• Title/Summary/Keyword: rate-limiting

Search Result 752, Processing Time 0.025 seconds

A Study on the Post-Weld Heat Treatment Effect Affecting Corrosion Behavior and Mechanical Property of Welding Part of RE36 Steel for Marine Structure (해양구조물용 RE36강 용접부의 부식거동 및 기계적 특성에 미치는 용접후 열처리 효과에 관한 연구)

  • 김성종;문경만
    • Journal of Welding and Joining
    • /
    • v.19 no.1
    • /
    • pp.65-74
    • /
    • 2001
  • A study on the corrosion behavior in case of As-welded and PWHT temperature 55$0^{\circ}C$ of welding part of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential measurement of weld metal(WM), base metal(BM) and heat affected zone(HAZ), both Al anode generating current and Al anode weight loss quantity under sacrificial anode cathodic protection conditions. And also we carried out slow strain rate test(SSRT) in order to research both limiting cathodic polarization potential for hydrogen embrittlement and optimum cathodic protection potential as well as mechanical properties by post-weld heat treatment(PWHT) effect. Hardness of HAZ was the highest among three parts(WM, BM and HAZ) and the highest galvanic corrosion susceptibility was HAZ. And the optimum cathodic polarization potential showing the best mechanical properties by SSRT method was from -770mV to -875mV(SCE). In analysis of SEM fractography, applied cathodic potential from -770mV to -875mV(SCE) it appeared dimple pattern with ductile fracture while it showed transgranular pattern (Q. C : quasicleavage) under -900mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement was under -900mV(SCE).

  • PDF

Numerical Analysis of a Tip Leakage Vortex in an Axial Flow Fan (축류홴 익단누설와류의 수치적 해석)

  • Jang, Choon-Man;Kim, Kwang-Yong
    • The KSFM Journal of Fluid Machinery
    • /
    • v.7 no.1 s.22
    • /
    • pp.36-44
    • /
    • 2004
  • Three-dimensional vortical flow and separated flow topology near the casing wall in an axial flow fan having two different tip clearances have been investigated by a Reynolds-averaged Navier-Stokes (RANS) flow simulation. The simulation shows that the tip leakage vortex formed close to the leading edge of the blade tip on suction side grows in the streamwise direction. On the casing wall, a separation line is formed upstream of the leakage vortex center due to the interference between the leakage vortex and main flow. The reverse flow is observed between the separation line and the attachment line generated downstream of the trailing edge, and increased with enlarging tip clearance. The patterns of a leakage velocity vector including a leakage flow rate are also analyzed according to two tip clearances. It is noted that the understanding of the distribution of a limiting streamline on the casing wall is very important to grasp the characteristics of the vortical flow in the axial flow fan.

A Study on the Corrosion Rehavior and Mechanical Property by SSRTTest of Welding Part of RE36 Steel for Marine Structure (해양구조물 RE36강의 용접부 부식거동 및 SSRT법에 의한 기계적 특성에 관한 연구)

  • 김종성;김진경;김종호;이명훈;김영식;문경만
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.24 no.4
    • /
    • pp.460-469
    • /
    • 2000
  • A study on the corrosion behavior of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential and corrosion current density measurement of weld metal(WM), base metal (BM) and heat affected zone(HAZ), Al anode generating current and Al anode weight loss quantity in case of cathodic protection. And we carried out slow strain rate test(SSRT) in order to research mechanical properties such as stress at maximum load, percent strain, time to fracture and strain to failure ratio etc and to find out limiting cathodic polarization potential for hydrogen embrittlement with applied cathodic polarization potential. Hardness of HAZ part was the highest among those three parts and also galvanic corrosion susceptibility was the highest in HAZ part among those three parts due to the lowest corrosion potential than other parts. However corrosion current density was the highest in WM part among those three parts. And the optimum cathodic polarization potential showing the best mechanical properties obtained by SSRT method with applied constant cathodic potential was from - 770mV to - 875mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement on the mechanical properties was under - 900mV(SCE).

