• Title/Summary/Keyword: rapid cycling

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The Study on the Cycling Time for Interbus (인터버스 순환시간 측정에 대한 연구)

  • Park, Jang-Hwan
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.6
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    • pp.170-175
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    • 2004
  • The test on the cycle time of the Interbus, widely used in automobile industry, is evaluated in this paper. The measurement of cycle time is a very Important factor for performance of Interbus. The test was performed by the under normal circumstances and circumstances with EMC. The theoretical cycle time which was derived from mathematical form and from real system with Interbus approach to nearly result. As a result, it is shown that Interbus is deterministic, rapid and reliable system.

Preparation of CoFe2O4 Nanoparticle Decorated on Electrospun Carbon Nanofiber Composite Electrodes for Supercapacitors (코발트 페라이트 나노입자/탄소 나노섬유 복합전극 제조 및 슈퍼커패시터 특성평가)

  • Hwang, Hyewon;Yuk, Seoyeon;Jung, Minsik;Lee, Dongju
    • Journal of Powder Materials
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    • v.28 no.6
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    • pp.470-477
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    • 2021
  • Energy storage systems should address issues such as power fluctuations and rapid charge-discharge; to meet this requirement, CoFe2O4 (CFO) spinel nanoparticles with a suitable electrical conductivity and various redox states are synthesized and used as electrode materials for supercapacitors. In particular, CFO electrodes combined with carbon nanofibers (CNFs) can provide long-term cycling stability by fabricating binder-free three-dimensional electrodes. In this study, CFO-decorated CNFs are prepared by electrospinning and a low-cost hydrothermal method. The effects of heat treatment, such as the activation of CNFs (ACNFs) and calcination of CFO-decorated CNFs (C-CFO/ACNFs), are investigated. The C-CFO/ACNF electrode exhibits a high specific capacitance of 142.9 F/g at a scan rate of 5 mV/s and superior rate capability of 77.6% capacitance retention at a high scan rate of 500 mV/s. This electrode also achieves the lowest charge transfer resistance of 0.0063 Ω and excellent cycling stability (93.5% retention after 5,000 cycles) because of the improved ion conductivity by pathway formation and structural stability. The results of our work are expected to open a new route for manufacturing hybrid capacitor electrodes containing the C-CFO/ACNF electrode that can be easily prepared with a low-cost and simple process with enhanced electrochemical performance.

Biomass-Derived Three-Dimensionally Connected Hierarchical Porous Carbon Framework for Long-Life Lithium-Sulfur Batteries

  • Liu, Ying;Lee, Dong Jun;Lee, Younki;Raghavan, Prasanth;Yang, Rong;Ramawati, Fitria;Ahn, Jou-Hyeon
    • Clean Technology
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    • v.28 no.2
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    • pp.97-102
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    • 2022
  • Lithium sulfur (Li-S) batteries have attracted considerable attention as a promising candidate for next-generation power sources due to their high theoretical energy density, low cost, and eco-friendliness. However, the poor electrical conductivity of sulfur and its insoluble discharging products (Li2S2/Li2S), large volume changes, severe self-discharge, and dissolution of lithium polysulfide intermediates result in rapid capacity fading, low Coulombic efficiency, and safety risks, hindering Li-S battery commercial development. In this study, a three-dimensionally (3D) connected hierarchical porous carbon framework (HPCF) derived from waste sunflower seed shells was synthesized as a sulfur host for Li-S batteries via a chemical activation method. The natural 3D connected structure of the HPCF, originating from the raw material, can effectively enhance the conductivity and accessibility of the electrolyte, accelerating the Li+/electron transfer. Additionally, the generated micropores of the HPCF, originated from the chemical activation process, can prevent polysulfide dissolution due to the limited space, thereby improving the electrochemical performance and cycling stability. The HPCF/S cell shows a superior capacity retention of 540 mA h g-1 after 70 cycles at 0.1 C, and an excellent cycling stability at 2 C for 700 cycles. This study provides a potential biomass-derived material for low-cost long-life Li-S batteries.

Development and Application of the Photosynthesis Experimental Module Based on Scientist's Inquiry Processes (과학자의 탐구 과정을 재구성한 광합성 실험 모듈의 개발과 적용)

