• Title/Summary/Keyword: property change

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Redox Property of Transition Metal Oxides in Catalytic Oxidation (TPR/TPO 실험기법을 이용한 전이금속산화물의 산화-환원 특성 연구)

  • Kim, Young-Ho;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1161-1168
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    • 1999
  • The redox property of oxide materials of the 3rd period transition metals(Cr~Zn), V, Mo, and W was studied with temperature-programmed reduction/temperature-programmed oxidation(TPR/TPO) experiment. The peak temperatures of TPO spectra were equal to or lower than those of TPR spectra. And the peak shapes of TPO spectra were broader than those of TPR ones. The activation energies of TPR/TPO for the oxides of the 3rd period transition metals showed in the range of 33~149 kJ/mol, while for the oxides of V, Mo, and W, they showed relatively higher values. The change of activation energies of TPR/TPO with various metal oxides showed a similar trend to the change of their metal-oxygen bond strengths. The change of activation energies of o-xylene oxidation for various metal oxides was proportional to the difference (${\Delta}E_a$) between the activation energy of TPR and that of TPO. From these results, we concluded that the oxidation of o-xylene over various metal oxide catalysts follows the Mars-van Krevelen mechanism including the surface reduction-oxidation of the metal oxide itself.

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Face Recognition Evaluation of an Illumination Property of Subspace Based Feature Extractor (부분공간 기반 특징 추출기의 조명 변인에 대한 얼굴인식 성능 분석)

  • Kim, Kwang-Soo;Boo, Deok-Hee;Ahn, Jung-Ho;Kwak, Soo-Yeong;Byun, Hye-Ran
    • Journal of KIISE:Software and Applications
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    • v.34 no.7
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    • pp.681-687
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    • 2007
  • Face recognition technique is very popular for a personal information security and user identification in recent years. However, the face recognition system is very hard to be implemented due to the difficulty where change in illumination, pose and facial expression. In this paper, we consider that an illumination change causing the variety of face appearance, virtual image data is generated and added to the D-LDA which was selected as the most suitable feature extractor. A less sensitive recognition system in illumination is represented in this paper. This way that consider nature of several illumination directions generate the virtual training image data that considered an illumination effect of the directions and the change of illumination density. As result of experiences, D-LDA has a less sensitive property in an illumination through ORL, Yale University and Pohang University face database.

The Change of Magnetic Easy Axis in Ion Beam Mixed Co/Pt Multilayer

  • Kim, S.H.;Chang, G.S.;Son, J.H.;Kim, T.Y.;Chae, K.H.;Kang, S.J.;Lee, J.;Jeong, K.;Lee, Y.P.;Whang, C.N.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.162-162
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    • 2000
  • We have studied magnetic properties of Co/Pt multilayered films which have attracted great interest as high-density magneto-optical (MO) recording media due to their good MO properties. For this study, [Pt(45 )/Co(35 )]$\times$8 films were deposited with a Pt buffer layer of 60 on Si(100) substrate by alternating electron-beam evaporation in a high vacuum and were ion beam mixed by using 80keV Ar+ at 25$0^{\circ}C$. Especially, an external magnetic field was added to help changing magnetic property during ion beam mixing (IBM). The intermixing of Co and Pt layers after IBM was confirmed with Rutherford Backscattering Spectroscopy (RBS) and Transmission Electron Microscopy (TEM). The MO property of the film was measured with magneto-optical Kerr spectrometer and the change of magnetic easy axis in the film plane was observed from Ker loop data. This anomalous result might be correlated with the change of atomic structure due to the intermixing effect.

