• Analytical Science and Technology
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• v.8 no.4
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• pp.723-730
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• 1995

Cyclic voltammetry and in situ STM were employed to examine the interfacial structures of a Pt(111) electrode in 0.1 mM KCN (pH9.5) and 0.1 mM KSCN (pH7) solutions. In situ STM atomic resolution revealed well ordered (2${\surd}$3${\times}$2${\surd}$3)$R30^{\circ}$-6CN and ($2{\times}2$)-2SCN structures within the double layer charging region. Six CN adsorbates formed a hollow hexagon, which embraced a coadsorbed $K^+$ cation. In contrast, the coadsorbed $K^+$ cations on the SCN covered Pt(111) were poorly ordered, despite adsorbed SCN formed a long range ordered ($2{\times}2$)-2SCN adlattice. In situ STM revealed the pronounced influence of potential in controlling the structures of compact layers at the proximity of a Pt electrode. Cathodic polarization facilitated the replacement of the coadsorbed cations by protons.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.2
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• pp.151-156
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• 2007

Solar cell and nanofiltration membrane were utilized in a system of enzymatic hydrogen production through light-sensitized photoanode, which resembles photoelectrochemical(PEC) configuration. Solar cell uses no additional light energy to increase energy for electrons to reduce protons and for holes to oxidize water to oxygen, and nanofiltration membrane replaces a salt bridge successfully with increased ion transport capability. With this system configuration, optimized amount of enzyme(10.98 unit), and an anodized tubular $TiO_2$ electrode($5^{\circ}C$/1 hr in 0.5 wt% HF-$650^{\circ}C$/5 hr) hydrogen evolved at a rate of ca. $43\;{\mu}mol/(cm^2{\times}hr)$ in a cathodic compartment and oxygen generated at a rate of ca. $20\;{\mu}mol/(cm^2{\times}hr)$ in an anodic compartment. The stoichiometric evolution of gases indicated that water was splitted in the system.

• Korean Journal of Materials Research
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• v.28 no.5
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• pp.308-314
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• 2018

Among the fuel cell electrolyte candidates in the intermediate temperature range, glass materials show stable physical properties and are also expected to have higher ion conductivity than crystalline materials. In particular, phosphate glass has a high mobility of protons since such a structure maintains a hydrogen bond network that leads to high proton conductivity. Recently, defects like volatilization of phosphorus and destruction of the bonding structure have remarkably improved with introduction of cations, such as Zr4+ and Nb5+, into phosphate. In particular, niobium has proton conductivity on the surface because of higher surface acidity. It can also retain phosphorus content during heat treatment and improve chemical stability by bonding with phosphorus. In this study, we fabricate niobium phosphate glass thin films through sol-gel processing, and we report the chemical stability and electrical properties. The existence of the hydroxyl group in the phosphate is confirmed and found to be preserved at the intermediate temperature region of $150-450^{\circ}C$.

• Macromolecular Research
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• v.14 no.1
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• pp.101-106
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• 2006

The transport of reactant gas, electrons and protons at the three phase interfaces in the catalytic layers of membrane electrode assemblies (MEAs) in proton exchange, membrane fuel cells (PEMFCs) must be optimized to provide efficient transport to and from the electrochemical reactions in the solid polymer electrolyte. The aim of reducing proton transport loss in the catalytic layer by increasing the volume of the conducting medium can be achieved by filling the voids in the layer with small-sized electrolytes, such as dendrimers. Generation 1.5 and 3.5 polyamidoamine (PAMAM) dendrimer electrolytes are well-controlled, nanometer-sized materials with many peripheral ionic exchange, -COOH groups and were used for this purpose in this study. The electrochemically active surface area of the deposited catalyst material was also investigated using cyclic voltammetry, and by analyzing the Pt-H oxidation peak. The performances of the fuel cells with added PAMAM dendrimers were found to be comparable to that of a fuel cell using MEA, although the Pt utilization was reduced by the adsorption of the dendrimers to the catalytic layer.

• Nuclear Engineering and Technology
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• v.38 no.4
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• pp.327-342
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• 2006

Radiation therapy is an important part of cancer treatment in which cancer patients are treated using high-energy radiation such as x-rays, gamma rays, electrons, protons, and neutrons. Currently, about half of all cancer patients receive radiation treatment during their whole cancer care process. The goal of radiation therapy is to deliver the necessary radiation dose to cancer cells while minimizing dose to surrounding normal tissues. Success of radiation therapy highly relies on how accurately 1) identifies the target and 2) aim radiation beam to the target. Both tasks are strongly dependent of imaging technology and many imaging modalities have been applied for radiation therapy such as CT (Computed Tomography), MRI (Magnetic Resonant Image), and PET (Positron Emission Tomogaphy). Recently, many researchers have given significant amount of effort to develop and improve imaging techniques for radiation therapy to enhance the overall quality of patient care. For example, advances in medical imaging technology have initiated the development of the state of the art radiation therapy techniques such as intensity modulated radiation therapy (IMRT), gated radiation therapy, tomotherapy, and image guided radiation therapy (IGRT). Capability of determining the local tumor volume and location of the tumor has been significantly improved by applying single or multi-modality imaging fur static or dynamic target. The use of multi-modality imaging provides a more reliable tumor volume, eventually leading to a better definitive local control. Image registration technique is essential to fuse two different image modalities and has been In significant improvement. Imaging equipments and their common applications that are in active use and/or under development in radiation therapy are reviewed.

