• Title/Summary/Keyword: rate dependent

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Nonlinear rheology of polymer melts: a new perspective on finite chain extensibility effects

  • Wagner Manfred H.
    • Korea-Australia Rheology Journal
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    • v.18 no.4
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    • pp.199-207
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    • 2006
  • Measurements by Luap et al. (2005) of elongational viscosity and birefringence of two nearly monodisperse polystyrene melts with molar masses $M_{w}$ of $206,000g{\cdot}mol^{-1}$ (PS206k) and $465,000g{\cdot}mol^{-1}$ (PS465k) respectively are reconsidered. At higher elongational stresses, the samples showed clearly deviations from the stress optical rule (SOR). The elongational viscosity data of both melts can be modeled quantitatively by the MSF model of Wagner et al. (2005), which is based on the assumption of a strain-dependent tube diameter and the interchain pressure term of Marrucci and Ianniruberto (2004). The only nonlinear parameter of the model, the tube diameter relaxation time, scales with $M_{w}^{2}$. In order to get agreement with the birefringence data, finite chain extensibility effects are taken into account by use of the $Pad\'{e}$ approximation of the inverse Langevin function, and the interchain pressure term is modified accordingly. Due to a selfregulating limitation of chain stretch by the FENE interchain pressure term, the transient elongational viscosity shows a small dependence on finite extensibility only, while the predicted steady-state elongational viscosity is not affected by non-Gaussian effects in agreement with experimental evidence. However, deviations from the SOR are described quantitatively by the MSF model by taking into account finite chain extensibility, and within the experimental window investigated, deviations from the SOR are predicted to be strain rate, temperature, and molar mass independent for the two nearly monodisperse polystyrene melts in good agreement with experimental data.

Cr - Mo鋼 熔接 後熱處理材 의 勞破壞 에 關한 硏究

  • 박재규;김석원;김연식
    • Journal of Welding and Joining
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    • v.3 no.2
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    • pp.16-26
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    • 1985
  • Post weld heat treatment(PWHT), at more than 600.deg. C, is essential to remove residual stress and hydrogen in weld HAZ and improve fatigue characteristics. However, residual stress during PWHT is responsible for PWHT embitterment and it promotes precipitation of impurities to grain boundary. In this paper, the effect of stress simulated residual stress on fatigue failure was evaluated by fatigue test, microhardness test and fractograph. The obtained results are summarized as follows; (1) The fatigue crack growth rate(da/dN) of parent and heat treated parent was affected by microstructure due to heat treatment and it depended on stress intensity factor (.DELTA.k). (2) The fatigue strength of weld HAZ was dependent on applied stress during PWHT and da/dN after PWHT was slower than as-weld. (3) Softening amount of weld HAZ was bigger than any other due to PWHT. Hardness value of weld HAZ was affected by heat treatment under the applied stress of 10 $kgf/mm^2$, but beyond 20 $kgf/mm^2$ it was increased by the applied stress rather than heat treatment. (4) Beyond the applied stress of 20 $kgf/mm^2$ during PWHT, intergranular fracture surface was observed and its amount was increased with applied stress during PWHT. (5) Effect of applied stress during PWHT on aspect of fracture surface was larger rather than that on fatigue crack growth behavior.

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Effect of Kamicheonmagudeungeum on Hypertension (가미천마구등음이 고혈압 병태모델에 미치는 영향)

  • Song, Byoung-Yong;Hong, Suk;Kim, Dong-Hee;Jeon, Sang-Yun
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.21 no.2
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    • pp.504-510
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    • 2007
  • Kamicheonmagudeungeum(KCGE), a traditional herbal medicine, has been used as a therapeutic agent for the treatments of acute stage of hypertension. We evaluated the effects of KCGE on hypertension induced by DOCA-salt in rats. The systolic blood pressure and pulse rate significantly lowered by oral administration with KCGE. The levels of plasma hormones including dopamine, epinephrine and norepinephrine, and serum electrolyte were also reduced in KCGE treated rats. In addition, the production of reactive oxigen species (ROS) were greatly decreased by the treatment with KCGE in cultured bovine endothelial cells and angiotensine converting enzyme (ACE) activites were also inhibited by KCGE in a dose dependent manner. This study indicated that KCGE is a safe and effective treatment for hypertension.

