• E2M - 전기 전자와 첨단 소재
• /
• 제9권7호
• /
• pp.702-707
• /
• 1996

In this paper, in order to improve the withstand voltage properties of epoxy resin, IPN(interpenetrating polymer network) method was introduced and the influence was investigated. The single network structure specimen(E series), simultaneous interpenetrating polymer network specimen(EM series) and pseudo interpenetrating polymer network(EMP series) specimen were manufactured. In order to understand the internal structure properties, scanning electron microscopy method was utilized, and glass transition temperature was measured. Also, AC voltage dielectric breakdown strength, tensile strength and impact strength were measured to investigate the influence upon electrical and mechanical properties. As a result, it was confirmed that simultaneous interpenetrating polymer network specimen was the most execellent.

• Bulletin of the Korean Chemical Society
• /
• 제19권4호
• /
• pp.444-449
• /
• 1998

The kinetics of the formation of triplex $poly(dA){\cdot}[poly(dT)]_2$ from poly(dA)·poly(dT) and poly(dT) is examined by various optical spectroscopic methods, including absorption, circular and linear dichroism (LD) spectroscopy. In the pseudo first order condition, where the poly(dT) concentration is kept lower than that of duplex, the association of the poly(dT) is enhanced by the presence of ethidium; the rate constant is proportional to the amount of ethidium in the mixture. When the concentration of the duplex and the single strand is the same, a spectral change is explained by double exponential curves, indicating that at least two steps are involved, the fast association and slow rearrangement steps. In contrast to the pseudo first order kinetics, the association step in an equimolar condition is not affected by the presence of ethidium. In the rearrangement step, the magnitude of LD decreases with an increase in ethidium concentration, suggesting that the bending of polynucleotide around the intercalation site occurs in the rearrangement step.

• 한국해양공학회지
• /
• 제33권1호
• /
• pp.17-25
• /
• 2019

A numerical method is suggested for evaluating the singular integral of curved panels in the higher-order boundary element method. Two-step mapping procedures that are significantly related to the physical properties of singular behaviors were developed and illustrated. As a result, the singular behaviors were significantly alleviated, and the efficiency and robustness of the present method for tangentially and axially deformed elements were proven. However, inaccuracies and numerical instabilities of twisted elements were discovered as a result of nonlinearities.

• 공업화학
• /
• 제34권1호
• /
• pp.86-93
• /
• 2023

In this study, we investigated the various adsorption factors influencing the adsorption of heavy metal ions based on the study of the composition and physicochemical properties of scoria dispersed throughout Jeju Island. Analysis of the distribution characteristics of scoria samples collected from five areas of Jeju showed that reddish-brown-colored scoria were predominant. Analysis of scoria collected from Jeju Island showed that its mineral components are ordered as follows: SiO₂ > Al₂O₃ > Fe₂O₃ > CaO and MgO. The experimental data did not show a linear relationship in the pseudo-first-order adsorption kinetics. In contrast, a pseudo-second-order model yielded a positive linear relationship, and this model was subsequently used. It could be concluded based on an intraparticle diffusion model indicating linear relationships that the capture of metal ions on scoria is dominated by the primary adsorption step.

• 한국정보통신학회:학술대회논문집
• /
• 한국해양정보통신학회 2000년도 추계종합학술대회
• /
• pp.180-185
• /
• 2000

본 논문에서는 주파수합성기에서 가장 큰 노이즈 Source인 VCO 및 각 단에서 발생하는 Phase Noise의 offset 주파수에 따른 변화를 예측하기위해 2303,15MHz의 주파수합성기를 설계하고 Lascari의 방법을 이용해 분석하였다. 그리고 VCO에서 발생되는 여러 중첩 형태로 된 Phase Noise중 저주파대역에서 문제가 되는 1/f Noise룰 3차 System에서 분석하였다. 3차 System에서는 해석이 복잡하므로 수학적인 분석을 통하여 1/f Noise를 예측한다는 것이 어렵지만 pseudo-damping factor의 도입으로 3차 시스템에서의 1/f Noise variance의 해석이 용이하도록 시도하였고 이를 2차 시스템과 비교하여 분석하였다.

• 한국미생물·생명공학회지
• /
• 제22권6호
• /
• pp.636-642
• /
• 1994

Essential amino acids involving in the catalytic mechanism of the $\beta$-D-xylosidase of Bacillus stearothermophilus were determined by chemical modification studies. Among various che- mical modifiers tested N-bromosuccinimide (NBS), $\rho$-hydroxymercurybenzoate (PHMB), N-ethylma- leimide, 1-[3-(di-ethylamino)-propyl]$-3-ethylcarbodi-imide (EDC), and Woodward's Reagent K(WRK)inactivated the enzyme, resulting in the residual activity of less than 20%. WRK reduced the enzyme activity by modifying carboxylic amino acids, and the inactivation reacion proceeded in the form of pseudo-first-order kinetics. The double-lagarithmic plot of the observed pseudo-first- order rate constant against the modifier concentration yielded a reaction order of 2, indicating that two carboxylic amino acids were essential for the enzyme activity. The $\beta$-D-xylosidase was also inactivated by N-ethylmaleimide which specifically modified a cysteine residue with a reaction order of 1, implying that one cysteine residue was important for the enzyme activity. Xylobiose protected the enzyme against inactivation by WRK and N-ethylmaleimide, revealing that carboxylic amino acids and a cysteine residue were present at the substrate-binding site of the enzyme molecule.

