• Proceedings of the KACD Conference
• /
• 2008.05a
• /
• pp.235-245
• /
• 2008

The aim of this study was to develop a method for measuring the slumping resistance of resin composites and to relate it to the rheological characteristics. Five commercial hybrid composites (Z100. Z250. DenFil, Tetric Ceram. ClearFil) and a nanofill composite (Z350) were used to make disc-shaped specimens of 2 mm thickness. An aluminum mold with square shaped cutting surface was pressed onto the composite discs to make standardized imprints. The imprints were light-cured either immediately (non-slumped) or after waiting for 3 minutes at $25^{\circ}C$ (slumped). White stone replicas were made and then scanned for topography using a laser 3-D profilometer. Slumping resistance index (SRI) was defined as the ratio of the groove depth of the slumped specimen to that of the non-slumped specimen. The pre-cure viscoelasticity of each composite was evaluated by an oscillatory shear test and normal stress was measured by a squeeze test using a rheometer. Flow test was also performed using a flow tester. Correlation analysis was performed to investigate the relationship between the viscoelastic properties and the SRI. SRI varied between the six materials (Z100 < DenFil < Z250 < ClearFil < Tetric Ceram < Z350). The SRI was strongly correlated with the viscous (loss) shear modulus G' but not with the loss tangent. Also. slumping resistance was more closely related to the resistance to shear flow than to the normal stress. Slumping tendency could be quantified using the imprint method and SRI. The index may be applicable to evaluate the clinical handling characteristics of composites.

• Journal of the Korea Concrete Institute
• /
• v.17 no.6 s.90
• /
• pp.923-930
• /
• 2005

This paper was to evaluate the high strength lightweight self-compacting concrete(HLSCC) manufactured by Nan-Su, which main factor, Packing Factor(PF) for mixing design, has been modified and improved. We have examined HLSCC performance at its fresh condition as well as its mechanical properties at the hardened condition. The evaluation of HLSCC fluidity has been conducted per the standard of second class rating of JSCE, by three categories of flowability(slump-flow), segregation resistance ability(time required to reach 500mm of slump-flow and time required to flow through V-funnel) and filling ability(U-box test) of fresh concrete. The compressive strength of HLSSC at 28 days has come out to more than 30MPa in all mixes. The relationship between the compressive strength-splitting tensile strength and compressive strength-modulus of elasticity of HLSSC were similar those of typical lightweight concrete. Compressive strength and dry density of HLSCC at 28 days from the multiple regression analysis resulted as $f_c=-0.16LC-0.008LS+50.05(R=0.83)\;and\;f_d=-3.598LC-2.244LS+2,310(R=0.99)$, respectively.

• Applied Chemistry for Engineering
• /
• v.30 no.6
• /
• pp.673-680
• /
• 2019

GAP or GAP-co-BO based energetic thermoplastic elastomers (ETPEs) were synthesized by changing the hard segment content percent in the range of 30~45% by 5% difference. Thermal and mechanical properties of GAP-co-BO based ETPEs were compared to those of GAP based ETPEs. FT-IR results showed that the capability of forming hydrogen bond increases with increasing the hard segment content in GAP/GAP-co-BO based ETPE, and also the GAP-co-BO based ETPEs are stronger than GAP based ETPEs in the hydrogen bond formation. DSC and DMA results showed that the glass transition temperature (T_g) of GAP based ETPEs increased with the increment of the hard segment content, while the T_g of GAP-co-BO based ETPEs was maintained even the hard segment content increased. The storage modulus at room temperature of the GAP-co-BO based ETPEs was higher than that of the GAP based ETPEs. This was due to the strong phase separation behavior of the hard and soft segment of GAP-co-BO based ETPEs, which further resulted in the stronger breaking strength and lower tensile elongation at break point for GAP-co-BO based ETPE than the GAP based one.

