• Carbon letters
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• 제28권
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• pp.38-46
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• 2018

Modified pitch A (MPA) and modified pitch B (MPB) were prepared by oxidative polymerization and thermal polycondensation reaction with refined pitch as the raw material, respectively. The toluene soluble components (TS-1 and TS-2) were obtained by solvent extraction from MPA and MPB, separately. The Flynn-Wall-Ozawa method and Kissinger-Akahira-Sunose method were used to calculate the pyrolysis activation energy of TS. The Satava-Sestak method was used to investigate the pyrolysis kinetic parameters of TS. Moreover, the optical microstructure of the thermal conversion products (TS-1-P and TS-2-P) by calcination shows that TS-1-P has more contents of mosaic structure and lower contents of fine fiber structure than TS-2-P. The research result obtained by a combination of X-ray diffraction and the curve-fitting method revealed that the ratios of ordered carbon crystallite (Ig) in TS-1-P and TS-2-P were 0.3793 and 0.4417, respectively. The distributions of carbon crystallite on TS-1-P and TS-2-P were calculated by Raman spectrum and curve-fitting analysis. They show that the thermal conversion product of TS-2 has a better graphite crystallite structure than TS-1.

• 한국경영과학회:학술대회논문집
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• 한국경영과학회 2006년도 추계학술대회
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• pp.273-276
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• 2006

At an integrated steel mill, various raw material such as coal and iron ore are unloaded from a large ship. The unloaded raw material is then transported to storage yards through a complex belt conveyer network. We propose an optimization model for scheduling the unloading operations under the limitations of available berths, unloading equipments and transportation capacity of the belt conveyer network. We show that the problem is NP-Hard and propose a heuristic approach to the problem.

• 한국주조공학회지
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• 제15권5호
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• pp.477-482
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• 1995

A computer simulation model of various smelting process for melting waste sand was developed by using energy and material balance concept. This model can predict the coal, flux and oxygen consumption and the volume and temperature of off-gas. The major critical variables for smelting process can be explained by using the analysis of energy and material balance. The major conclusions were as follows; 1. The most important variables for smelting process were high post-combustion ratio, high heat transfer efficiency and refractory protection technology. 2. For saving energy in this smelting process, selection of raw materials i.e coal, flux are very important, espacially using of low volatile coal is very profitable. 3. The treatment cost of waste sand is high and environmental restriction is severe, in this reason we must be concerned in the treatment of waste sand by smelting process.

• 한국세라믹학회지
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• 제33권2호
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• pp.135-142
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• 1996

Fly Ashes which are produced from coal-fired powder plants and classified as general waste can be used as raw materials for bricks and tiles because of their compositional similarity with clays. There was a limit of substituting fly ash for clay because plasticity decreased with increasing fly ash additions. Accordingly this study tried to suggest a feastibility of enhancing the substitution ratio by controlling the interfacial properties of fly ash. The slip with 1:1 volume ratio showed that best dispersive characteristics under the condition of pH 2 Filter pressed cakes made of pH 2 slips also showed better plastickity than those of untreated ones. of pH 2 Filter pressed cakes made of pH 2 also shwoed better plasticity than those of untreated ones.

• 한국세라믹학회지
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• 제43권5호
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• pp.315-319
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• 2006

There have been some studies on the use of coal waste as a raw material for clay bricks due to the lack of naturally producing minerals. It can help resolving the problems of pollution, forest conservation and flood control by utilizing coal waste. However, high content of carbon materials usually leads to the black core in clay bricks after firing process, and diminishes the mechanical and aesthetical properties of clay brick. In this study, the effect of firing process is investigated for the removal of black core in clay bricks with carbon content. The removal kinetics of black core are also compared and investigated with the firing schedule and black core removal.

• 청정기술
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• 제19권4호
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• pp.464-468
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• 2013

본 연구에서는 석탄 종류, 저등급석탄으로부터 첨가제의 종류, 입도분포 및 건조 방법에 따른 석탄-물 혼합연료(coal water fuel, CWF)의 고체함유량을 높이고자 하였다. 건조 방법에는 열풍 건조 방법(flash drying, FD), 유동층 건조 방법(fluidized bed, FB), 유중 건조 방법(oil deposit stabilized, ODS)을 사용하였다. 석탄 종류에 의해서 고체함유량 차이는 최대 20% 이상 보였다. 또한, CWF을 제조할 때 넣어주는 첨가제의 종류를 다르게 하여 실험한 결과 첨가제에 의해서 5%까지 효율을 더 높일 수 있었다. 석탄의 입도분포는 $75{\mu}m$ 이하의 미분탄이 80% 함유되어야 CWF의 성능이 향상되는 것을 관찰하였다. 3가지 건조 방법을 활용하여 CWF를 제조해본 결과, 안정화시킨 유중 건조 석탄이 원탄에 비하여 12% 정도 더 높은 고체함유량을 갖는 CWF를 제조할 수 있는 것을 알 수 있었다.

