3 days below zero temperature. It is identified to prevent early frost damage of concrete below zero temperature.