• Title/Summary/Keyword: quartz zone

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A Geochemical Study on the Alunite Zone of the Nohwa Pyrophyllite Deposits (노화납석광산에서 산출되는 명반석대에 대한 지구화학적 연구)

  • Shin, Sang Eun;Park, Hong Bong
    • Economic and Environmental Geology
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    • v.25 no.4
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    • pp.373-378
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    • 1992
  • Ores of the Nohwa Pyrophyllite Deposits are composed mainly of pyrophyllite, kaolinite (dickite), quartz, pyrite, alunite and diaspore, etc. Alunite ore zone is located in the middle-lower parts of the deposits. Alunite ore zone with thickness of 20~30 cm is divided into two parts according to alunite contents: reddish and white greyish zone in the upper and lower parts, respectively. And the reddish alunitic ore has higher contents $Al_2O_3$, $K_2O$, $Na_2O$ and Ig.loss than the white greyish alunitic ore. Perhaps alunitization of the deposits occurred in the vicinity of paleo-ground water table. EPMA data shows that sodium replaces potassium considerably in alunite structures and that the hydrothermal solution probably contains considerable amounts of sodium.

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A Study on Mineralization of Anyang Feldspar Ore Deposit (안양장석광상의 광화작용에 관한 연구)

  • Park, Boo Seong;Chi, Jeong Mahn
    • Economic and Environmental Geology
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    • v.27 no.1
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    • pp.11-28
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    • 1994
  • The Anyang Feldspar Mine is located in Seoksu Dong, Anyang City, Kyeonggi Do, Korea and has a long exploitation record that is once produced high grade sodium feldspars, for glaze. Geologically, This area is mainly composed of Mesozoic Jurassic biotite granite (Anyang granite) which intruded Precambrian Kyeonggi Gneiss Complex outcroped near the mining area. The deposit is localized on the southwest hill side of Anyang granite batholith and is confined in hydrothemal alteration zone formed by sodium-rich alkali hydrothermal fluids along the fractures of leucocratic granite showing later differentiation facies in the biotite granite. The hydrothermal alteration is characterized by albitization, sericitization, and desilication. The microscopic observation and EPMA, XRD analysis of the feldspar ores show that major minerals are albite and quartz and accessory minerals are orthoclase and sericite, and they are rarely associated with perthite, fluorite, zircon, kaolinite, molybdenite, microcline and iron-oxide. In the REE pattern, the strong negative Eu anomalies of the feldspar ores indicate the influence of feldspar fractionation and show similiar pattern of the host leucocratic granite. The filling temperature of quartz crystals in ore zone ranges from $276^{\circ}C$ to $342^{\circ}C$, and it is inferred that the alteration occurred by the hypothermal solution.

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Nonlinear optical properties of $TiO_{2}$ single crystal ($TiO_{2}$ 단결정의 비선형광학 특성)

  • 신재혁;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.3
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    • pp.240-249
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    • 1995
  • Rutile type of $TiO_{2}$ single crystal was grown by floating zone method in order to obtain the highly transparent and contamination-free single crystal. The linear refractive index of perpendicular and parallel to c-axis was measured as a function o f wavelength from 500 to 1000nm. The optical energy band gap was estimated as 2.99 eV from the absorption spectrum. The theoretical $\chi^{(3)}$} value of $TiO_{2}$ was discussed in comparison with that of $SiO_{2}$ quartz single crystal on the basis of semiempirical model. On the other hand, the second-hyperpolarizability, ${\gamma}({Ti}^{4+})$ was calculated in order to describe the effect of $Ti_{4}$ ion on the third order nonlinear optical properties.

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A review on the K-Ar Ages of Quartz Schist in the Okdong Fault Zone: Robust Enough for the Evidence for the Precambrian Deposition of the Jangsan Formation? (옥동단층대 석영편암의 K-Ar 연령에 대한 검토: 장산층의 선캠브리아기 퇴적에 대한 확실한 증거로 활용 가능한가?)