  • PDF

Electrodialysis with a channeled stack for high strength cadmium removal from wastewater

  • Kyung Jin, Min;Hyo Jin, An;Ah Hyun, Lee;Hyun-Gon, Shin;Ki Young, Park
    • Membrane and Water Treatment
    • /
    • v.14 no.1
    • /
    • pp.47-54
    • /
    • 2023
  • In this study, high concentrations of cadmium-containing wastewater were treated by electrodialysis (ED) with a channel stack. The limiting current density (LCD), cadmium removal efficiency, and current efficiency were investigated under each experimental condition according to the Reynolds number (Re), membrane area, and pH. With the increase in the film area to 111, 333, 555, and 777 cm2 at Re (109.1), LCDs decreased to 408.11, 44.45, 35.32, and 13.64 A/m2, respectively. The highest cadmium removal efficiency (99.6%) and current efficiency were obtained for the membrane area of 111 and 777 cm2, respectively. Under changing Re in the pH range of 1 to 4, Re and LCD were proportional under the same pH condition, and pH and LCD tended to be inversely proportional under the same Re condition. Cadmium removal rate was the best at the pH range 3 - 4. It has been found that ED with channeled stacks can be successfully applied to treat wastewater containing high concentrations of cadmium.

Design of Residual Treatment Process with Filter Backwash Recycle System (역세척수 회수시스템이 포함된 배출수처리공정의 설계)

  • Bae, Byung-Uk;Choi, Kyung-Hwan
    • Journal of Korean Society on Water Environment
    • /
    • v.28 no.1
    • /
    • pp.109-114
    • /
    • 2012
  • In this study, both sedimentation and thickening experiments were conducted for residuals produced from an advanced water treatment plant for more accurate and practical design of residual treatment train. In order to design a backwashed residual sedimentation basin (SRSB) in the filter backwash water recycle system, two kinds of backwash waters, one from sand filter (SFBW) and the other from GAC adsorption bed (GACBW), were separately collected and their surface loading rate measured. In addition, in order to design a gravity thickener, batch thickening tests were conducted for concentrated residuals taken from sedimentation basin and their limiting solid flux ($SF_{L}$) measured. From the experimental results and consideration of the seasonal characteristics of the residual, surface loading rate of $70m^{3}/m^{2}{\cdot}d$ was proposed as a design parameter for SRSB and solid loading rate of 20 kg $TS/m^{2}{\cdot}d$ was proposed as a design parameter for gravity thickeners. Finally, the material mass-balance was made for the design of each unit process in the residual treatment train.

미세조류의 Methane 발효특성

  • 강창민;최명락
    • Microbiology and Biotechnology Letters
    • /
    • v.24 no.5
    • /
    • pp.597-603
    • /
    • 1996
  • This study was carried out to examine degradation characteristics of microalgae Chlorella vulgaris in methane fermentation. We measured COD and VS reduction, gas and methane productivity, VFA (volatile fatty acid), respectively. Then we calculated material balance and hydrolysis rates in soluble and solid material. The substrate concentration was controlled from 14 gCOD$_{cr}$/l to 64 gCOD$_{cr}$/l in batch cultures, and HRT (hydraulic retention time) controlled from 2 days to 30 days in continuous experi- ments. The results were as follows. In batch culture, accumulated gas productivity increased with the increase of the substrate concentration. The SS and VSS was removed all about 30% increase of substrate concentration and the most of the degradable material removed during the first 10 days. The curve of gas and methane production rate straightly increased until substrate concentration is 26 gCOD$_{cr}$/l. In continuous culture experiments, the removal rates at HRT 10days were 20% for total COD and TOC, respectively. At longer HRT, there was no increase in the removal efficiency. At HRT 15 days, the removal rates were 30% for SS and VSS, respectively. Soluble organic materials were rapidly degraded, and so there was no accumulated. Soluble COD concentration was not increase regardless of HRT-increasing. That meaned the hydrolysis was one of the rate-limiting stage of methane fermentation. The first-order rate constants of hydrolysis were 0.23-0.28 day$^{-1}$ for VSS, and 0.07-0.08 day$^{-1}$ for COD.

  • PDF

Effects of chemical reaction on the polishing rate and surface planarity in the copper CMP

  • Kim, Do-Hyun;Bae, Sun-Hyuk;Yang, Seung-Man
    • Korea-Australia Rheology Journal
    • /
    • v.14 no.2
    • /
    • pp.63-70
    • /
    • 2002
  • Chemical mechanical planarization (CMP) is the polishing process enabled by both chemical and mechanical actions. CMP is used in the fabrication process of the integrated circuits to achieve adequate planarity necessary for stringent photolithography depth of focus requirements. And recently copper is preferred in the metallization process because of its low resistivity. We have studied the effects of chemical reaction on the polishing rate and surface planarity in copper CMP by means of numerical simulation solving Navier-Stokes equation and copper diffusion equation. We have performed pore-scale simulation and integrated the results over all the pores underneath the wafer surface to calculate the macroscopic material removal rate. The mechanical abrasion effect was not included in our study and we concentrated our focus on the transport phenomena occurring in a single pore. We have observed the effects of several parameters such as concentration of chemical additives, relative velocity of the wafer, slurry film thickness or ash)tract ratio of the pore on the copper removal rate and the surface planarity. We observed that when the chemical reaction was rate-limiting step, the results of simulation matched well with the experimental data.

