• 제목/요약/키워드: property change

검색결과 1,970건 처리시간 0.033초

고분자 전해질 연료전지 가스켓 및 GDL의 구조 해석 (Structural Analysis of Gasket and GDL for Enhanced Performance of PEMFC)

  • 윤진영;박정선
    • 한국항공우주학회지
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    • 제36권7호
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    • pp.642-650
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    • 2008
  • 고분자 전해질 연료전지 스택의 성능향상과 안전성 확보를 위하여 스택의 체결하중으로 인한 가스켓과 GDL의 구조적 거동을 살펴보았다. 가스켓 구조 해석의 경우 하중과 변위의 초탄성 거동을 표현하기 위하여 Mooney-Rivlin의 변형률에너지 함수를 사용하였으며, 재료물성을 구하기 위하여 단축 인장 및 등가 이축 인장 시험을 수행하였고 유한요소 해석과 비교하였다. GDL의 물성측정을 위하여 압축 하중의 변화에 따라 두께변화를 측정하였고 단위 셀을 제작하여 하중의 변화에 따른 채널의 압력차를 측정하였다. 실험 데이터를 바탕으로 채널 단면적의 변화를 계산, 유한요소 해석결과와 비교하였다.

Highly Sensitive and Transparent Pressure Sensor Using Double Layer Graphene Transferred onto Flexible Substrate

  • Chun, Sungwoo;Kim, Youngjun;Jin, Hyungki;Jung, Hyojin;Park, Wanjun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.229.2-229.2
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    • 2014
  • Graphene, an allotrope of carbon, is a two-dimensional material having a unique electro-mechanical property that shows significant change of the electrical conductance under the applied strain. In addition of the extraordinary mechanical strength [1], graphene becomes a prospective candidate for pressure sensor technology [2]. However, very few investigations have been carried out to demonstrate characteristics of graphene sensor as a device form. In this study, we demonstrate a pressure sensor using graphene double layer as an active channel to generate electrical signal as the response of the applied vertical pressure. For formation of the active channel in the pressure sensor, two single graphene layers which are grown on Cu foil (25 um thickness) by the plasma enhanced chemical vapor deposition (PECVD) are sequentially transformed to the poly-di-methyl-siloxane (PDMS) substrate. Dry and wet transfer methods are individually employed for formation of the double layer graphene. This sensor geometry results a switching characteristic which shows ~900% conductivity change in response to the application of pulsed pressure of 5 kPa whose on and off duration is 3 sec. Additionally, the functional reliability of the sensor confirms consistent behavior with a 200-cycle test.

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실리콘의 화학기계적 미세가공 특성 (Characterization of the Chemical Mechanical Micro Machining for Single Crystal Silicon)

  • 정상철;박준민;이현우;정해도
    • 한국정밀공학회지
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    • 제19권1호
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    • pp.186-195
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    • 2002
  • The mechanism of micro machining of reacted layer on silicon surface were proposed. The depth of reacted layer and the change of mechanical property were measured and analyzed. Depth of hydrated layer which is created on the surface of silicon by potassium hydrate was analyzed with SEM and XPS. The decrease of the micro victors hardness of silicon surface was shown with the increase of the concentration of potassium hydrate and the change of the dynamic friction coefficient by chemical reacted layer was measured due to the readiness of machining. The experiment of groove machining was done with 3-axis machine with constant load. With chemical mechanical micro machining the surface crack and burrs generated by both brittle and ductile micro machining were diminished. And the surface profile and groove depth was shown in accordance with the machining speed and reaction time with SEM and AFM.