  • Kim, Myoung Jung;Park, Kye-Hun
    • The Journal of the Petrological Society of Korea
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    • v.27 no.1
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    • pp.67-72
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    • 2018
  • The K-Ar ages of a sericite quartz schist in the lower Jangsan Formation along the Okdong fault zone reported by Yun (1983) have attracted attention again because of their potential to constrain the depositional timing of the Jangsan Formation. The oldest age of $562{\pm}2Ma$ among three reported K-Ar ages in the schist led to the claim that the depositional period of the lowermost Jangsan Formation in the Joseon Supergroup is late Neoproterozoic. Its depositional age is important for understanding the tectonic evolution of the Korean Peninsula including the formation and evolution histories of its sedimentary basins. Thus, the reliability and geological meaning of three K-Ar ages in the original paper (Yun, 1983) were revisited in the review. Quartz grains in the analyzed sample contain a considerable amount of excess Ar, and therefore it is inappropriate to use the ages as a basis for a depositional age constraint of the Jangsan Formation. The timing of mylonitization in the schist is recalculated as ~170 Ma.

Mineral Distribution in the Southeastern Yellow Sea Surface Sediments; KORDI Cruise Samples in 2010 (황해 남동부 표층 해양 퇴적물의 광물 분포; 2010년 한국해양연구원 탐사 시료)

  • Cho, Hyen-Goo;Kim, Soon-Oh;Yi, Hi-Il;Shin, Kyung-Hoon
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.3
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    • pp.205-216
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    • 2011
  • Mineral compositions of 69 southeastern Yellow Sea surface sediments collected at the Korea Ocean Research and Development Institute (KORDI) cruise in 2010, were determined using the quantitative X-ray diffraction analysis. Southeastern Yellow Sea surface sediments are composed of major minerals (quartz 49.1%, plagioclase 13.0% and alkali feldspar 9.3%), clay minerals, calcite, and aragonite. Illite (9.4%) is the most abundant clay mineral, chlorite (4.6%) is the second, and kaolinite (0.8%) is few. Quartz and alkali feldspar contents are high in coarse-grained sediments, whereas amphibole and clay mineral contents are high in fine-grained sediments. Quartz, plagioclase, alkali feldspar, chlorite, and kaolinite contents are higher, and illite content is lower in mud zone 1 corresponding to south margin of Central Yellow Sea Mud than in mud zone 2, a part of Southeastern Yellow Sea Mud. Difference of mineral composition between two mud zone suggests that source of fine sediment may be different in two mud zone and Southeastern Yellow Sea Mud might be largely supplied from the Keum and Youngsan rivers in southern part of the west coast in the Korean Peninsula.

Geological Structures of the Imgye Area, Kangweondo, Korea (강원도(江原道) 임계지역(臨溪地域)의 지질구조(地質構造))

  • Kim, Jeong Hwan;Kee, Weon Seo
    • Economic and Environmental Geology
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    • v.24 no.1
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    • pp.43-55
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    • 1991
  • The Imgye area, in the NE Taebaegsan Region, consists of Precambrian granites and schist complex at the base and Paleozoic sedimentary rocks and amphibolite at cover. The granites in the area were previously thought to be Paleozoic in age, but recent geochronological data yields isotopic age ranging from $1837{\pm}82Ma$ to $2108{\pm}82Ma$ by Rb-Sr whole rock method. Therefore, basement-cover relations in the area should be reexamined. During the study, mylonite zone recognized along the contact boundary between Precambrian granites and Cambrian Jangsan Quartzite Formation. Mylonite zone has 150 - 250 m in width. Mylonitic rocks can divide into two groups; quartz mylonite derived from Jangsan Formation and mylonitic granites from Precambrian granites. Intensity of mylonitic foliation decreased toward the north. Amphibolite occurs as an intrusive sills within mylonite zone. Mineral fabrics and small scale shear zones are commonly seen in amphibolite. It indicates that intrusive age of amphibolite is synchronous to the formation of mylonite zone. Mylonite zone was reactivated as ductile thrust faults and forms the hinterland dipping imbricate zone during the Cretaceous Bulkuksa Orogeny. The near parallelism of mineral stretching lineation and long axis of strain ellipes indicates that the area is affected by a homogeneous pure shear flattening together with the variable components of simple shear.