Evaluation of the Relationship between Nutrients and Phytoplankton; and Phytoplankton and Organic matter (영양염과 식물성플랑크톤 그리고 식물성플랑크톤과 유기물의 상관관계의 평가)

  • Kim, Woo-Hang
    • Proceedings of KOSOMES biannual meeting
    • /
    • 2006.05a
    • /
    • pp.117-120
    • /
    • 2006
  • The objective of this study was to evaluate the relationship between nutrients and phytoplankton; and phytoplankton and organic matter. In order to examine the limiting nutrient for phytoplankton, Redfield ration was used and revealed nitrogen limitation. Nitrogen limitation was greatest with a 4.7 DIN/DIP ratio especially during the summer season. Chl.-a increase by 79% and 97% in spring and summer, respectively, compared to winter. COD was lowest with 0.84mg/l in winter and highest with 1.12mg/l in summer. The interrelationship between nutrients and Chl.-a was high. Relationship coefficient$(r^2)$ between DIN and Chl.-a, and DIP and Chl.-a were 0.93 and 0.89, respectively. This suggests Nutrients might be utilized at the increase of phytoplankton. Also, Relationship coefficient$(r^2)$ between Chl.-a and COD was 0.78. COD production rate was calculated with Regression Equation. The COD production rate was 25% in winter and 40% in summer.

  • PDF

Protecting E-mail Server with Class-Based Rate Limiting Technique (클래스 기반의 대역 제한 기법을 통한 이메일 서버의 보호)

  • Yim, Kang-Bin;Lee, Chang-Hee;Kim, Jong-Su;Choi, Kyung-Hee;Jung, Gi-Hyun
    • Journal of the Institute of Electronics Engineers of Korea TC
    • /
    • v.41 no.6 s.324
    • /
    • pp.17-24
    • /
    • 2004
  • This paper proposes an efficient technique to protect e-mail server from DDoS attack using the CBQ (Class Based Queuing) algorithm The proposed method classifies incoming trafic to an e-mail server into three classes: 'more important mail traffic', 'less important traffic' and 'unknown traffic' and assigns bandwidths differently to the traffics. By differentiating the bandwidths of classes, normal mail traffic may flow even under DDoS attack in the proposed technique. The proposed technique is implemented on an embedded system which hires a switching processor with the WFHBD(Weighted Fair Hashed Bandwidth Distribution) engine that has been known as an efficient algorithm to distribute a given bandwidth to multiple sources, and it is verified that it can be an efficient way to protect e-mail server from DDoS attack.

Performance Enhancement of Anaerobic Treatment of Waste Sludge by Chemical Pretreatment (화학적 전처리를 통한 혐기성 슬러지 처리효율의 향상)

  • 허준무;박종안;손부순
    • Journal of environmental and Sanitary engineering
    • /
    • v.13 no.1
    • /
    • pp.16-25
    • /
    • 1998
  • Laboratory-scale experiment using anaerobic fluidized bed reactor was carried out to investigate the prehydrolysis step with caustic soda on the treatment efficiency of anaerobic sludge treatment, since the overall rate-limiting step for the complete anaerobic digestion of sludge was the hydrolysis step by extracellular bacterial enzymes of insoluble polymeric molecules. Reactors received a sludge which had not been pretreated, a 50-50 mixture of pretreated and untreated sludge, and the fully pretreated sludge. Hydraulic retention time of 10, 5, 2.5 days and 1 day were applied with an respective equivalent organic loading rate of 1.17, 2.23, 4.17, 11.24 gCOD/L/d. Reactor with the untreated sludge did not archieve adequate digestion even at the HRT of 5 days, and reactor, which received the 50-50 mixture, operated well at the HRT of 5 days, but began to show signs of unstable digestion at the HRT of 2.5 days. While, reactor, which was fed the hydrolyzed sludge, operated reasonably well at the 2.5 days, but was showing somewhat decrease in removal efficiencies. Results, therefore, have substantiated that the limiting reaction in the anaerobic treatment process is hydrolysis. The soluble COD did not significantly accumulate in the reactor as organic acid form, even when they were highly stressed. It was believed that this resistance to a build-up of organic acids and soluble COD behavior was mainly due to the maintenance of the methane bacteria in the fixed-film system which prevents washout as the organic loading increased. The anaerobic fluidized bed reactor was therefore effective for the digestion of waste activated sludge at short HRT.

  • PDF