• Title/Summary/Keyword: reaction characteristics

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A Study on Combustion Characteristics of Methane-air Homogeneous Mixture in a Constant Volume combustion Chamber by FIRE Code (FIRE Code를 사용한 정적연소기의 메탄-공기 균질 혼합기 연소특성 연구)

  • Lee, Suk-Young;Huh, Kang-Yul
    • Journal of the Korean Society of Combustion
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    • v.11 no.2
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    • pp.28-36
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    • 2006
  • A constant volume combustion chamber was used to investigate the combustion characteristics. of homogeneous charge of methane-air mixture under various initial pressure, equivalence ratio and ignition times. The constant volume combustion chamber(CVCC) mostly has been studied by the experiments of visualization until now. So it is needed the numerical analysis of fluid and combustion characteristics in chamber by the more detail simulation. In this paper, the numerical analysis is tried to approach basically the homogeneous charge combustion phenomena under the various conditions, and the combustion phenomena in chamber is numerically analyzed by the commercial FIRE code. As a results, the combustion phenomena which were mean temperature, OH radical and reaction rate in chamber were investigated and it showed that the smallest flame growth occurs for the lean state and the increase of initial charged pressure condition due to the reduced OH radical.

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Dynamic Behavior Analysis of a Crankshaft-Bearing System in Variable Speed Reciprocating Compressor (가변속 왕복동형 압축기 크랭크축-베어링계의 동적 거동 해석)

  • 김태종
    • Tribology and Lubricants
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    • v.17 no.6
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    • pp.426-434
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    • 2001
  • The hermetic reciprocating compressor driven by the BLDC motor rotating with variable speeds, is modelled and analyzed for dynamic characteristics. The governing equations of piston, connecting rod and crank-shaft of the reciprocating compression mechanism and characteristics of driving torque of the motor are obtained. Dynamic behavior of the crankshaft supported on 2 journal bearings is analyzed considering compression load and eccentric unbalance for the 4 rotating speeds of crankshaft. And. reaction forces generated from oil film in the journal bearings are analyzed under transient condition using Reynolds' equation. To take into account the dynamic characteristics depending on the variable rotating speeds, comparison on the dynamic behavior of crank-shaft is made for the 4 operating modes of the compressor. Results show that the magnitude of crankshaft locioperating on the lower rotating speeds is more larger than the higher ones due to reduction of inertia force of the reciprocating piston.

A Study of Light-off Performance of Catalytic Converter with the Effect of Flow Characteristics (유동특성을 고려한 촉매변환기의 활성화(Light-off) 성능에 관한 연구)

  • 정수진;김우승
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.5
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    • pp.107-120
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    • 1999
  • Catalytic converters are the most fascinating and complicated chemical reactors. They are most often operated in the transient state with respect to composition, flow rate, temperature, etc. The mathermatical model developed in this work accounts for simultaneous heat and mass transfer, chemical reaction, and multi dimensional flow characteristics to analyze the light-off performance of monolithic catalytic converter with comparable mass flow rate. To validate the mathematical model, comparison between experimental and numerical results has been performed. The numerical results show a good agreement with experimental data. It is forund that inflow rate shows major effect on the characteristics of termal response of catalytic converter.

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An Experimental Study on the Combustion Characteristics with Hydrogen Enrichment in a Dump Combustor (수소 혼합에 따른 덤프 연소기내의 연소 특성에 관한 실험적 연구)

  • Kim, Dae-Hee;Hong, Jung-Goo;Shin, Hyun-Dong
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2977-2983
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    • 2008
  • The combustion characteristics of a partially premixed flame in a dump combustor were studied to determine the effects of hydrogen enrichment in propane. Bluff-body was used for flame stabilization. Fuel mixtures containing a hydrogen mole fraction ranging from 0.1 to 0.5 were burnt at ambient pressure within a quartz chamber. Tests were carried out keeping the total reactant flow rate by adjusting the fuel and air flow rates. The fluctuations of pressure were measured by piezoelectric pressure sensor. The instantaneous flame structure and OH chemiluminescence images were described by High-speed Intensified Charged Coupled Device (HICCD) camera and Intensified Charged Coupled Device (ICCD) camera. The present results show that hydrogen enrichment in fuel changed the location of primary reaction zone from inner recirculation zone to turbulent shear layer and pressure signal. The reason is that chemical aspects take precedence over flow aspects in the hydrogen-enriched flame.

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Combustion Characteristics According to the Equivalence Ratio of Hydrocarbon Fuel/Air Premixture Excited by Ultrasonic Standing Wave (정상초음파가 인가된 탄화수소계 연료/공기 혼합물의 당량비에 따른 연소특성)

  • Kim, Min Cheol;Bae, Seong Hun;Hong, Joon Yeol;Kim, Jeong Soo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.628-631
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    • 2017
  • An experimental study of the combustion characteristics according to the equivalence ratio of hydrocarbon fuel/air premixture excited by ultrasonic standing wave are presented. The image of the propagating flame was acquired using a high-speed camera, and the combustion characteristics of each fuel were closely observed through image processing. it was conformed that ultrasonic standing wave has been found to stimulate the combustion reaction in the stoichiometric ratio.