• Journal of the Korean Chemical Society
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• v.38 no.3
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• pp.179-185
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• 1994

The Raman stretching frequency of nitrile group was affected by change of solvents and its in concentration in same solvent. In the case of acetonitrile, nitrile group stretching frequencies were observed in the region of 2247.3∼2254.9 cm-1 with various solvents. While in benzonitrile, they were found in the region of 2226.1∼2230.3$ cm^{-1}. With the addition of water in acetonitrile,νC≡N was shifted to high frequency from 2250.1 cm^{-1} in pure acetonitrile to 2257.7 cm^{-1} in 90% water forwhich had with higher volume % of water caused higher hydrogen-bonded equilibrium between methyl protons and water. The νC≡N frequency for nitrile group was shifted to high frequency by solvent inductive effect with the increasing mixed solvent (CHCl_3/CCl_4)$mole% ratio.

• Nuclear Engineering and Technology
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• v.37 no.3
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• pp.279-286
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• 2005

A prototype of a relativistic proton generation system, based on laser-induced plasma interaction, has been designed and fabricated. The system is composed of three major parts: a fs TW laser; a target chamber, including targets and controls; and a diagnostic system for charged particles and lasers. An Offner-type pulse stretcher for chirped pulse amplification (CPA) and eight pass pre-amplifier are installed. The main amplifier will be integrated with a new pumping laser. The design values of the laser at the first stage are 1 TW in power and 50 fs in pulse duration. We expect to generate protons with their maximum energy of approximately 3 MeV and the flux of at least $10^6$ per pulse using a 10 $\mu$m Al target. A prototype target chamber with eight 8-inch flanges, including target mounts, has been designed and fabricated. For laser diagnostics, an adaptive optics based on the Shack-Hartmann type, beam monitoring, and alignment system are all under development. For a charged particle, CR-39 detectors, a Thomson parabola spectrometer, and Si charged-particle detectors will be used for the density profile and energy spectrum. In this paper, we present the preliminary design for laser-induced proton generation. We also present plans for future work, as well as theoretical simulations.

• Environmental Engineering Research
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• v.22 no.2
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• pp.149-156
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• 2017

Chromium(III) recovery from tanning wastewater by means of adsorption on activated carbon and elution with sulfuric acid was studied. Tests were carried out at laboratory scale on an effluent of industrial origin. Initially, proteinaceous materials and fats were separated via sieving followed by ultrafiltration. The chemical composition of the sample thus precleansed was (in g/L): 1.09 chromium(III); 10.36 sulfate; 11.10 sodium; 9.57 chloride; 0.40 proteinaceous materials; and 0.20 fats. Adsorptions were made at 20, 30, and $40^{\circ}C$, establishing what temperature favored chromium(III) uptake. At $40^{\circ}C$, the maximum cation fixation was 40.2 mg/g, and the lowest content in an equilibrium solution was 3.9 mg/L. As regards sodium, chloride, and sulfate, the concentrations before and after the treatment were similar. Likewise, it was found that protons were also retained, modifying the pH of the liquid medium. Adsorption isotherms were analyzed using the Langmuir, Temkin, and Freundlich models. Finally, the extraction of the adsorbed tanning agent with sulfuric acid was evaluated. A recovery of 96.5% was achieved with 0.9 N at $70^{\circ}C$ (13.23 g/L $Cr^{3+}$; 42.98 g/L sulfate; and 0.40 g/L NaCl).

• The Bulletin of The Korean Astronomical Society
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• v.41 no.1
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• pp.47.2-47.2
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• 2016

The protons and helium ions in the solar wind are observed to possess anisotropic temperature profiles. The anisotropy appears to be limited by various marginal instability conditions. One of the efficient methods to investigate the global dynamics and distribution of various temperature anisotropies in the large-scale solar wind models may be that based upon the macroscopic quasi-linear approach. The present paper investigates the proton and helium ion anisotropy instabilities on the basis of comparison between the quasi-linear theory versus particle-in-cell simulation. It is found that the overall dynamical development of the particle temperatures is quite accurately reproduced by the macroscopic quasi-linear scheme. The wave energy development in time, however, shows somewhat less restrictive comparisons, indicating that while the quasi-linear method is acceptable for the particle dynamics, the wave analysis probably requires higher-order physics, such as wave-wave coupling or nonlinear wave-particle interaction. We carried out comparative studies of proton firehose instability, aperiodic ordinary mode instability, and helium ion anisotropy instability. It was found that the agreement between QL theory and PIC simulation is rather good. It means that the quasilinear approximation enjoys only a limited range of validity, especially for the wave dynamics and for the relatively high-beta regime.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.1
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• pp.29-29
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• 2014

A fundamental problem in space physics is to explain the origin of energetic charged particles in space close to the Earth and the significant temporal variations of their flux. The particles are primarily electrons and protons although energetic heavy ions such as O+ are sometimes non-negligible. By "energetic" we mean a rather broad energy range of particles from a few tens of keV to well above MeV. Drastic variations of the particle fluxes (by >3 orders of magnitude) occur over both a short time scale like a few minutes and a long time scale like the 11-year sunspot cycle. In this talk I will focus on relativistic energy electrons (~MeV) trapped within the Earth's magnetosphere. They are a primary element of the space weather since they can cause damage to satellites, so often called "killer electrons". Considering that the source particles in both the solar wind and the ionosphere are relatively cold (~eV), the quasi-permanent existence of these very energetic particles close to the Earth has been a surprise to space physicists for decades. Complex electromagnetic processes such as wave-particle interactions within the magnetosphere are believed to play a major role in generating these killer electrons. While detailed physics remains an active research area, for this lecture I will introduce a synthesized picture of how solar activities are related to wave-particle interaction physics inside the magnetosphere. This can be applied to other astrophysical systems.