• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.337-347
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• 2006

Papers made from unbleached and bleached bagasse chemimechanical pulp were chemically modified by acetylation. The effects of irradiation on unbleached and bleached also reduced papers of bagasse chemimechanical pulp before and after acetylation were investigated in this study. Chemimechanical pulp was prepared from bagasse and then bleached with hydrogen peroxide. Unbleached and hydrogen bleached pulps were reduced by Sodium borohydride in different procedures. Paper sheets were prepared from pulps and then acetylated using a technical grade of acetic anhydride. Accelerated photo-aging was run on the samples using fluorescent lamps to verify photo-stability of paper sheets before and after pretreatments. Brightness reversion (as Post-color number) and other optical properties of the paper sheets were measured. Efficient inhibition of photo-yellowing of papers made from bagasse CMP was achieved by acetylation. The acetylated unbleached CMP was noticeably photo-bleached during irradiation. Sodium borohydride reduction followed by acetylation had the same effect as acetylation alone at the same degree of reaction time and reductive treatment did not affect the yellowing rate to any great extent. The pre-reduced, acetylated unbleached papers were, however, not brightened during irradiation. Calculation done by Kubelka-Munk equation showed that reductive treatment had little effect in reducing the photo-yellowing of paper made from CMP pulp; a small stabilization effect was observed in the case of bleached CMP, while unbleached CMP was slightly more prone to discolor in the later phase of photo-reversion. The improved stability towards light may was closely related to the decrease in the phenolic hydroxyl content as a result of blocking by acetyl groups during treatment with acetic anhydride. The results support the hypothesis that phenolic hydroxyl has an important role in the process of photo-reversion of high-yield pulps. The results obtained in this study demonstrate that the acetylation of paper manufactured from peroxide bleached Bagasse CMP significantly retards light-induced discoloration. The inhibition of yellowing is connected with a decrease in the phenolic hydroxyl content of both unbleached and peroxide bleached papers.

• Journal of the Korean Wood Science and Technology
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• v.4 no.1
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• pp.21-27
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• 1976

This study was carried out in order to obtain the effect of active alkali concentration. Sulfidity 25%, maximum temperature 170$^{\circ}C$, cooking time 3hrs., liquor to wood ratio 5 : 1 in the kraft cooking conditions were maintained. Active alkali concentration were varied at intervals of 3% between 12% and 24%. The rates of de lignification increased with an increase in active alkali concentration and beatability, brightness, and strength of pulp also improved. The total pulp yield trand to decrease with an increase of active alkali concentration. The maximum screened pulp yield were obtained between 18% and 21% A.A.. Therefore, the optimum active alkali concentration was 18~21%.

• Journal of Korean Society of Forest Science
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• v.53 no.1
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• pp.44-55
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• 1981

Neutral sulfite precooked fir chips were refined in the Asplund Laboratory Defibrator at various temperature ($20^{\circ}C$, $120^{\circ}C$ and $180^{\circ}C$). The effects of refining temperatures on the physical property and morphological structure of the resulting pulps were discussed. Yields of precooked chips (84%, 92% and 100%) and refining temperature affected remarkably the yield of refined pulp, its beatability, sheet strength and morhphological characteristics. Pulp yield and beatability decreased with increasing refining temperature. Fiber surface of unbeaten pulp from precooked chips of 84% yield was to some extent covered by the secondary wall, while that of the pulp form precooked yield of 92% by the compound middle lamella. In the case of uncooked chips, fibers were damaged heavily, and the exposed fiber surface resulted from the equal amount of the secondary wall and the compound middle lamella. In the case of pulps prepared from precooked chips of higher yields (92% and 100%), sheet strength increased linearly as sheet density increased. But at the same sheet density, pulp from lower precooked yield (84%) had better sheet strength after open discharge refining as compared to pressurized refining, because pulp from the former had much amounts of fines fraction of higher water retention value than the latters. And there was observed a little difference in fiber length distribution but nearly similar in its morphology with increasing refining temperature.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.1
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• pp.8-15
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• 2001

Presence of small amount of old newsprints printed with waterbased flexographic inks leads to a significant loss brightness of the deinked pulp by flotation process. Recently there has been an increased interest in employing neutral deinking processes to solve the problems associated with waterbased flexo ink. A comparative experimental study was performed to evaluate the efficiency of neutral deinking and conventional alkaline deinking for ONP furnishes contaminated with flexo ink. It was shown that neutral deinking provides significant improvements in brightness, yield and freeness as compared with alkaline deinking. Flotation efficiency was different depending upon the type of surfactants used in neutral deinking. The result of this study showed that alcohol type surfactant is superior to fatty acid type surfactant in neutral deinking efficiency.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.2
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• pp.1-7
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• 2001