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Gold Abundance in Aicd-Sulfate Alteration Zone of the Ogmaesan-Seongsan Ore Deposits in Haenam Area, Korea (해남 옥매산-성산광산 Acid-Sulfate 변질대에서 금 함량에 관한 연구)

  • Yoon, Chung-Han
    • Economic and Environmental Geology
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    • v.26 no.2
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    • pp.155-166
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    • 1993
  • Gold contents with major and trace elements have been determined in 67 fresh igneous and altered wall rocks in the acid-sulfate alteration zone of the Ogmaesan-Seongsan pyrophyllite deposits in the Haenam area of the south-western part of Korean peninsula. The results are as follows; (1) Li contents have a tendency to show high value in dickite and altered rocks with dickite, while As, Mo and Sb contents have tendencies to show high values in alunite vein and silicified zone. F contents are higher in the altered rocks compared to fresh rocks. (2) Gold contents are enriched in alunite vein and silicified zone of the Seongsan deposit, but depleted in dickite and altered rock with dickite. Gold contents are especially concentrated in fault or conjunction area of two faults. (3) Gold contents are higher values in the mineral assemblages of alunite-quartz-pyrite and alteration zone of the Seongsan deposit among the studied deposits. (4) Gold contents in samples of silicified zones tend to show positive correlations with Ag, As, Co, Hg, Sb and V content, but negative correlations with Y and Zr contents, while on the other gold contents of silicified tuffs tend to show positive correlations with Hg and Sb contents. Therefore it is important to survey alunite vein and silicified zone at the conjunction of faults, and to analyze pathfinder elements such as Ag, As, Hg and Sb for geological and geochemical exploration of gold in the studied deposits.

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Geochemistry of the Country Rock of Eosangcheon Manganese Deposit (어상천망간광산 모암의 지구화학)

  • Lee, Jae Yeong;Hwang, Duk Hwan
    • Economic and Environmental Geology
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    • v.17 no.1
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    • pp.17-34
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    • 1984
  • The Ordovician limestone and dolomite was mineralized by the intrusion of quartz porphyry to form hydrothermal ore deposit along the fault shear zone, which trends $N30^{\circ}-40^{\circ}W$ dipping $60^{\circ}-70^{\circ}SW$. The primary manganese carbonates in the upper part of the deposit were oxidized to form supergene manganese ore deposits. The quartz porphyry is plotted mainly in granite region of the triangular diagram of normative composition. The granite phase contains more copper and lead, but less zinc, nickel and chromium than the granodiorite phase which occupies the northwestern part of the quartz porphyry. The content of copper, lead, zinc, nickel and chromium in the quartz porphyry is lower compared with the granitic rocks from the copper province in the Gyeongsang basin. But the granitic rocks from the lead-zinc province has lower content of copper and nickel than the quartz porphyry. The primary distribution pattern of trace elements in the country rock of limestone and dolomite has close relation with the hydrothermal mineralization, showing anomalous or high content near the fault shear zone. The secondary distribution pattern of trace elements in soils shows close relation with the solubility of the carbonates of the elements under weathering condition.