Control of the Asymmetric Flow in a Supersonic Nozzle (초음속 노즐에서 발생하는 비대칭 유동의 제어에 관한 연구)

  • Matsuo, Shigeru;Setoguchi, Toshiaki;Hashimoto, Tokitada;Tokuda, Seiya;Nagao, Junji;Kim, Heuy-Dong
    • Journal of the Korean Society of Visualization
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    • v.9 no.2
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    • pp.61-65
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    • 2011
  • Several previous works on rocket nozzle flows have revealed the existence of the transition from FSS to RSS and the occurrence of asymmetric flow associated with the boundary layer separation, which can cause excessive side-loads of the propulsion system. Thus, it is of practical importance to investigate the asymmetric flow behaviors of the propulsion nozzle and to develop its control method. In the present study, the asymmetric flow control method using a cavity system was applied to supersonic nozzle flow. Time-dependent asymmetric flow was experimentally investigated with the rate of change of the nozzle pressure ratio. The results obtained showed that the cavity system installed on nozzle wall would be helpful in fixing the unsteady motions of the boundary layer separation, consequently reducing the possibility of the occurrence of the asymmetric flow.

Gastroprotective Activities of Sennoside A and Sennoside B via the Up-Regulation of Prostaglandin E2 and the Inhibition of H+/K+-ATPase

  • Hwang, In Young;Jeong, Choon Sik
    • Biomolecules & Therapeutics
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    • v.23 no.5
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    • pp.458-464
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    • 2015
  • Sennoside A (erythro) and sennoside B (threo) are dianthrone glycosides and diastereomers. We investigated their abilities to prevent the gastric lesions associated with diseases, such as, gastritis and gastric ulcer. To elucidate their gastroprotective effects, the inhibitions of $HCl{\cdot}tOH$-induced gastritis and indomethacin-induced gastric ulcers were assessed in rats. It was observed that both sennoside A and sennoside B increased prostaglandin $E_2$ ($PGE_2$) levels and inhibited $H^+/K^+$-ATPase (proton pump). In a rat model, both compounds reduced gastric juice, total acidity and increased pH, indicating that proton pump inhibition reduces gastric acid secretion. Furthermore, sennoside A and B increased $PGE_2$ in a concentration-dependent manner. In a gastric emptying and intestinal transporting rate experiment, both sennoside A and sennoside B accelerated motility. Our results thus suggest that sennoside A and sennoside B possess significant gastroprotective activities and they might be useful for the treatment of gastric disease.

Regulation of circulating Mg2+ in the rat by metabolic inhibition (흰쥐에서 대사작용 억제에 의한 혈중 Mg2+ 조절)

  • Kim, Jong-shick;Kim, Shang-jin;Kim, Jin-shang
    • Korean Journal of Veterinary Research
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    • v.39 no.1
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    • pp.70-76
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    • 1999
  • Magnesium ($Mg^{2+}$) plays an important role in the regulation of a range of intracellular processes. Regulation of extracellular $Mg^{2+}$ contents was studied in the anesthetized Sprague-Dawley (SD) rats. Animals were injected intraperitoneally with sodium nitrite ($NaNO_2$), and circulating $Mg^{2+}$($[Mg^{2+}]c$) was measured after the injection and then 10 and 20 minutes later. A dose-dependent increase in $[Mg^{2+}]c$ was observed in animals injected with $NaNO_2$ at a dose of 10mg/kg or higher. Pretreatment with methylene blue prevented the $NaNO_2$-induced increase in $[Mg^{2+}]c$. $[Mg^{2+}]c$ displayed an inverse linear correlation with hemoglobin and exponential correlation during $NaNO_2$ injection. Injection of KCN or rotenone also induced an increase in $[Mg^{2+}]c$. An increase in $[Mg^{2+}]c$ was observed when respiration rate was reduced from 100/min (140ml/min) to 10/min (14ml/min) during 30 min. These results indicate that changes in $[Mg^{2+}]c$ inversely reflect alteration of ATP in a model of metabolic inhibition.

