• Title/Summary/Keyword: protective film

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Effect of pre-treatment of AZ91 Mg alloy in HF solution on PEO film formation behavior (AZ91 마그네슘 합금의 PEO 피막 형성거동에 미치는 HF전처리의 영향)

  • Kwon, Duyoung;Song, Pung-Keun;Moon, Sungmo
    • Journal of Surface Science and Engineering
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    • v.54 no.4
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    • pp.184-193
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    • 2021
  • This study demonstrates formation behavior and morphological changes of PEO (Plasma Electrolytic Oxidation) films on AZ91 Mg alloy as a function of pre-treatment time in 1 M HF solution at 25 ± 1 ℃. The electrochemical behavior and morphological changes of AZ91 Mg alloy in the pre-treatment solution were also investigated with pre-treatment time. The PEO films were formed on the pre-treated AZ91 Mg alloy specimen by the application of anodic current 100 mA/cm2 of 300 Hz AC in 0.1 M NaOH + 0.4 M Na2SiO3 solution. Vigorous generation of hydrogen bubbles were observed upon immersion in the pre-treatment solution and its generation rate decreased with immersion time. It was also found that 𝛽-Mg17Al12 in AZ91 Mg alloy was dissolved and a protective thin film of MgF2 was formed on the AZ91 Mg alloy surface during the pre-treatment process in the 1 M HF solution. PEO film did not grow on the AZ91 Mg alloy specimen when the surface was not pre-treated and irregular PEO films with nodular defects were formed for the specimens pre-treated up to 1 min. Uniform PEO films were formed when the AZ91 Mg alloy specimen was pre-treated more than 3 min. The growth rate of PEO films on AZ91 Mg alloy increased significantly with increasing pre-treatment time.

The antiwear performance of several organic phosphates from the aspect of interaction between polyolester base oil and additive (Polyolester base oils과의 상호작용에 의한 Organic Phosphates계 내하중첨가제의 마모방지 성능)

  • ;Masabumi Masuko
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.06a
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    • pp.189-194
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    • 1999
  • The antiwear performance of several organic phosphates ,such as tricrecylphosphate(TCP), tributylphosphate(TBP), diphenylhydrogenphosphate(DPHP) ,dissolved in polyol ester based oils is studied. These organic phosphates are well known for antiwear additive for lubricating oil that produce reacted surface protective film. These antiwear additives can drastically reduce wear with their concentration increasing, because the amount of additive adsorbed on metal sur(ace increases. But in the higher concentration region, the wear is increased by excessive and corrosive reaction of the metal surface with these additives. That is to say, there is an optimum concentration for minimum wear. The optimum concentration was different with the kinds of base oils and additives. Different polyolesters showed different optimum concentrations of the additive. The order of optimum concentration among the polyolesters was different with different phosphates. The order of the optimum concentration is shown that the effect of the concentration of additives on the antiwear performance. It can be explained by the interaction between additives and base oils using the solubility parameter.

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The role of mass transfer layer on the tribological characteristics of silver-coated surfaces

  • Yang, Seung-Ho;Kong, Ho-Sung;Yoon, Eui-Sung;Kim, Dae-Eun
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.153-154
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    • 2002
  • Wear map of silver coatings on AISI 52100 has been constructed to delineate the wear transition behavior with the change in operating conditions in various environments. Three main regimes were clearly identified: (i) elastic/plastic deformation of silver coating without failure. (ii) mild wear regime after initial failure of silver coating and (iii) severe wear regime. In the mild wear regime, the contact surfaces were covered with transfer layers of agglomerated wear particles. The transfer layer acted as a protective layer and resulted in low friction even after the initial failure of the coated films, whose characteristics were strongly dependent on both the operating and environmental conditions. Also, the existence of the critical sliding speed, above which no transfer layer was able to form, was discussed in the work.

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APPLICATION OF RERFLUOROPOLYMETHYLISOPROPYLETHER TO HAND CARE CREAM USING ABSORPTION AND DISPERSION

  • Ahn, Baek-Sun;Sliin, Dong-Ug;Jo, Pan-Gu;Kim, Sang-Je;Lim, Ho-Soon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.75-81
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    • 1997
  • It has been used that fluorinated compounds could be applied to cosmetic products. It is that fluorinated conpounds are hydrophobicity and lipophobicity. These fluorinated compounds are reported to form a highly protective and effective film against most aggressive chemical and physical agents. PerfluropolymethyoisopropylEther has homophobicity and are colorless, odorless, tasteless and non-greasy. In this we made a success to formulate the new type of hand care cream using PFPE. PFPE are suitable thickness and chemical inertness to skin. The reason that we select PFPE for this investigation. We developed the new type hand care cream by adsorption and dispersion of PFPE. There are very stable dispersion and highly moisture diffusion control. And these characteristics were verified by actual consumer test.