Use of high yield pulp and recycled fiber as raw materials and water system closure result in higher fines content and buildup of organic and inorganic contaminants in white water. These are detrimental for the effectiveness of chemical additives including retention aids. Thus it is imperative to employ a retention systems that maintains its efficiency in closed papermaking system for reducing fresh water consumption. The performance of four different microparticle retention systems including cationic polyacrylamide (C-PAM)/bentonite, highly charged cationic starch (HCS)/silica, C-PAM/micropolymer, cationic guar gum (CGG)/silica was evaluated and compared at three different levels of papermaking system closure. Buildup of detrimental substances in a closed white water system increased cationic demand and finally reduced the performance of retention systems. Cationic starch and guar gums maintained their effectiveness in retention in closed white water systems contaminated with anionic trashes because of their structural rigidity and hydrogen bonding ability. Particularly, cationic guar gums, due its stiffness of molecular structure, appeared perform better than catinonic starch.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.41 no.5
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• pp.44-49
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• 2009

Old newspaper was deinked using commercial cellulolytic enzymes and a surfactant complex at low alkalinity. The properties of the deinked pulp(DIP) were evaluated and the suspended solids content, cationic demand, turbidity, and chemical oxygen demand(COD) of the process water were measured. The results can summarized as follows, 1. The brightness and yield of the DIP were improved using enzymatic surfactant complex deinking. 2. The amount of foaming during deinking with the enzyme surfactant complex was higher than that with synthetic surfactant deinking. However, it was not sufficient to cause process problem. 3. The pH and turbidity of the white water from deinking with the enzyme surfactant complex were similar to those of the white water from surfactant deinking. 4. The suspended solids content, cationic demand, and COD of the white water from deinking with the enzyme surfactant complex were improved compared to those of the white water from surfactant deinking.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.39 no.5
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• pp.7-11
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• 2007

Kraft pulping of Trema orientalis (Nalita) was studied in order to find kinetic data for delignification. Pulping runs were carried out in the temperature range of $160-180\;^{\circ}C$ under constant and well-defined conditions. The delignification was found to be first order with respect to residual lignin and was chemically controlled. The rate of delignification reaction was increased 1.11-1.23 for $10\;^{\circ}C$ temperature increase in the range of $160-180\;^{\circ}C$ range. A mean value of 93% of lignin was removed at the transition between bulk and residual delignification. The influence of cooking temperature on the rate constant was expressed by an Arrhenius-type equation. The obtained activation energy of the delignification reaction was 6,164 cal/mol. The transition point between bulk and residual phase was shifted to lower lignin and carbohydrate yield with the increase of temperature.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.4
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• pp.1-6
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• 2001

Today's paper industry tries to use greater amount of high yield pulp and recycled fiber and to close mill water system, which results in higher fines content and buildup of organic and inorganic contaminants in white water system. Researches are being focused to develop chemical additives that provide good retention and drainage in a closed papermaking system. A microparticle retention system consisted of cationic guar gum and anionic colloidal silica so has been developed to meet the requirements for improving machine speed and product quality. The objective of this investigation was to determine the effects of the degree of cationic guar gums, charge density and structure of anionic colloidal silica sols, and the degree of system closure on the performances of this microparticle retention system. Cationic guar gums and anionic colloidal silica sols with higher charge densities showed better retention performance. Particularly, wider maximum in retention was obtained when structure colloidal silica was used suggesting as mechanism of microparticle bridging is functioning in this system.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.5
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• pp.30-36
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• 2001

Caro's acid (persulphuric acid) has been proposed as a promising reagent used in pulping of lignocellu-losic materials. Bagass was subjected to caro's acid pulping under different pulping conditions of per acid concentration (2~8 percent), pulping temperatures (40~$60^{\circ}C$) and pulping time (120~240 min). The influence of different parameters of caro's acid pulping process on the chemical and strength properties of the produced pulps had been studied. Peracid concentration and pulping temperature are the most important variables of the pulping process. High degree of delignification and good deliberation were achieved at moderate pulping conditions in the studied range. Pulping experiments of bagasse by using caro's acid had been carried out for determination of the optimum comditions of the process. In inch case to effectively tackle the problem, a specific design of an experiment is selected depending on the goals to be achieved in the experimentation. The study could enable us to excepect the bagasse pulp properties (yield, Kappa number, DP) that be stated as function of the independent variables of caro's acid pulping process (per acid concentration, pulping temperature and pulping time).

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06b
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• pp.291-294
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• 2006

Studies of the effectiveness of anthraquinone (AQ) in kraft-AQ pulping in terms of its mechanism of mass transfer have been conducted. Experiments performed have demonstrated an 'apparent solubility' of AQ in caustic solutions of wood lignin. The adsorption behavior of AQ species was also analyzed. Anthraquinone-2-sulfonic acid (AQ-S), a water-soluble derivative of AQ, showed selective adsorption on wood. A mechanism for the transport of AQ into wood chips during kraft pulping are proposed, and some explanations for previously unexplained observations are addressed.