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Electro-optical properties of photo-aligned VA-LCD by irradiation of unpolarized UV light. (비편광 UV조사에 의한 광배향 VA-LCD의 전기광학특성)

  • 박두석;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.545-548
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    • 1999
  • The electro-optical characteristics of photo-aligned vertical-alignment (VA)-liquid crystal display (LCD) with non-polarized ultraviolet (UV) light irradiation of 45\`on homeotropic polyimide (Pl) surface were investigated. LC alignment on photo-aligned VA-LCD is attributed to photo-depolymerized reaction of the polymer with non-polarized UV light irradiation on PI surface. We had good voltage-transmittance (V-T) characteristics of photo-aligned VA-LCD. The response time of photo-aligned VA-LCD was slower than that of the rubbing-aligned VA-LCD. Finally, we suggest that the slow response time of photo-aligned VA-LCD depends on the LC domain.

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Numerical Investigation on the Thermal and Flow Characteristics of Combustion Heater for Commercial Vehicle (차량용 연소식 난방기의 열 및 유동특성에 대한 수치연구)

  • Hwang, Chang-Hwan;Baek, Seung-Wook
    • Journal of the Korean Society of Combustion
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    • v.16 no.2
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    • pp.40-46
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    • 2011
  • The diesel pre-heater has being used in cabin heating and coolant heating of engine to reduce the engine warm up time for commercial vehicle. The pre-heaters are classified as diesel spray combustor and it forms diffusion flame. By using swirler, a recirculation flow of hot product gases is established near the fuel nozzle and it helps the maintaining of diffusion flame. The design difference of swirler can affect on reaction characteristics and temperature distribution inside pre-heater. The purpose of this study is the investigation of the effect of swirler configuration on combustion characteristics. To solve spray combustion problem, the Euler-Lagrange approach discrete model is used to track droplet trajectory and evaporation history. The PDF equilibrium model is used for chemical reaction model. These models are implemented into the FLUENT code.

Liquid crystal alignment by photo-dimerization reaction of PCEMA photo polymer (PCEMA 광폴리머의 광중합 작용을 이용한 액정배향)

  • 황정연;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.541-544
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    • 1999
  • We synthesised a novel photo-alignment material of PCEMA (poly(cinnamolyethyl methacrylate)) on photo-dimerization reaction. Next we investigated the electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-liquid crystal display (LCD) with linearly polarized ultraviolet (UV) light irradiation on PCEHA surface. The excellent voltage-transmittance characteristics of photo-aligned TN-LCD on PCEMA surface were obtained. The threshold voltage of photo-aligned TN-LCD decreases with increasing the UV light irradiation time on PCEMA surface. Also, the response time of photo-aligned TN-LCD on PCEMA surface is almost the same as rubbing-aligned TN-LCD.

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Characteristics of Temperature in Reformer Tube and Chemical Reaction for Steam Methane Ratio (수증기-메탄 혼합비에 따른 개질 튜브 내 온도 및 화학반응 특성)

  • Han, Jun Hee;Kim, Ji Yoon;Lee, Seong Hyuk
    • Journal of the Korean Institute of Gas
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    • v.20 no.5
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    • pp.27-33
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    • 2016
  • The aim of numerical study is the investigation of the solid and fluid temperatures in a reformer tube and chemical reaction characteristics of different steam-carbon ratio. We considered conjugate heat transfer contain radiation, convection and conductive heat transfers. This is because steam reforming reaction of hydrocarbon occurred high temperature conditions up to 800 K- 1000 K by using commercial computational fluid dynamics (CFD) code (Fluent ver. 13.0). For numerical simulation, the Reynolds-Averaged Navier-Stokes, momentum and energy equation were employed. In addition, inside of reformer tube is assumed as the porous medium to consider the Nichrome-based catalyst. To analysis characteristics of tube temperature in chemical reaction, we changed steam-methane ratio(SCR) from 1 to 6. As increased SCR, the higher tube temperature and methane conversion were observed. It was obtained that the highest hydrogen production held in SCR of 5.

Characteristics of Hydrogen Iodide Decomposition using Alumina-Supported Ni Based Catalyst (Ni 기반 촉매를 이용한 HI 분해 반응 특성)

  • KIM, JI HYE;PARK, CHU SIK;KIM, CHANG HEE;KANG, KYOUNG SOO;JEONG, SEONG UK;CHO, WON CHUL;KIM, YOUNG HO;BAE, KI KWANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.6
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    • pp.507-515
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    • 2015
  • HI decomposition reaction requires a catalyst for the efficient production of hydrogen as a key reaction for hydrogen production in sulfur-iodine thermochemical water-splitting (SI) cycle. As a catalyst used in the reaction, the performance of platinum catalyst is excellent. While, the platinum catalyst is not economical. Therefore, studies of a nickel catalyst that could replace platinum have been carried out. In this study, the characteristics of the catalytic HI decomposition on the amount of loaded nickel (Ni = 0.1, 0.5, 1, 3, 5, 10 wt%) were investigated. As the supported Ni amount increased up to 3 wt%, HI decomposition was found to increase in linear proportion. However, the conversion of $Ni/Al_2O_3$ catalyst loaded above 3 wt% was not linear. It was thought that the different HI decomposition characteristics was caused in the size and metal dispersion of Ni particles of catalyst. The physical property of catalyst before and after HI decomposition reaction was characterized by BET, chemisorption, XRD and SEM analysis.