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Application of Perfluoropolymethlisopropyl Ether to Long Wearing Lipstick

  • Sang-Je Kim;Don
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.152-160
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    • 1997
  • It has been used that fluorinated compounds could be applied to Make-up products. It is that fluorinated compounds are hydrophobicity, lipophobicity and homophobicity. These fluorinated compounds are reported to form a highly protective and effective film against most aggressive chemical and physical agents. In this study we maed a success to formulate the new type of lipstic using perfluoropolymethylisopropylether with low molecular weight which is long wearing and comfortable to use. This PPIE was adsorbed more than 90% in this experiment and formed the well-balanced gel networks even if the selected PPIE is 100% volatile at room temperature. On the basis of the adsorption of PPIE, we developed the new type lipstick, which was highly-lip feeling and had long wearing and non coloration. And these characteristics were verified by actual consumer test.

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Dosimetry according to the Object Thickness (피사체(被射體)두께에 따른 선량분포(線量分布))

  • Lee, Sang-Suk;Park, Sung-Ock
    • Journal of radiological science and technology
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    • v.2 no.1
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    • pp.85-88
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    • 1979
  • When X-radiation passes through the human body; some is transmitted some is truly absorbed, and some is scattered. In diagnostic radiography, scattered radiation can reach the film if no protective measures are taken. This scattered ray increased density which not necessary for image formation. We studied about absorbtion, scattered ray and the way of get rid of scatter ray according to the x-ray tube kilovoltage and obtained results as follow; 1. Absorbtion ray increased proportion to KVP. 2. Scattered ray increased at high KVP and thick object. 3. Secondary radiation of the primary increased at high KVP and thick object. 4. Remove .ate of scattered ray decreased at thick object and increase at low KVP make use of 6:1 grid ratio

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Effect of MgO Deposition Condition on the Discharge Characteristic of AC-PDP (AC-PDP에서 MgO 증착조건에 따른 패널특성 연구)

  • Jeong, Joo-Young;Cho, Sung-Yong;Lee, Don-Kyu;Lee, Hae-June;Lee, Ho-Jun;Park, Chung-Hoo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.8
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    • pp.1566-1571
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    • 2009
  • The discharge electrodes in ac PDP are coated with dielectric layer, and transparent MgO thin films are deposited on the dielectric layer. The main role of the MgO thin films in ac PDP is to protect the dielectric layer from sputtering by ion bombardment in the glow-discharge plasma. An additional important role of the MgO thin film is the high secondary electron emission coefficient which leads the low firing voltage and low cost of the PDP. In this paper, we investigated the relations of the crystal orientation about deposition thickness, deposition rate, temperature of substrate, and distance between the MgO tablet and the substrate. Additionally, we investigated the discharge characteristics of the AC PDP using nano-powder MgO tablet

Implementation and Performance Evaluation of Opto-Electronic OverCurrent Relay (광전자식 과전류 보호계전기의 구현 및 성능 평가)

  • Park, Byung-Seok;Ahn, Sung-Joon;Jang, Moon-Jong;Woo, Hee-Gon
    • Journal of Institute of Control, Robotics and Systems
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    • v.6 no.3
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    • pp.284-290
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    • 2000
  • The measurement of electric current using optical techniques provides a number of important practical advantages including effective isolation from high line potentials and freedom from the saturation effects observed in conventional current transformers. In this work the optical current sensor which uses thin YIG(Yittrium Ion Garnet) film as a Faraday element has been developed. We have characterized this optical current sensor and implemented it to the OOCR(Opto-electronic OverCurrent Realy) Performance of the OOCR shows the possibility of replacing the present overcurrent relays with OOCR.

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A Study on the Material Property and Application of the Si-doped MgO Layer (Si가 첨가된 MgO의 기초 물성 및 응용 연구)

  • Cho, Sung-Yong;Park, Chung-Hoo;Yu, Yun-Sik;Lee, Don-Kyu
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.12
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    • pp.2441-2445
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    • 2009
  • The effects of Si -doped MgO have been investigated in order to improve the material properties of the MgO protective layer in plasma display panels. A small amount of Si is added to the MgO pellet while the MgO layer is being deposited by using an electron-beam evaporation method. Both the surface characteristics of the protecting layer and the electro-optical properties of 4 in. test panels are investigated, such as XRD patterns, SEM images, firing and sustain voltages, secondary electron emission coefficient($\gamma$), luminance, luminous efficacy and lifetime. The firing and sustain voltage are minimized when Si concentration is 0.038%, where the luminance and luminous efficacy increase up to 17% and 26% compared with that of the pure MgO film, separately, and lifetime also shows good characteristics.

Corrosion Characteristics of hot rolled and thermo-mechanically treated steel rebar in concrete pore solution (콘크리트 기공 솔루션에서의 열간 압연 및 열 기계 처리 철근의 부식 특성)

  • Lee, Han-Seung;Singh, Jitendra Kumar
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.202-203
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    • 2018
  • Chemistry and microstructure of steel reinforcement bars play an important role to control the corrosion in concrete environments. In present study, we have chosen two different microstructure of steel rebars produced from companies and assessed their corrosion characteristics in simulated concrete pore (SCP) solution with prolonged exposure periods. Hot rolled steel rebar showed more corrosion resistance compare to thermo-mechanically treated (TMT) one. The growth of passive is greater in hot rolled (A) than TMT (B) due to orientation of microstructure. TMT steel rebar exhibit distorted microstructure with many micro cells which enhances the galvanic coupling and induce the deterioration while on the other hand hot rolled rebars exhibit fine grain boundary which responsible in growth of uniform, adherent and protective passive film resultant improved impedance was observed.

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