AS wire의 생산성에 미치는 클래딩속도와 예열온도의 영향 (Effects of cladding speed and preheating temperature on the productivity of AS wire)

  • 윤종서;이상헌
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 추계학술대회 논문집
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    • pp.373-376
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    • 2005
  • In recent years, there has been a growing need fur productivity improvement of ACS wire (Aluminum clad Steel wire) In optical communication market. So, it is necessary to improve the production speed and following quality of ACS wire to reduce the unit cost of the products. In this study, the pre-heating temperature and cladding speed is chosen as the factors can influence the mechanical and metallurgical properties during cladding, and the changing behavior of mechanical property and microstructure by controlling above two factors are investigated. And the bearing length and approach angle in cladding die are selected as the important elements for designing optimum die enabling high speed cladding. So we carried out FE(Finite Element) analysis using the above two elements as variables. This paper aims to understand the change of mechanical properties and microstructure according to the change of each factor during cladding and suggest the optimized cladding condition to get the best quality of OPGW. And also we would like to introduce the optimum die structure that enables high-speed cladding.

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그라포일 분리판을 이용한 고분자 전해질 연료전지의 운전 조건에 관한 연구 (Operating Conditions of Proton Exchange Membrane Fuel Cell Using Grafoil$^{TM}$ as Bipolar Plates)

  • 박태현;장익황;이윤호;이주형;차석원
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.85.1-85.1
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    • 2011
  • In this study, Grafoil$^{TM}$ which has comparable electric resistance and chemical stability but is flexible, fragile, and cheap material was adopted as bipolar plates for proton exchange membrane fuel cell(PEMFC) having only one straight line flow channel. Because of its flexibility, pressurizations of cell with various pressures showed different operating characteristics compared to ordinary graphite-used PEMFC. While performances of both cells decreased as these were pressurized, investigation of ohmic and faradaic resistance by electrochemical impedance measurement indicated different tendency of change. Ohmic resistance of graphite-used cell increased with increasing pressure, which is reversed in Grafoil$^{TM}$-used cell. It is speculated that effective chemical reaction area is decreased with increasing pressure in case of graphite-used one, but because of flexible property of Grafoil$^{TM}$, gas diffusion layer in Grafoil$^{TM}$-used cell was well-activated. Different rate of change of faradaic resistances in both cells support this supposition. However, although optimum point of pressurization is found, it is required to investigate other operating conditions because of low performance compared to graphite-used cell.

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소결체와 저탄소강의 레이저용접 특성에 미치는 입열량 및 용접부 성분변화의 영향 (Influence of Heat Input and Weld Bead Composition on Welding Property in the Laser Welding between Sintered Segment and Mild Steel Shank)

  • 정우광;조남준;김성욱;이창희;김승대;이주형;박화수
    • 한국재료학회지
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    • 제14권6호
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    • pp.425-431
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    • 2004
  • A laser welding was applied between sintered tip of Fe-Co-W and low carbon steel shank for the diamond saw blade. The welding characteristics and formation of defects were investigated carefully for the weld fusion zone in different welding condition. Dendrite arm spacing in weld bead decreased with decrease of heat input. Co and W increased and Fe decreased in the weld fusion zone with increase of the heat input. The corresponding change of composition was observed with the change of beam position. The maximum and total length of crack decreased with increase of the heat input. The crack in weld bead was propagated along the dendrite boundary and was caused mainly by the segregation of constituent during the solidification.

중장비용 우레탄 도료 내후성 가속시험 (Accelerated Weathering Test of Urethane Paint for Heavy Construction Equipment)

  • 김대용;김영준
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제1권2호
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    • pp.79-93
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    • 2001
  • Recently, new aspects of paints such as a beautiful appearance, use of environmentally friendly paints, etc., in addition to the superior performance of paints have been requested for industrial paints including the paints for heavy construction equipment and others. Particularly, the quality of appearance of coating affects the sales of heavy construction equipment. And the necessity for the paints to have a superior weather-proof property without changing the luster or color even after long-time exposure to the open air is emphasized. The change in the surface color and luster of the paint due to the natural environment progresses very slowly, and it takes a long time to verify material properties when developing new paints. In order to improve such methods, weathering tests are performed in many laboratories as a test for accelerating aging of coating, and the lifetime of the products is estimated through evaluation of the weathering (environment-proof) quality of paints. However, not a great deal of research activity has been conducted up to the present time since the interrelationship between the actual results of testing and field data is different for each paint and it takes a long time to study relevant materials. Therefore, introduced in the present study is the estimation of the change in the quality of appearance of coating in the field through the accelerated aging test among the cases of improvement of the quality of appearance of the urethane paint for heavy construction equipment.