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A Study on the Elastic Property Change with Temperature in Si Materials for MEMS (MEMS용 Si 소재의 온도에 따른 탄성 특성 변화에 관한 연구)

  • Jung, Sung-Hoon;Lee, Se-Ho;Lee, Sung-Hun;Kwon, Dong-Il
    • Proceedings of the KIEE Conference
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    • 2001.11a
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    • pp.59-61
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    • 2001
  • Electrostatically actuated test devices were designed to evaluate the elastic modulus of single crystalline Si (100) materials for MEMS device. Elastic modolus was calculated from resonant frequency by applying Rayleigh's energy method. Temperature effect on elastic properties was evaluated by detecting the resonant frequency change with increasing temperature to $600^{\circ}C$. The elastic modulus was decreased with heating and then increased with cooling, but specimen with thermal cycle showed a permanent change which is lower than the initial value. This phenomenon was explained by the change of interatomic force and the formation of $SiO_2$ layer on Si. The thickness of oxide layer was estimated by considering the change of mass and stiffness, and the formation of oxide layer was observed by the SEM photograph.

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A Study on Planning Preference Property of Apartment Housing according to the Participatory Design Method through Generation (참여디자인을 통한 세대(世代)별 공동주택 평면계획 선호특성에 관한 연구)

  • Cho, Sung-Woo;Oh, Se-Gyu;Yu, Po-Sook
    • Journal of the Korean housing association
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    • v.25 no.5
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    • pp.1-10
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    • 2014
  • In the upcoming 21st century, we predict change and development in various aspects. Some fundamental causes of change in housing lifestyles such as the change in family make-up are gradually becoming more and more realistic problems as the society is shifting to the younger generation family make up refer to the rapid increase of the agedpopulation, growth of single households, the drop in the number of family members, the change in the economic situation and technology level, and change in values. The purpose of this research is to, more away from the standardized supply of housing and to approach apartment housing plans in multilateral aspects, compare and analyze the difference between the housing demands of different generations and the influence that the current housing type has on demand forecasting by case studies of Unit Living Space planning that we will utilize the participating design method in which parents and children took part in.

Application of a Large Ocean Observation Buoy in the Middle Area of the Yellow Sea (황해중부해역에서의 대형 해양관측부이의 운용)

  • Shim, Jae-Seol;Lee, Dong-Young;Kim, Sun-Jeong;Min, In-Ki;Jeong, Jin-Yong
    • Ocean and Polar Research
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    • v.31 no.4
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    • pp.401-414
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    • 2009
  • Yellow Sea Buoy (YSB) was moored in the center of the Yellow Sea at 35$^{\circ}$51'36"N, 124$^{\circ}$34'42"E, on 12 September 2007. YSB is a large buoy of 10 m diameter, and as such is more durable against collision by ships and less likely to be lost or removed by fishing nets compared to small ordinary buoys of 2.3 m diameter. YSB is equipped with 12 kinds of oceanic and meteorologic instruments, and transfers its realtime observation data to KORDI through ORBCOMM system every 1 hour. Data on ocean winds, air temperature, air pressure, and sea temperature appear to be accurate, while water property sensors (AAQ1183), which are sensitive to fouling, are producing errors. YSB (2007), Ieodo ocean research station (2003), and Gageocho ocean research station, which was completed in October 2009, will establish the 2 degrees interval by latitude in the Yellow Sea, and they will contribute though the 'Operational Oceanography System' as the important realtime observation network.

Application of 4-D resistivity imaging technique to visualize the migration of injected materials in subsurface (지하주입 물질 거동 규명을 위한 4차원 전기비저항 영상화)

  • Kim, Jung-Ho;Yi, Myeong-Jong
    • 한국지구물리탐사학회:학술대회논문집
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    • 2007.12a
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    • pp.31-42
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    • 2007
  • Dc resistivity monitoring has been increasingly used in order to understand the changes of subsurface conditions in terms of conductivity. The commonly adopted interpretation approach which separately inverts time-lapse data may generate inversion artifacts due to measurement error. Eventually the contaminated error amplifies the artifacts when reconstructing the difference images to quantitatively estimate the change of ground condition. In order to alleviate the problems, we defined the subsurface structure as four dimensional (4-D) space-time model and developed 4-D inversion algorithm which can calculate the reasonable subsurface structure continuously changing in time even when the material properties change during data measurements. In this paper, we discussed two case histories of resistivity monitoring to study the ground condition change when the properties of the subsurface material were artificially altered by injecting conductive materials into the ground: (1) dye tracer experiment to study the applicability of electrical resistivity tomography to monitoring of water movement in soil profile and (2) the evaluation of cement grouting performed to reinforce the ground. Through these two case histories, we demonstrated that the 4-D resistivity imaging technique is very powerful to precisely delineate the change of ground condition. Particularly owing to the 4-D inversion algorithm, we were able to reconstruct the history of the change of subsurface material property.