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Avoidance of Internal Resonances in Hemispherical Resonator Assemblies from Fused Quartz Connected by Indium Solder

  • Sarapuloff, Sergii A.;Rhee, Huinam;Park, Sang-Jin
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2013.04a
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    • pp.835-841
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    • 2013
  • Modern solid-state gyroscopes (HRG) with hemispherical resonators from high-purity quartz glass and special surface superfinishing and ultrathin gold coating become the best instruments for precise-grade inertial reference units (IRU) targeting long-term space missions. Designing of these sensors could be a notable contribution into development of Korea as a space nation. In participial, 40mm diameter thin-shell resonator from high-purity fused quartz, fabricated as a single-piece with its supporting stem has been designed, machined, etched, tuned, tested, and delivered by STM Co. (ATS of Ukraine) several years ago; an extremely-high Q-factor (upto 10~20 millions) has been shown. Understanding of the best way how to match such a unique sensor with inner glass assembly of the gyro means how to use the high potential in a maximal extent; and this has become the urgent task. Inner quartz glass assembly has a very thin indium (In) layer soldered the resonator and its silica base (case), but effects of internal resonances between operational modal pair of the shell-cup and its side (parasitic) modes can notable degrade the potential of the sensor as a whole, instead of so low level of resonator's intrinsic losses. Unfortunately, there are special combinations of dimensions of the parts (so-called, "resonant sizes"), when intensive losses of energy occurs. The authors proposed to use the length of stem's fixture as an additional design parameter to avoid such cases. So-called, a cyclic scheme of finite element method (FEM) and ANSYS software were employed to estimate different combinations of gyro assembly parameters. This variant has no mismatches of numerical origin due to FEM's discrete mesh. The optimum length and dangerous "resonant lengths" have been found. The special attention has been paid to analyses of 3D effects in a cup-stem transient zone, including determination of a difference between the positions of geometrical Pole of the resonant hemisphere and of its "dynamical Pole", i.e., its real zone of oscillation node. Boundary effects between the shell (cup) and 3D short "beams" (inner and outer stems) have been ranged. The results of the numerical experiments have been compared with the classic model of a quasi-hemispherical shell band with inextensional midsurface, and the solution using Rayleigh's functions of the $1^{st}$ and $2^{nd}$ kinds. To guarantee the truth of the recommended sizes to a designer of the real device, the analytical and FEM results have been compared with experimental data for a party of real resonators. The consistency of the results obtained by different means has been shown with errors less than 5%. The results notably differ from the data published earlier by different researchers.

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Study on Constituent Minerals and Illitization Characteristics of Yeongdong Illite Ore (영동 일라이트 광체의 구성광물 및 일라이트화 특성 연구)

  • EunJi Baek;Yu Na Lee;Byeongyong Yu;Dongbok Shin;Youngseuk Keehm;Sun Young Park;Hyun Na Kim
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.1
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    • pp.41-54
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    • 2023
  • Illite is a common mineral that forms readily from feldspar and mica via hydrothermal alteration and exhibits various characteristics depending on the degree of hydrothermal alteration. To ensure continued mining of high-quality illite ore, it is crucial to understand the illitization. Thus, this study collected ores from two illite ore deposit and their surrounding alteration zones in Yeongdong-gun, Chungcheongbuk-do, a significant source of illite in the Republic of Korea, to determine the constituent mineral contents and textural characteristics. Polarized light microscopy analyses revealed that the illite ore deposit were highly illitized with little remaining textural characteristics of the parent mica schist, and only some quartz was present. The ore zone contained illite, muscovite, quartz, and feldspar, with illitization primarily occurring around feldspar and quartz. X-ray diffraction analyses identified that the content of illite/muscovite was approximately 50-75 wt.%, with a maximum of 75 wt.%. Additionally, X-ray fluorescence analyses indicated a linear increase in K2O content with increasing illite content, showing the highest correlation among the major components analyzed. It is suggested that the illite in the Yeongdong area results from feldspar and quartz alteration by hydrothermal fluids along the fault, with illitization of feldspar occurring before that of quartz. The results of this study are expected to contribute to the development of high-quality illite ore deposit in Yeongdong, Chungcheongbuk-do.