  • Kim, Ho-Gi;Kim, Yeon-Ju;Kim, Sung-Ha
    • Journal of Science Education
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    • v.35 no.2
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    • pp.204-220
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    • 2011
  • This study was intended to develop an experimental module based on inquiry processes conducted by photosynthesis scientists. It was aimed to enhance scientific inquiry ability of the middle school students by applying the developed module. Developed module included some experiments conducted by earlier photosynthesis scientists such as Helmont, Woodward, Priestly, Hales and Ingen-Hausz. Inquiry process was involved in the developed module for instructing the inquiry methods. Rapid-cycling Brassica rapa known as a Fast Plant was used for the experimental material. Developed module was applied to the experimental group consisting 27 eighth grader, while experiments suggested in the science textbook was applied to the control group consisting 30 eighth grader. Developed module was more effective in improving students' scientific inquiry ability, especially measuring, forecasting and hypothesizing ability as its subordinate elements. When the result of post-test was compared to one of pre-test in the experimental group, their observing, forecasting, and generalization ability were improved. Experimental group showed that students' conception in photosynthesis and conceptual development related with the role of plants in the ecosystem and plant's food and movement of the water and nutrients were also improved. Before application, students in the experimental group did not have enough understanding of the abstract concept such as the existence or the role of the materials like $CO_2$ or $O_2$ or the energy accumulation. Developed module could help students to achieve the comprehensive concept regarding the role of plants as producers of organic matter and oxygen and to enhance their scientific inquiry ability and concepts regarding photosynthesis.

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A Study on the Electrode Characteristics of Hypo-Stoichiometric Zr-based Hydrogen Storage Alloys

  • Lee, Sang-Min;Kim, Seoung-Hoe;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.4
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    • pp.197-210
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    • 1999
  • The hydrogen storage performance and electrochemical properties of $Zr_{1-X}Ti_X(Mn_{0.2}V_{0.2}Ni_{0.6})_{1.8}$(X=0.0, 0.2, 0.4, 0.6) alloys are investigated. The relationship between discharge performance and alloy characteristics such as P-C-T characteristics and crystallographic parameters is also discussed. All of these alloys are found to have mainly a C14-type Laves phase structure by X-ray diffraction analysis. As the mole fraction of Ti in the alloy increases, the reversible hydrogen storage capacity decreases while the equilibrium hydrogen pressure of alloy increases. Furthermore, the discharge capacity shows a maxima behavior and the rate-capability is increased, but the cycling durability is rapidly degraded with increasing Ti content in the alloy. In order to analyze the above phenomena, the phase distribution, surface composition, and dissolution amount of alloy constituting elements are examined by S.E.M., A.E.S. and I.C.P. respectively. The decrease of secondary phase amount with increasing Ti content in the alloy explains that the micro-galvanic corrosion by multiphase formation is little related with the degradation of the alloys. The analysis of surface composition shows that the rapid degradation of Ti-substituted Zr base alloy electrode is due to the growth of oxygen penetration layer. After comparing the radii of atoms and ions in the electrolyte, it is clear that the electrode surface becomes more porous, and that is the source of growth of oxygen penetration layer while accelerating the dissolution of alloy constituting elements with increasing Ti content. Consequently, the rapid degradation (fast growth of the oxygen-penetrated layer) with increasing Ti substitution in Zr-based alloy is ascribed to the formation of porous surface oxide through which the oxygen atom and hydroxyl ion with relatively large radius can easily transport into the electrode surface.

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LC-MS/MS-based Quantification of Ten Neurotransmitters in Rat Limbic System and Serum: Application to Chronic Unpredictable Mild Stress-Induced Depression Rats

  • Mingyan Ma;Qiangxiang Chen;Wen Cao;Yubo Zhou;Aijuan Yan;Yanru Zhu
    • Mass Spectrometry Letters
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    • v.14 no.3
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    • pp.91-103
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    • 2023
  • As one of the most common mood disorders, numerous studies have shown depression is the main risk factor for non-suicidal self-harm. The pathogenesis of depression is complex, and a comprehensive and rapid measurement of monoamine neurotransmitters and their metabolites will be very helpful in understanding the pathogenesis of depression. Therefore, a rapid and sensitive underivatized liquid chromatography-tandem mass spectrometry method was developed and validated for the simultaneous monitoring of the levels of ten neurotransmitters and their metabolites in rat serum and limbic system and successfully applied to quantify the changes of neurotransmitter levels in chronic unpredictable mild stress-induced rats. The analytes studied were mainly involved in tyrosine metabolism, tryptophan metabolism, and glutamate cycling pathways, which are important in the pathogenesis of depression. It had been verified the method was sensitive and effective, with satisfactory linearity, and met the requirements of biological sample determination. Levels of neurotransmitters in rat serum, hippocampus, amygdala, prefrontal cortex, striatum, and hypothalamus were determined via the method. The results showed serotonin, dopamine, norepinephrine, and their metabolites were decreased, glutamine was increased, and glutamate was disturbed in chronic unpredictable mild stress-induced depression rats. This method provides a new approach to studying the pathogenesis of depression and other neurological disorders.