• Polymer(Korea)
• /
• v.30 no.1
• /
• pp.85-89
• /
• 2006

The effect of vapor grown carbon fiber (VGCF) contents on electrical and rheological properties of VGCF filled polyphenylene sulfide (PPS) composites prepared through melt mixing using a twin screw exruder was studied. This method was proved to be quite effective to produce good dispersion of VGCF in the matrix even for highly filled PPS. From the dependence of the electrical conductivity on VGCF content, the percolation phenomena began to occur above $10\;wt\%$. While there is only a marginal increase of viscosity for 1 and $5\;wt\%$ VGCF filled PPS, the composites containing $10\;wt\%$. While VGCF showed abrupt increase in viscosity as well as flattening of frequency vs modulus curve, indicating a transition from a liquid-like to a solid-like behavior due to the creation of VGCF network. This result agrees well to the fact that the network formation in the composite can be composite by rheological property dependence on filler content as well as by electrical conductivity measurement.

• Restorative Dentistry and Endodontics
• /
• v.33 no.3
• /
• pp.235-245
• /
• 2008

The aim of this study was to develop a method for measuring the slumping resistance of resin composites and to relate it to the rheological characteristics. Five commercial hybrid composites (Z100, Z250, DenFil, Tetric Ceram, ClearFil) and a nanofill composite (Z350) were used to make disc-shaped specimens of 2 mm thickness. An aluminum mold with square shaped cutting surface was pressed onto the composite discs to make standardized imprints. The imprints were light-cured either immediately (non-slumped) or after waiting for 3 minutes at $25{\circ}C$ (slumped). White stone replicas were made and then scanned for topography using a laser 3-D profilometer. Slumping resistance index (SRI) was defined as the ratio of the groove depth of the slumped specimen to that of the nonslumped specimen. The pre-cure viscoelasticity of each composite was evaluated by an oscillatory shear test and normal stress was measured by a squeeze test using a rheometer. Flow test was also performed using a flow tester. Correlation analysis was performed to investigate the relationship between the viscoelastic properties and the SRI. SRI varied between the six materials (Z100 < DenFil < Z250 < ClearFil < Tetric Ceram < Z350). The SRI was strongly correlated with the viscous (loss) shear modulus G' but not with the loss tangent. Also, slumping resistance was more closely related to the resistance to shear flow than to the normal stress. Slumping tendency could be quantified using the imprint method and SRI. The index may be applicable to evaluate the clinical handling characteristics of composites.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.23 no.2
• /
• pp.107-115
• /
• 2019

The many countries are facing the shortage of natural resources, and the supply of aggregates are being exhausted. To consider this situation a variety of studies were performed for the development of alternative resources. In particular, high density filler material was used for shielding radioactive waste, large amount of natural aggregates are required in order to produce filler material. Also, in order to improve the shielding performance of filler material, it is required to increase the density of the filler material. Therefore, in this study was carried out to provide basic data for expanding the feasibility of high density industrial waste resource as aggregate in heavyweight concrete. From the test results, OPC case, concrete strength decreased by using heavyweight waste glass as fine aggregate, however, it is improved by using mineral admixture as binder. Therefore, when the heavyweight waste glass and steel slag are applied to heavyweight concrete, it is desirable to use mineral admixture, especially to use BFS than FA. Meanwhile, when the steel slag was replaced as coarse aggregate of heavyweight concrete, elasticity of modulus and radiation shielding performance can be improved owing to high density of steel slag.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.19 no.4 s.74
• /
• pp.389-398
• /
• 2006

Structural optimization design has been developed with finite element analysis using effective and fast computational technology. Especially topology optimization design has been recently often used since it yields an optimal topology as well as an optimal shape under satisfied constraints. In general in finite element analysis, it is assumed that the structural material properties such as Young's modulus and Poisson's ratio and the variable of applied loading are fixed with obvious values in structure. However practically these values may take uncertainties because of environmental effect or manufactural error of structures. Therefore static or dynamic analysis of the structures may make an error, then finally it may have an influence on qualify of optimal design. In this study, the topology optimization design of structure is carried out using so called the interval finite element method, and the analysis method Is proposed. The results are also validated by comparing with conventional topology optimization results of density distribution method and finite element analysis results. The present method can be used to predict the optimal topology of linear elastostatic structures with respect to structural uncertainty of behavior.