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비노출 방수층에 작용하는 정하중과 동하중 작용 후의 방수층 물성변화에 관한 연구 (A Study on the Change of Physical Capability of Waterproofing Layer after the Application of Static Load and Moving Load to a Non-Exposed Type Waterproofing Layer)

  • 선윤숙;김진성;오상근
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2007년도 춘계학술논문 발표대회
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    • pp.141-145
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    • 2007
  • The part in the structure that is most affected by changes of external temperature is the protective concrete layer that protects a waterproofing layer. Also, the waterproofing layer that is situated under or on the back of such a protective concrete layer is affected by temperature and the behavior of the protective concrete layer under the condition of consolidation or close adhesion. In particular, in many cases, the damage is serious mainly around the projection (such as a parapet), crack, and joint (expansion joint). However, there is no proper way of examining again the non-exposed waterproofing layer once it has been constructed. Therefore, there is an assessment only on the physical property of materials and the capability of the layer in construction, and there is no actual assessment in consideration of its environmental condition or the condition of the use of buildings after construction. Therefore, in order to create more pleasant buildings and to enhance the durability of structures, this study conducts research into the change of capability of non-exposed waterproofing material after the application of a static load and moving load on the waterproofing layer situated under or on the back of protective concrete.

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Fluorescence Quenching of Norfloxacin by Divalent Transition Metal Cations

  • Park, Hyoung-Ryun;Seo, Jung-Ja;Shin, Sung-Chul;Lee, Hyeong-Su;Bark, Ki-Min
    • Bulletin of the Korean Chemical Society
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    • 제28권9호
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    • pp.1573-1578
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    • 2007
  • Fluorescence quenching of norfloxacin (NOR) by Cu2+, Ni2+, Co2+ and Mn2+ was studied in water. The change in the fluorescence intensity and lifetime was measured as a function of quencher concentration at various temperatures. According to the Stern-Volmer plots, the NOR was quenched both by collisions and complex formation with the same quencher. However, the static quenching had a more important effect on the emission. Large static and dynamic quenching constants support significant ion-dipole and orbital-orbital interactions between NOR and cations. The both quenching constants by Cu2+ were the largest among quenchers. Also, quenching mechanism of Cu2+ was somewhat different. The change in the absorption spectra due to the quencher provided information on static quenching. The fluorescence of NOR was relatively insensitive to both the dynamic and static quenching compared with other quinolone antibiotics. This property can be explained by the twisted intramolecular charge transfer.

자외선 조사가 아선약 염색 직물의 색상 및 역학적 특성에 미치는 영향 (Effect of UV Irradiation on the Color and Mechanical Properties of Catechu Dyed Fabrics)

  • 남기연;이정순
    • 한국생활과학회지
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    • 제20권5호
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    • pp.1009-1023
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    • 2011
  • This study was carried out to investigate the variations of catechu dyed fabrics under UV irradiation. Catechu dyed cotton and silk fabrics mordanted with Fe and Cu were irradiated with UV under dry and wet conditions, and then were evaluated on color changes and mechanical properties. Owing to UV irradiation, the K/S values of catechu dyed cotton fabrics increased until a certain amount of time but those of catechu-dyed silk fabrics increased continuously. Cu mordanting cotton fabrics showed the smallest changes due to the UV treatment, and silk fabrics mordanted with Fe showed the largest changes. Wetted fabrics were accelerated maillard browning by UV. Un-mordanted cotton fabrics treated with UV under dry conditions changed its YR color to Y, but changed its Y color to YR under wet conditions. However, mordanted cotton fabrics treated with UV didn't change their color. Dyed silk fabrics except those Fe mordanted and in wet conditions continued to keep their color after UV irradiation. Silk fabric mordanted with Fe under wet conditions changed its Y color to YR by UV irradiation. UV irradiation didn't affect the mechanical properties of catechu-dyed cotton and silk fabrics in any significant way.