• Title/Summary/Keyword: reaction characteristics

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Investigation on Desorption Reaction and Heating Value of Used Activated Carbons Collected from VOC Adsorption Towers (휘발성 유기화합물 흡착탑 폐활성탄의 탈착반응 및 열량특성 연구)

  • Yoon, Sung-Min;Kim, Joo-Yeon;Park, Kun-Yik;Yoon, Soo-Kyung;Kil, In-Sub;Park, Hui-Jae;Rhee, Young-Woo
    • Clean Technology
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    • v.16 no.1
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    • pp.33-38
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    • 2010
  • The characteristics of desorption reaction and the heating values of used activated carbons collected from the companies of Shiwha/Banwal industrial complex were investigated. The desorption characteristics of used activated carbons were analyzed based on the data obtained from a thermogravimetric analyzer. The activation energies and reaction orders for desorption reaction of used activated carbons were calculated by employing Freeman-Carroll method. Heating values of volatile organic compounds(VOC) desorbed from used activated carbons were estimated based on the data obtained from a total hydrocarbon analyzer. It was found that the reaction orders of desorption of used activated carbons were 0.1~0.8, their desorption activation energies, 6.9~26.4 kJ/mol, and VOC heating values, 0.4~10.7 kcal/kg.

Estimation of reaction forces at the seabed anchor of the submerged floating tunnel using structural pattern recognition

  • Seongi Min;Kiwon Jeong;Yunwoo Lee;Donghwi Jung;Seungjun Kim
    • Computers and Concrete
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    • v.31 no.5
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    • pp.405-417
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    • 2023
  • The submerged floating tunnel (SFT) is tethered by mooring lines anchored to the seabed, therefore, the structural integrity of the anchor should be sensitively managed. Despite their importance, reaction forces cannot be simply measured by attaching sensors or load cells because of the structural and environmental characteristics of the submerged structure. Therefore, we propose an effective method for estimating the reaction forces at the seabed anchor of a submerged floating tunnel using a structural pattern model. First, a structural pattern model is established to use the correlation between tunnel motion and anchor reactions via a deep learning algorithm. Once the pattern model is established, it is directly used to estimate the reaction forces by inputting the tunnel motion data, which can be directly measured inside the tunnel. Because the sequential characteristics of responses in the time domain should be considered, the long short-term memory (LSTM) algorithm is mainly used to recognize structural behavioral patterns. Using hydrodynamics-based simulations, big data on the structural behavior of the SFT under various waves were generated, and the prepared datasets were used to validate the proposed method. The simulation-based validation results clearly show that the proposed method can precisely estimate time-series reactions using only acceleration data. In addition to real-time structural health monitoring, the proposed method can be useful for forensics when an unexpected accident or failure is related to the seabed anchors of the SFT.

The Psychological Reaction of Landscape Design Elements on the District Unit Plan(DUP) (지구단위계획상의 경관계획요소에 대한 심리적 반응)

  • 정태일;오덕성
    • Journal of the Korean Institute of Landscape Architecture
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    • v.32 no.3
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    • pp.76-90
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    • 2004
  • The purpose of this study is to extract landscape design elements regulation of the District Unit Plan(DUP) in new town areas, and to find out characteristics in terms of urban design elements in comparison with the psychological and physical aspects. For this purpose, we reviewed urban design elements and design elements in terms of the landscape by DUP and analyzed the activation of landscape on the selected case-area by interviewing experts such as planners, public officials, and professors in the department of urban planning and landscape, as well as the university students. The analysis framework for the case-study consists of 4 components: the section of region, street, building, open space, etc. The new development areas in Daejeon Metropolitan City was chosen as the case study area, because they have been developed by DUP regulations. As a result of this study, we can extract characteristics of landscape. The results indicate that `skyline design',`view corridor design',`landscape design',`street furniture design' and `building design(form, height, color, and elevation)' are the key planning and design factors influencing differences in the landscape preference. This research identifies that there are no detailed planning and design guidelines adopted within the four case study areas in Daejeon for regulating the characteristics of skyline, planting and street furniture while detailed guidelines established for density, building height and site layout. Considering their significant correlation with the level of landscape preference, this study suggests that detailed planning and design guidelines for the characteristics of skyline, rooftop and streetscape should be established in future DUP.

