• Title/Summary/Keyword: reaction concept

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The Uptake of Solvent in Polymeric Thin Membranes By a Relaxation-Sorption Coupled Mechanism

  • Song, Kyu-Min;Hong, Won-Hi
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.10a
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    • pp.43-44
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    • 1995
  • The diffusion behavior of liquid into polymer has been described by Fick's law, but the departure from Fickian diffusion is frequently found. In this study, 'noble' expressions for the rates of relaxation and sorption are introduced to eliminate these limitations. The ralaxation-sorption coupled mechanism model are based on the possibility of contacting liquid molecule and the active site which has the numerical concept of free volume. The concept has an analogy of reaction rate expressed by the possibility of collision with molecules and used in adsorption and reactive extraction etc. The new model simulated by Rungc-Kutta method for initial-value problem and Fickian diffusion is caompared with experimental data. The results show that the ralaxation-sorption coupled mechanism is able to account well for Fickian and non-Fickian sorption behavior including sigmoid and two-stage. In addition, this model has a chance of expansion to multi-component sorption with ease.

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Development of a scale to Measure the Self Concept of Cesarean Section Mothers. (제왕절개술 산모의 자아개념 측정 도구 개발)

  • 이미라;조정호
    • Journal of Korean Academy of Nursing
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    • v.20 no.2
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    • pp.131-141
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    • 1990
  • Recently, the rate of cesarean section in Korea has been increasing. The results of several previous studies in foreign countries on the emotional responses of cesarean section mothers showed that they might experience difficulties in the mother- infant interaction due to fatigue, lack of early mother - infant interaction, disappointments, anger, feelings of loss of control, and other factors. Human behavior is said to be determined by one's self concept, and self concept is influenced by both internal and external environmental factors. A scale to measure the self concept of cesarean section mothers was needed in order to identify those who might have difficulties in the mother- infant interactions in future. The purposes of this study were to develop a measuring scale, and to test its reliability and validity. The process of this study was as follows. A structured interview was done with 50 cesarean section and vaginal delivery mothers to find their state of emotional reaction after giving birth to their babies. Based on the results of the interviews, a 50 items Likert scale was developed. The self concept of 268 cesarean section and vaginal delivery mothers who were hospitalized at six hospital in seoul were measured, during the period between Feb. 1 and April 30. Reviewing the discriminating power of each item by means of crosstabulation, ten items were selected for the final scale. The reliability and validity of this ten item scale were tested by Cronbach's alpha and t-test, using spss pc+package. The results of this study and recommendation are as follows. 1. The ten selected items were as follows. I feel pains in my breast. (-) I have a good appetite now. (+) I feel pains in my flank. (-) I feel fine now. (+) My body seems to have returned to its prepregnant state. (+) Thinking of the delivery process, I feel sorry. (-) I want to hold my baby in my arms. (+) I want to keep my own life, even if I became a mother. (-) I want to delegate the care of the baby to my mother / mother in law. (-) I think baby is my alter ego. (+) 2. The reliability of this scale was tested by Cronbach's alpha, and the coefficient of this scale was .8066. 3. The construct validity of this scale was tested by means of known group methods. The value of self concept for cesarean section mother was significantly lower than for vaginal delivery mothers(t=-5.51, df=266, p=0.007). 4. The criterion validity of this scale was tested indirectly. Though this scale could discriminate the differences in the self concept between cesarean section and vaginal delivery mothers, the five items on the personal self concept scale didn's show any differences between cesarean section and vaginal delivery mothers. Therefore, the study indicates that those who shows lower values in the personal self concept measurement, that is, lower than 12.03 points, could be regaled as “risk mothers” 5. Further studies using this scale to clarify the influencing factors on negative self concept are strongly recommended.

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A Study on the Detailed Diesel Surrogate Chemical Mechanism for Analysis of HCCI Engine (HCCI 엔진 해석을 위한 Diesel Surrogate 반응 기구에 관한 연구)

  • Lee, Won-Jun;Lee, Seung-Ro;Lee, Chang-Eon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.4
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    • pp.64-71
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    • 2011
  • Homogeneous charge compression ignition (HCCI) was the best concept able to provide low NOx and PM in diesel engine emissions. This new alternative combustion process was mainly controlled by chemical kinetics in comparison with the conventional combustion in internal combustion engine. In this paper, detailed kinetic reaction mechanisms of diesel surrogate was investigated to understand the diesel HCCI engine combustion. It was tested two existing mechanisms and two new mechanisms for the comparison of experimental result. The best mechanism for diesel surrogate was suggested through this comparison.

Decoupling Method Between Digital Signals on FPCB and Mobile Handset Antenna

  • Kim, Joon-Chul;Kim, Hyeong-Dong
    • ETRI Journal
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    • v.33 no.1
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    • pp.121-124
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    • 2011
  • Digital harmonics, which may reduce the radio frequency sensitivity of a system, can be coupled with an antenna in a mobile handset. This letter presents a decoupling method for increasing the isolation between digital harmonics on a flexible printed circuit board (FPCB) and an antenna in terms of the ground mode current and the concept of reaction. We model the signal and ground lines in an FPCB as a loop circuit exciting a ground mode current and demonstrate a simple but efficient decoupling method for reducing the excited ground mode current.

Experimental Study of Decomposition Characteristics of Catalyst for Hydrazine Monopropellant Thruster (하이드라진 단일 액체추력기용 촉매의 분해거동 특성 연구)

  • Kim, Jung-Hun;Lee, Jae-Won;Kim, In-Tae;Yu, Myoung-Jong;Lee, Kyun-Ho;Kim, Su-Kyum
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.151-154
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    • 2007
  • The purpose of this study is to identify the basic concept of thruster design through the visualization firing test on a hydrazine thruster. We designed the visual catalyst bed on the basis of the 1lbf hydrazine thruster for a low earth orbit satellite and observed visually the internal catalyst bed reaction.

