• Journal of Korea Water Resources Association
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• v.39 no.7 s.168
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• pp.593-603
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• 2006

The basin response to storm is regarded as nonlinearity inherently. In addition, the consistent nonlinearity of hydrologic system response to rainfall has been very tough and cumbersome to be treated analytically. The thing is that such nonlinear models have been avoided because of computational difficulties in identifying the model parameters from recorded data. The parameters of nonlinear system considered as dynamic effects in the conceptual model are optimized as the sum of errors between the observed and computed runoff is minimized. For obtaining the optimal parameters of functions, the historical data for the Bocheong watershed in the Geum river basin were tested by applying the numerical methods, such as quasi-linearization technique, Runge-Kutta procedure, and pattern-search method. The estimated runoff carried through from the storage function with dynamic effects was compared with the one of 1st-order differential equation model expressing just nonlinearity, and also done with Nash model. It was found that the 2nd-order model yields a better prediction of the hydrograph from each storm than the 1st-order model. However, the 2nd-order model was shown to be equivalent to Nash model when it comes to results. As a result, the parameters of nonlinear 2nd-order differential equation model performed from the present study provided not only a considerable physical meaning but also a applicability to Korean watersheds.

• Journal of Environmental Science International
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• v.5 no.5
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• pp.593-603
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• 1996

A dual-porosity filmed agglomerate model for the porous cathode of the molten carbonate fuel has been investigated to predict the cell performance. A phenomenological treatment of molecular, kinetic and electrode parameters has been given. The major physical and chemical phenomena being modeled include mass transfer, ohmic losses and reaction kinetics at the electrode- electrolyte interface. The model predicts steady-state cell performance, given the above conditions that characterize the state of the electrode. Quasi-linearization and finite difference techniques are used to solve the coupled nonlinear differential equations. Also, the effective surface area of electrode pore was obtained by mercury porosimeter. The results of the investigation are presented in the form of plots of overpotential vs. current density with varied the electrode material, gas composition and mechanism. The predicted polarization curves are compared with the empirical data from 1 c$m^2$ cell. A fair correspondence is observed.