Study on Kinetics and Syngas Production of Sewage Sludge Gasification (하수슬러지 가스화의 kinetics 및 합성가스 생산 연구)

  • Roh, Seon Ah
    • Resources Recycling
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    • v.24 no.6
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    • pp.3-8
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    • 2015
  • Gasification characteristics and gas produced from a sewage sludge char were analyzed by using a thermobalance reactor, which is used for a reaction kinetic analysis by measuring weight change of materials at a desired temperature. Gasification reaction rate increased with increasing temperature and steam partial pressure due to the promotion of gasification reaction. Three models of gas-solid reaction were applied to the reaction kinetics analysis and modified volumetric reaction model was an appropriated model for the steam gasification of the sewage sludge char. Apparent activation energy and pre-exponential factors were evaluated as 155.5 kJ/mol and $14,087s^{-1}atm^{-1}$, respectively. The order of reaction on steam partial pressure was 0.68. Gas analysis was performed at $900^{\circ}C$ and hydrogen concentration was highest in the gas concentrations, which increased with increasing the steam partial pressure. Hydrogen concentration increased the most and hydrogen concentration in the produced gas was 2-4 times higher than that of carbon monoxide due to the gasification and water gas shift reaction.

A Study on Characteristics of NOx and Ozone by Plasma Reaction (Plasma반응에 의한 NOx와 Ozone의 특성에 관한 연구)

  • Choi Jae Wook;Yamaguma Mizuki;Choi Jae Jin
    • Journal of the Korean Institute of Gas
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    • v.4 no.2 s.10
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    • pp.1-6
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    • 2000
  • In this experiment, we made the plasma reactor which adhere needle electrode in order to treat safely an NOx which was included in the gas. Also we experimently investigated characteristics of equipment and inspected efficiency. As a reaction gas, by using mixture gas of $NO/N_2$ and $N_2/O_2$, we setted up initial NO concentration and gas flow rate was set at 2 ${\iota}$/min. As a reaction characteristics of NOx, when discharge input power was high, NO concentration decreased and when the oxygen concentration increased, the NO decomposition was easy and decomposition energy efficiency was high. Also in case that NO concentration increased, NO decomposition energy efficiency was high but decomposition rate was low. The characteristics of ozone, when discharge input power was high, ozone increased and when $NO/N_2$ concentration increased, the ozone decreased.

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The Reaction Characteristics of NOx/N2O and NH3 in Crematory Facility SCR Process with Load Variation (부하변동이 큰 화장시설 SCR 공정에서 NOx/N2O 및 NH3 동시 저감 특성 연구)

  • Park, Poong Mo;Lee, Ha Young;Yeo, Sang-Gu;Yoon, Jae-Rang;Dong, Jong In
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.6
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    • pp.605-615
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    • 2017
  • Efficient simultaneous reduction conditions for $NO_x$ and $NH_3$-slip was investigated in SCR (Selective Catalytic Reduction) process with load variation by applying dual catalysts (SCR catalyst, $NH_3$ decomposition catalyst) system. $N_2O$ formation characteristics were analyzed to look into possible undesirable reaction pathways. In the experiments of catalyst characteristics, various operational variables were tested for the combined catalytic system, such as $NH_3/NO_x$ ratio, temperature, oxygen concentration and $H_2O$. The reaction characteristics of $NO_x$, $NH_3$ and $N_2O$ were analyzed and optimal conditions could be evaluated for the combustion facility with varied load. In terms of $NO_x/NH_3$ simultaneous reduction and $N_2O$ formation suppression, optimal condition was considered NSR 1.2 and temperature $300^{\circ}C$. At this operational condition, $NO_x$ conversion was 98%, $NH_3$ reduction efficiency was 95%, generated $N_2O$ concentration 9.5 ppm with inlet $NO_x$ concentration of 100 ppm. In $NH_3-SCR$ process with $NH_3$ decomposition catalyst, $NO_x$ and $NH_3$ can be considered to be reduced simultaneously at limited conditions. The results of this study may be utilized as basic data at facilities requiring simultaneous $NO_x$ and $NH_3$ reduction for facilities with load variation.