• Polymer(Korea)
• /
• v.28 no.1
• /
• pp.24-34
• /
• 2004

Transient sorption experiments were conducted among several combinations of fluoropolymers and various organic solvents. Fully fluorinated polymer tended to exhibit ideal sorption behavior, while partially fluorinated polymers showed anomalous sorption behaviors with a drastic acceleration at the final stage of uptake. Minimization of least-squares of the measured and predicted fractional uptake, which indicated the increasing degree of deviation from Fickian diffusion, gave values of 3.0${\times}$10$\^$-4/, 1.75${\times}$10$\^$-3/, 8.68${\times}$10/sup-3/, 1.75${\times}$10$\^$-2/, respectively, for perfluoroalkoxy copolymer, poly(ethylene-co-tetrafluoroethylene), poly(vinylidene fluoride), poly(ethylene-co-chlorotrifluoroethylene). From stress-strain tests, it was confirmed that non-Fickian diffusion is closely related to the significant variation of mechanical properties (such as modulus and tensile strength) of swollen polymer. Anomalous sorption behavior stemmed from non-Fickian diffusion caused by nonlinear disruption of polar inter-segmental bonds due to solvent-induced plasticization. Thus, it is imperative to investigate the diffusion behavior of swelling solvents in partially fluorinated polymers, especially for the application to barrier materials or perm-selective membranes.

• Journal of the Korean Geotechnical Society
• /
• v.29 no.4
• /
• pp.23-32
• /
• 2013

In order to evaluate the bearing capacity behaviour of a monopod suction bucket foundation for an offshore wind tower at the western sea of Korea, a centrifuge load test and numerical analyses were performed. The monopod bucket foundation was designed to be installed in a silty sand layer. The model soil was prepared to simulate a target site by using soil samples having similar properties and controlling relative density. In-flight miniature cone penetration test and bender element array were used to confirm that the model soil had represented the target site conditions. The load - rotation curve of the centrifuge load test was analysed. A series of numerical analyses were performed to validate the experimental conditions. Self-weight of the model, distance to the boundary and elastic modulus of the soil layer were varied to study their effects on the load - rotation curves.

• Journal of the Korea Concrete Institute
• /
• v.16 no.1 s.79
• /
• pp.61-69
• /
• 2004

The bridge piers under service suffered a brittle failure due to the deterioration of lap-spliced longitudinal reinforcement without developing its flexural capacity or ductility. The earthquake induced lateral force results in tension which causes bond-slip failure at the lap-spliced region in circular bridge piers. In this case, such a brittle failure can be controlled by the seismic retrofit using FRP laminated circular tube. The retrofitted piers using FRP laminated circular tube showed significant improvement in seismic performance due to FRP's confinement effect. This paper presents the analytical results on the seismic strengthening effect of circular bridge piers with poor lap-splice details and strengthened with FRP laminated circular tube. FRP's confinement effect is predicted by the classical elasticity solution for the laminated circular tube manufactured with several layers. The FRP laminated circular tube induces the flexural failure instead of a bond-slip failure of the circular reinforced concrete piers under seismic induced lateral forces. To investigate the correctness and effectiveness of analytical solution derived in this study, the analytical results were compared with the experimental data and it was confirmed that the results were correlated well each other, The effects on the confinement of FRP laminated circular tube, such as the number of layers, the fiber orientations, and the mechanical properties, were investigated. From the parametric study, it was found that the number of layers, the fiber orientations, and the major Young's modulus (E11) of the FRP laminated circular tube were the dominant parameters affecting the confinement of reinforced concrete circular bridge piers.