• 한국세라믹학회지
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• 제18권4호
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• pp.219-228
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• 1981

To clarify influences of silicious raw materials on mineralogcal and petrological properties in clinkering process clay, shale, quartzite, sand and coal ash have been used as silicious raw materials. The tests on thermal properties, reactivity and burnability of raw mixtures which have different silicious raw materials respectively have been made by means of X-ray diffractometry, differential thermal analysis, optical microscopy and transmission electron microscopy. Limestone contains coarse crystalline grains which show 0.1-1.0mm and its decarbonation temperature is 86$0^{\circ}C$. Reaction temperatures among raw mixtures have been determined by X-ray diffractometry and their results are as follows; clay minerals under 1, 00$0^{\circ}C$, mica group, 100$0^{\circ}C$-110$0^{\circ}C$, feldspar group, 1, 10$0^{\circ}C$-1, 20$0^{\circ}C$ and quartz 1, 20$0^{\circ}C$-1, 30$0^{\circ}C$. Burnabilities of raw mixtures of different temperatures have been found that they mainly depend upon their mineral contents in silicious raw materials and their order is as follows; $clay\geq shale\gg quartzite \geq sand$.

• 자원리싸이클링
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• 제19권3호
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• pp.16-23
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• 2010

최근 고유가 시대로 접어들면서 연탄의 사용량이 급격하게 증가하고 있어 이때 발생되는 연탄재의 친환경적인 순화자원화 기술개발이 필요하게 되었다. 연탄재에는 가연성분인 미연탄소와 고온열적특성이 우수한 뮬라이트 성분이 다량 함유되어 있어 소성 에코벽돌의 원료로 적합하다고 판단된다. 이 연구의 목적은 연탄재에 함유되어 있는 미연탄소가 소성 에코벽돌의 특성에 어떠한 영향을 미치는 가를 파악하는데 있었다. 미연탄소 함량 10.5 wt%인 연탄재 50 wt%와 폐유리 50 wt%의 배합비율로 제조한 에코벽돌을 $950^{\circ}C$로 소성한 시험체의 압축강도는 소성 점토벽돌 국내규격(KS L 4201)의 1종 규격에 해당하였다. 특히, 미연탄소 함량이 1.0 wt%인 연탄재의 배합비율을 70 wt%까지 증가시켜 제조한 소성 에코벽돌 시험체의 압축강도는 소성 점토벽돌 1종 규격에 해당하였다.

• 플랜트 저널
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• 제4권4호
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• pp.71-77
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• 2008

The sulfur oxides is one of important materials to come about air pollution at thermal plant consuming fossil fuel. The several flue gas desulfurization equipments are installed and operated to decrease sulfur oxides. The flue gas desulfurization of our thermal plant is designed for optimizing flue gas desulfurization technical development and research by Korea Electric Power Research Institute. We operate this desulfurization equipment. Now, our country imports nearly 97 percentage of the energy source and competes with the world for the energy because of the sudden rise of raw materials cost. The fuel cost decrease of power plants is the most important factor of the operation. The fuel used in the experiment is the domestic anthracite from Kangwon Taeback and the bituminous coal from Taldinsky Mine in Russia. This Study is experimental investigations of desulfurization characteristics for domestic anthracite power plant by increasing bituminous coal. We surveyed possible parameters and conducted the performance about desulfurization equipment in Yong Dong thermal power plant.

• Nuclear Engineering and Technology
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• 제54권4호
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• pp.1161-1166
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• 2022

Green pitch coke with an average particle size of 2 mm was adopted as densifier and added to the raw materials of conventional A3-3 matrix graphite (MG) to prepare modified A3-3 matrix graphite (MMG) by the quasi-isostatic molding method. The structure, mechanical and thermal properties were assessed. Compared with MG, MMG had a more compact structure, and exhibited improved properties of higher mechanical strength, higher thermal conductivity and better molten salt barrier performance. Notably, under the same infiltration pressure of 5 atm, the fluoride salt occupation of MMG was only 0.26 wt%, whereas it was 15.82 wt% for MG. The densification effect of green pitch coke endowed MMG with improved properties for potential use in the spherical fuel elements of molten salt reactor.