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Effect of Fines Distribution on Press Dewatering and Physical Properties of Multi-ply Sheet

  • Lee, Hak-Lae;Youn, Hye-Jung;Kang, Tae-Young;Choi, Ik-Sun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.5
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    • pp.36-41
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    • 2008
  • Multi-ply sheet forming has many advantages including the possibility of using wide range of materials in a given structure, lowering production cost, making higher grammage products and so on. But, incorrect structure of sheet makes flow resistance higher so that it shows poor dewatering in press section. One of major factors that affect sheet structure and dewatering property is fines content in each layer. We, therefore, examined the press dewatering of multi-ply sheet that has the different fines content in each layer and the effect of fines distribution on physical properties of sheet to find a technology for optimum utilization of raw materials. In case of two layered sheet, the sheet which was composed of layers with the different flow resistance showed higher dewatering rate than one which has the same flow resistance. And the more difference in fines content for layers existed, the more dewatering occurred. For three layered sheets, dewatering is mainly dependent on fines content of bottom layer. Strength properties were affected by dewatering degree and multi-ply sheet structure.

Hydrazine Doped Graphene and Its Stability

  • Song, MinHo;Shin, Somyeong;Kim, Taekwang;Du, Hyewon;Koo, Hyungjun;Kim, Nayoung;Lee, Eunkyu;Cho, Seungmin;Seo, Sunae
    • Applied Science and Convergence Technology
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    • v.23 no.4
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    • pp.192-199
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    • 2014
  • The electronic property of graphene was investigated by hydrazine treatment. Hydrazine ($N_2H_4$) highly increases electron concentrations and up-shifts Fermi level of graphene based on significant shift of Dirac point to the negative gate voltage. We have observed contact resistance and channel length dependent mobility of graphene in the back-gated device after hydrazine monohydrate treatment and continuously monitored electrical characteristics under Nitrogen or air exposure. The contact resistance increases with hydrazine-treated and subsequent Nitrogen-exposed devices and reduces down in successive Air-exposed device to the similar level of pristine one. The channel conductance curve as a function of gate voltage in hole conduction regime keeps analogous value and shape even after Nitrogen/Air exposure specially whereas, in electron conduction regime change rate of conductance along with the level of conductance with gate voltage are decreased. Hydrazine could be utilized as the highly effective donor without degradation of mobility but the stability issue to be solved for future application.

Hygrothermal Fracture Analysis in Dissimilar Materials

  • Ahn, Kook-Chan;Lee, Tae-Hwan;Bae, Kang-Yul
    • International Journal of Aeronautical and Space Sciences
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    • v.2 no.2
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    • pp.65-72
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    • 2001
  • This paper demonstrates an explicit-implicit, finite element analysis for linear as well as nonlinear hygrothermal stress problems. Additional features, such as moisture diffusion equation, crack element and virtual crack extension(VCE) method for evaluating J-integral are implemented in this program. The Linear Elastic Fracture Mechanics(LEFM) Theory is employed to estimate the crack driving force under the transient condition for an existing crack. Pores in materials are assumed to be saturated with moisture in the liquid form at the room temperature, which may vaporize as the temperature increases. The vaporization effects on the crack driving force are also studied. The ideal gas equation is employed to estimate the thermodynamic pressure due to vaporization at each time step after solving basic nodal values. A set of field equations governing the time dependent response of porous media are derived from balance laws based on the mixture theory. Darcy's law is assumed for the fluid flow through the porous media. Perzyna's viscoplastic model incorporating the Von-Mises yield criterion are implemented. The Green-Naghdi stress rate is used for the invariant of stress tensor under superposed rigid body motion. Isotropic elements are used for the spatial discretization and an iterative scheme based on the full Newton-Raphson method is used for solving the nonlinear governing equations.

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Powder Densification Using Equal Channel Angular Pressing (ECAP 공정을 이용한 분말의 치밀화)

  • Yoon Seung-Chae;Seo Min-Hong;Hong Sun-Ig;Kim Hyoung-Seop
    • Journal of Powder Materials
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    • v.13 no.2 s.55
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    • pp.124-128
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    • 2006
  • In recent years, equal channel angular pressing (ECAP) has been the subject of intensive study due to its capability of producing fully dense samples having a ultrafine grain size. In this paper, the ECAP process was applied to metallic powders in order to achieve both powder consolidation and grain refinement. In the ECAP process for solid and powder metals, knowledge of the internal stress, strain and strain rate distribution is fundamental to the determination of the optimum process conditions for a given material. The properties of the ECAP processed solid and powder materials are strongly dependent on the shear plastic deformation behavior during ECAP, which is controlled mainly by die geometry, material properties, and process conditions. In this study, we investigated the consolidation, plastic deformation and microstructure evolution behaviour of the powder compact during ECAP.