• 대한기계학회논문집A
• /
• 제34권6호
• /
• pp.667-673
• /
• 2010

본 논문은 의사-임피던스 모델을 이용하여 2족보행로봇이 비평탄면에서 보행하는 제어기법을 제안한다. 의사-임피던스 모델은 인간이 보행 시, 발바닥이 지면과 순응하는 동작을 모사하였다. 지면과 접촉하면서 인간의 발바닥은 2가지 보행상태를 갖게 된다. 첫 번째 상태에서는 지면과 순응하기 위해 노력이나 의도적인 토크를 가하는 것이 아니라 수동적인 모션으로 순응하게 된다. 두 번째 상태에서는 지면과 접촉한 후, 적절한 토크를 유지하여 인간의 몸이 보행을 지속할 수 있게끔 유도하며 이를 하중이동단계라고 한다. 이러한 과정이 안정적으로 로봇의 보행을 유지할 수 있음을 12자유도의 2족보행로봇과 6축의 힘을 가지는 환경모델을 반영한 시뮬레이션을 통해 보여준다. 이러한 시뮬레이션결과가 제안된 의사-임피던스 모델이 효과적임을 보여준다.

• 공업화학
• /
• 제26권2호
• /
• pp.210-216
• /
• 2015

석탄계 입상 활성탄을 사용하여 수용액으로부터 brilliant blue FCF 염료의 흡착에 대해 조사하였다. 회분식 실험은 흡착제의 양, 초기농도와 접촉시간과 온도를 흡착변수로 사용하여 수행하였다. 흡착평형자료는 Langmuir, Freundlich 및 Temkin 식을 사용하여 해석한 결과 Freundlich 식이 가장 좋은 일치도를 나타냈다. 평가된 Freundlich 상수(1/n = 0.129~0.212)로부터 이 흡착공정이 적절한 처리방법이 될 수 있음을 알았다. 흡착속도실험자료를 유사일차 및 유사이차 반응속도식에 적용해 본 결과는 유사이차반응속도식에 잘 맞는 것으로 나타났다. 음수값의 Gibbs 자유에너지(-4.81~-10.33 kJ/mol)와 양수값의 엔탈피(+78.59 kJ/mol)는 흡착이 자발적이고 흡열공정으로 진행된다는 것을 나타냈다.

• Membrane and Water Treatment
• /
• 제8권3호
• /
• pp.259-277
• /
• 2017

Adsorption is a widely used technique for the removal of dyes from wastewaters by variety of adsorbents. In this work, the main focus is on the potential assessment of anion exchange membrane for the removal of different dyes using batch system and investigation of experimental data by applying various kinetic and thermodynamic models. The removal of anionic dyes i.e., Eosin-B, Eriochrome Black-T and Congo Red by anion exchange membrane BII from aqueous solution was carried out and effect of various parameters such as contact time, membrane dosage, temperature and ionic strength on the percentage removal of anionic dyes was studied. The experimental data was assessed by kinetic models namely pseudo-first-order, pseudo-second-order, Elovich liquid film diffusion, Bangham and the modified Freundlich models equation have been used to analyze the experimental data. These results indicate that the adsorption of these anionic dyes on BII follows pseudo-second-order kinetics with maximum values of regression coefficient (0.992-0.998) for all the systems. The adsorption of dyes was more suitable to be controlled by a liquid film diffusion mechanism. The adsorptive removal of dye Eosin-B and Eriochrome Black-T were decreased with temperature and thermodynamic parameters such as free energy (${\Delta}G^o$), enthalpy (${\Delta}H^o$) and entropy (${\Delta}S^o$) for adsorption of dyes on membrane BII were calculated at 298 K, 308 K and 318 K. The values of enthalpy and entropy were negative for EB and EBT representing that the adsorption of these dyes on BII is physiosorptive and exothermic in nature. Whereas the positive values of enthalpy and entropy for CR adsorption on BII, indicating that its adsorption is endothermic and spontaneous in nature. It is evident from this study that anion exchange membrane has shown good potential for the removal of dyes from aqueous solution and it can be used as adsorbent for dues removal on commercial levels.

• 청정기술
• /
• 제17권2호
• /
• pp.97-102
• /
• 2011

입상활성탄에 의한 아마란스 염료의 흡착특성을 회분식 실험을 통해 조사하였다. 아마란스 염료의 흡착동력학적 연구는 298, 308, 318 K에서 초기농도 100, 200, 300 mg/L의 수용액을 가지고 수행하였다. 입상활성탄에 의한 아마란스 염료의 흡착 평형관계는 298K에서 Langmuir 등온식이 잘 적용되었다. 유사일차반응속도식과 유사이차반응속도식을 사용하여 동력학 실험값을 평가한 결과, 유사이차반응속도식이 더 잘 맞았으며, 속도상수($k_2$) 값은 아마란스 초기농도 100, 200, 300 mg/L 에 대해 각각 0.1076, 0.0531 및 0.0309 g/$mg{\cdot}h$로 조사되었다. 활성화에너지, 표준엔탈피, 표준엔트로피 및 표준자유에너지를 평가하였다. 조사된 표준자유에너지값은 초기농도 200 mg/L 에서 -5.08 ~ -8.10 kJ/mol로 자발적인 공정임을 알 수 있었다. 엔탈피변화량이 양의 값인 38.89 kJ/mol을 나타내어 활성탄에 대한 아마란스 염료의 흡착이 흡열반응으로 일어난다는 것을 알 수 있었다.