Effects of Canopy Removal on Cellulose Decomposition and Nitrogen Mineralization in Quercus rubra Stands (임관 제거가 루브라참나무림의 셀룰로오스 분해와 질소 무기화에 미치는 영향)

  • Kim, Choonsig
    • The Korean Journal of Ecology
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    • v.18 no.2
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    • pp.219-230
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    • 1995
  • Although many studies of nutrient cycling in forest ecosystems have reported that clearcutting creates increased organic matter decomposition and nitrogen (N) mineralization in soils, little is known about the change of these factors following various levels of canopy removal. A series of experimental plots with four levels of canopy cover, i.e., clearcut, 25%, 75%, and uncut, was established in northern red oak (Quercus rubra L.) stands in northern Lover Michigan, U.S.A. I examined decomposition of cellulose filter papers and N mineralization using an in situ soil incubation technique in the top 15cm of mineral soil during the second growing season (1992, May-October) following stand manipulation. Mass loss from cellulose filter papers was more rapid in the canopy removal treatments than in the uncut treatment. similarly, net N mineralization was significantly greater in the canopy removal treatments than in the uncut treatment. There was no significant difference in net N mineralization rates among the three levels of canopy removal. Net N mineralization for the growing season was 58 kg/ha for the clearcut, 54 kg/ha for the 25% canopy cover, 51 kg/ha for the 75% canopy cover, and 22 kg/ha for the uncut treatment. These results indicated that even only small amounts of canopy removal (leaving 75% canopy cover) let to substantial increases of cellulose decomposition and the amount of available soil nitrogen.

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Flexible and Transparent Plastic Electrodes Composed of Reduced Graphene Oxide/Polyaniline Films for Supercapacitor Application

  • Sarker, Ashis K.;Hong, Jong-Dal
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1799-1805
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    • 2014
  • In this article, we described about the preparation and electrochemical properties of a flexible energy storage system based on a plastic polyethylene terephthalate (PET) substrate. The PET treated with UV/ozone was fabricated with multilayer films composed of 30 polyaniline (PANi)/graphene oxide (GO) bilayers using layer-by-layer assembly of positively charged PANi and negatively charged GO. The conversion of GO to the reduced graphene oxide (RGO) in the multilayer film was achieved using hydroiodic acid vapor at $100^{\circ}C$, whereby PANi structure remained nearly unchanged except a little reduction of doping state. Cyclic voltammetry and charge/discharge curves of 30 PANi/RGO bilayers on PET substrate (shorten to PANi-$RGO_{30}$/PET) exhibited an excellent volumetric capacitance, good cycling stability, and rapid charge/discharge rates despite no use of any metal current collectors. The specific capacitance from charge/discharge curve of the PANi-$RGO_{30}$/PET electrode was found to be $529F/cm^3$ at a current density of $3A/cm^3$, which is one of the best values yet achieved among carbon-based materials including conducting polymers. Furthermore, the intrinsic electrical resistance of the PANi-$RGO_{30}$/PET electrodes varied within 20% range during 200 bending cycles at a fixed bend radius of 2.2 mm, indicating the increase in their flexibility by a factor of 225 compared with the ITO/PET electrode.

Review of Evaluation Methods and Soil Quality Factors for Agriculture Soils (농경지 토양의 토질요소와 평가 방법의 검토)

  • Chung, Doug Young;Lee, Kyo Suk
    • Korean Journal of Agricultural Science
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    • v.32 no.2
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    • pp.243-253
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    • 2005
  • In agricultural ecosystem, soils which play important roles of storage and cycling of substances become a crtitical social problem due to rapid increase of contaminants with respect to our health. Soil as productivity should be interpreted as soil quality, that is important criteria in maintaining sustainable agriculture for production of safe food. Therefore, it needs to set the criteria of soil quality by considering environmental factors including relevant parameters which are involved in soil quality soil health because soils are widely distributed and have various characteristics such as physical, chemical, and biological propevties. Therefore, it requires intensive investigation of evaluation methods and development of related parameters for environmentally sound agriculture and safe soil management.

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Optimized Digital Proportional Integral Derivative Controller for Heating and Cooling Injection Molding System

  • Jeong, Byeong-Ho;Kim, Nam-Hoon;Lee, Kang-Yeon
    • Journal of Electrical Engineering and Technology
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    • v.10 no.3
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    • pp.1383-1388
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    • 2015
  • Proportional integral derivative (PID) control is one of the conventional control strategies. Industrial PID control has many options, tools, and parameters for dealing with the wide spectrum of difficulties and opportunities in manufacturing plants. It has a simple control structure that is easy to understand and relatively easy to tune. Injection mold is warming up to the idea of cycling the tool surface temperature during the molding cycle rather than keeping it constant. This “heating and cooling” process has rapidly gained popularity abroad. However, it has discovered that raising the mold wall temperature above the resin’s glass-transition or crystalline melting temperature during the filling stage is followed by rapid cooling and improved product performance in applications from automotive to packaging to optics. In previous studies, optimization methods were mainly selected on the basis of the subjective experience. Appropriate techniques are necessary to optimize the cooling channels for the injection mold. In this study, a digital signal processor (DSP)-based PID control system is applied to injection molding machines. The main aim of this study is to optimize the control of the proposed structure, including a digital PID control method with a DSP chip in the injection molding machine.