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A Study on the Change of Mechanical Property According to the Aging of Polymer Electrolyte Membrane (고분자전해질막의 노후화에 따른 기계적 특성 변화에 관한 연구)

  • KIM, SEUNGHWAN;EO, JUNWOO;SEO, YOUNGJIN;HWANG, CHULMIN;JUNG, YOUNGGUAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.2
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    • pp.176-182
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    • 2022
  • Since the various characteristics of the polymer electrolyte membrane are not clearly identified, it is difficult to predict and design applications for various conditions. In this study, as a previous study on the aging of the polymer electrolyte membrane, a study was conducted on the change of mechanical properties according to the aging of the polymer electrolyte membrane. Through the tensile test of Nafion 117, the mechanical properties change due to aging was confirmed. As a result of the tensile test, it was confirmed that the aged Nafion 117 had reduced tensile strength. Through DSC measurement, aged Nafion confirmed that the glass transition temperature and enthalpy change were low, which is thought to be the effect of molecular motion and transition due to the lapse of time. The effect is thought to cause a difference in the amount of change in enthalpy, resulting in a difference in mechanical properties during tension.

The appearance change and heat·moisture transfer properties of knitted fabric by yarn shrinkage (원사의 수축에 따른 다공성 편성물의 형태변화와 열·수분 전달특성)

  • Sang, Jeong-Seon;Park, Juhyun;Lee, Mee-Sik;Oh, Kyung Wha
    • The Research Journal of the Costume Culture
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    • v.25 no.6
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    • pp.880-892
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    • 2017
  • In this study, the appearance change and the heat moisture transfer properties of knitted fabric by yarn shrinkage were examined to obtain useful data on the development of thermo-sensitive functional materials. Eleven types of knitted fabric were knitted using highly bulky acrylic-blended yarn. After shrinking the specimens using dry heat treatment, the appearance change and thickness were measured. An HEC simulator was adopted for measuring the heat moisture transfer properties of specimens by yarn shrinkage. When holes were arranged vertically in the mesh structure, the specimens with 2,500 and 5,000 holes showed high percent change of hole area, appearance, and thickness. When holes were diagonally arranged in the mesh structure, the percent change of hole area in the specimen with 1,250 holes was larger than the one with 2,500 holes. However, the dimensional stability of the specimen with 2,500 holes was better because of its smaller appearance and thickness change. In the tuck structure, the percent change of hole area in the specimen with 625 and 416 holes was relatively large compared with the appearance and thickness change. Furthermore, the hole size in the tuck structure was smaller than that in the mesh structure but the percent change of hole area was larger. Therefore, it was proved that the tuck structure is more suitable than the mesh structure for developing thermo-sensitive functional materials. Heat moisture transfer property test verified that the change of hole area by yarn shrinkage enabled obtaining the thermal effect due to the distinct temperature difference in the inner layer.

A Study on Changes of Traditional Wall Technique (전통 벽체 기법 변화에 관한 연구)

  • Cho, Young-Min
    • Journal of architectural history
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    • v.23 no.4
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    • pp.47-56
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    • 2014
  • Traditional wall is ground coat, twice plater, last plaster by such a process has made a wide variety of used materials and techniques are accordingly diverse. These traditional techniques handed down the traditional walls of the techniques, rather than coming to the lowered cut off at any moment from now when the technique is used, not knowing whether to be used. Repair and restore cultural property maintenance work, it is not only the outward form hiding inside it is a technique to keep the preservation of cultural assets can be called true. When viewed from the side walls of these conventional techniques to reveal changes in the traditional process by looking at the changes in technology with traditional techniques for cause shall be made in stock. This paper is from the late Joseon Japanese occupation of techniques ranging from traditional wall to reveal the change process to its current significance of cultural property repair method to be helped.