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A New Topology of Solutions of Chemical Equations

  • Risteski, Ice B.
    • Journal of the Korean Chemical Society
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    • v.57 no.2
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    • pp.176-203
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    • 2013
  • In this work is induced a new topology of solutions of chemical equations by virtue of point-set topology in an abstract stoichiometrical space. Subgenerators of this topology are the coefficients of chemical reaction. Complex chemical reactions, as those of direct reduction of hematite with a carbon, often exhibit distinct properties which can be interpreted as higher level mathematical structures. Here we used a mathematical model that exploits the stoichiometric structure, which can be seen as a topology too, to derive an algebraic picture of chemical equations. This abstract expression suggests exploring the chemical meaning of topological concept. Topological models at different levels of realism can be used to generate a large number of reaction modifications, with a particular aim to determine their general properties. The more abstract the theory is, the stronger the cognitive power is.

Conceptual design of a copper-bonded steam generator for SFR and the development of its thermal-hydraulic analyzing code

  • Im, Sunghyuk;Jung, Yohan;Hong, Jonggan;Choi, Sun Rock
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.2262-2275
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    • 2022
  • The Korea Atomic Energy Research Institute (KAERI) studied the sodium-water reaction (SWR) minimized steam generator for the safety of the sodium-cooled fast reactor (SFR), and selected the copper bonded steam generator (CBSG) as the optimal concept. This paper introduces the conceptual design of the CBSG and the development of the CBSG sizing analyzer (CBSGSA). The CBSG consists of multiple heat transfer modules with a crossflow heat transfer configuration where sodium flows horizontally and water flows vertically. The heat transfer modules are stacked along a vertical direction to achieve the targeted large heat transfer capacity. The CBSGSA code was developed for the thermal-hydraulic analysis of the CBSG in a multi-pass crossflow heat transfer configuration. Finally, we conducted a preliminary sizing and rating analysis of the CBSG for the trans-uranium (TRU) core system using the CBSGSA code proposed by KAERI.

First Year Undergraduate Students' Difficulties with Ball-and-stick Molecular Models

  • Chue, Shien;Kim, Chwee;Tan, Daniel
    • Journal of The Korean Association For Science Education
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    • v.27 no.6
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    • pp.477-487
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    • 2007
  • Previous studies show that students have difficulties in understanding and using molecular visualization tools. This study focuses on the ways in which first year chemistry undergraduates use ball-and-stick molecular models to explain the concept of addition reaction and the difficulties that they face using the models. Video recordings of interviews with undergraduates manipulating ball-and-stick models to solve problems related to reaction mechanisms are analysed to determine if they are able to elucidate their understanding with use of models. The results showed that students have difficulties with viewing the ball-and-stick models from the proper perspective and understanding the relationship between the various structures that they have created using the models. They also find the use of ball-and-stick models tedious and prefer drawing molecular structures on paper to explain their ideas. Implications for the teaching using ball-and-stick molecular models are discussed.

Use of Hydrazine for Pitting Corrosion Inhibition of Copper Sprinkler Tubes: Reaction of Hydrazine with Corrosion By-Products

  • Suh, Sang Hee;Kim, Sohee;Suh, Youngjoon
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.247-256
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    • 2017
  • The feasibility of using hydrazine for inhibiting pitting corrosion in copper sprinkler tubes was investigated by examining microscopical and structural evolution of corrosion by-products with SEM, EDS, and XRD. Hydrazine removed dissolved oxygen and reduced CuO and $Cu_2O$ as well. The stable phase was changed from CuO to $Cu_2O$ or Cu depending on hydrazine concentration. Hydrazine concentration of 500 ppm could convert all CuO corrosion by-products to $Cu_2O$. In a tightly sealed acryl tube filled with aqueous solution of 500 ppm hydrazine, octahedral $Cu_2O$ particles were formed while plate-like structures with high concentration of Cu, O, N and C were formed near a corrosion pit. The inside structure of a corrosion pit was not altered by hydrazine aqueous solution. Uniform corrosion of copper was almost completely stopped in aqueous solution of 500 ppm hydrazine. Corrosion potential of a copper plate was linearly dependent on log (hydrazine concentration). The concept of stopping pitting corrosion reaction by suppressing oxygen reduction reaction could be verified by applying this method to a reasonable number of real sprinkler systems before full-scale application.

Direct kinematic method for exactly constructing influence lines of forces of statically indeterminate structures

  • Yang, Dixiong;Chen, Guohai;Du, Zongliang
    • Structural Engineering and Mechanics
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    • v.54 no.4
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    • pp.793-807
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    • 2015
  • Constructing the influence lines of forces of statically indeterminate structures is a traditional issue in structural engineering and mechanics. However, the existing kinematic method for establishing these force influence lines is an indirect or mixed approach by combining the force method with the theorem of reciprocal displacements, which is yet inconsistent with the kinematic method for statically determinate structure. This paper proposes the direct kinematic method in conjunction with the load-displacement differential relation for exactly constructing influence lines of reaction and internal forces of indeterminate structures. Firstly, through applying the principle of virtual displacement, the formula for influence lines of reaction and internal forces of indeterminate structure via direct kinematic method is derived based on the released structure. Then, a computational approach with a clear concept and unified procedure as well as wide applicability based on the load-displacement differential relation of beam is suggested to achieve conveniently the closed-form expression of force influence lines, and exactly draw them. Finally, three representative examples for constructing force influence lines of statically indeterminate beams and frame illustrate the superiority of the proposed method.