• Membrane Journal
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• v.19 no.2
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• pp.89-95
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• 2009

A comb-like copolymer consisting of a poly(vinyl chloride) backbone and poly(hydroxy ethyl acrylate) side chains, i.e. PVC-g-PHEA, was synthesized through atom transfer radical polymerization (ATRP). This comb-like copolymer was crosslinked with 4,5-imidazole dicarboxylic acid (IDA) via the esterification of the -OH groups of PHEA in the graft copolymer and the -COOH groups of IDA. Upon doping with phosphoric acid (PA, $H_3PO_4$) to form imidazole-PA complexes, the proton conductivity of the membranes continuously increased with increasing PA content. A maximum proton conductivity of 0.011 S/cm was achieved at $100^{\circ}C$ under anhydrous conditions. The PVC-g-PHEA/IDA/PA complex membranes exhibited good mechanical properties, i.e. 575 MPa of Young's modulus, as determined by a universal testing machine (UTM). Thermal gravimetric analysis (TGA) shows that the membranes were thermally stable up to $200^{\circ}C$.

• Polymer(Korea)
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• v.33 no.3
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• pp.243-247
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• 2009

Cellulose diacetate (CDA) was plasticized with triacetine (TA) and epoxidized soybean oil (ESO) in a high speed mixer. Composites of plasticized CDA and zeolite were prepared by a melting process. The $T_g$ value, $106^{\circ}C$ of the plasticized CDA was confirmed by DMA analysis. The $T_g$ value of the CDA with 50% zeolite was $125^{\circ}C$. As the content of zeolite was increased from 10 to 50% the modulus of the composite was increased from 1.7to 3.6 GPa by two times over the plasticized CDA, and its tensile strength was increased to 62 MPa and then decreased down 51 MPa, and its elongation was increased to 10% and then decreased down 3.2%. In the SEM image, the compatibility between CDA and zeolite was observed. Increasing the amount of zeolite in the composites resulted in further enhancement of the $CH_3COOH$ absorption effects.

• Resources Recycling
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• v.8 no.4
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• pp.57-63
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• 1999

Wood-Polymer Composites (WPC) m s prepared irom recycled films of agricullural use and wood wastes, and LLDPE and neal PE resin mlxlurr war also utilized in order to cornpiue the praperlies. Molc~ca nhydride (MA) and dicumyl peroxide were used as an adheslon pmmoler and an il~lliatotor~, .espcmivelyT. ensile prapenies of W Cw zrc measured via lenslle test as a funclieu of woad lille~m d MA contmt, and rractu1.e surface was also mvestigaled wilh SEM. As the content of wwd tiller mcreased, clongauon deneased bul modulus increased However, tensile slrength OI WPC increased only when MA war used, and 1 wt.% of MA may be hgh enough to increase the tensile properties. The tensilc ptopcrlies af WPC prepwed from recycled PE films were &nost same as thosc of neal PE resin mixture.

• Polymer(Korea)
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• v.38 no.6
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• pp.735-743
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• 2014

The rheological measurement of polypropylene (PP) has been performed using a rheometer, an intrinsic viscometer, and an MI machine to predict the molecular weight and the molecular weight distribution. Also, GPC has been used for the determination of the molecular structure. The distribution broadness parameter using modified Carreau model has been used to make the correlation between the rheological parameter and the molecular structure instead of the rheological PI (polydispersity index) which is determined from the cross of modulus from the dynamic oscillatory measurement. Even though the rheological PI is useful to determine the molecular weight distribution of the PP using controlled rheology, which has narrow and uniform molecular weight distribution, but not suitable to determine the molecular weight distribution of the PP made from direct polymerization which has broad and various molecular weight distribution. However the distribution broadness parameter which determined from the index of the shear thinning of the PP melt well predicts the molecular weight distribution of PP.

• Elastomers and Composites
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• v.53 no.4
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• pp.213-219
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• 2018

The degradation mechanism and physical properties of an FKM O-ring were observed with thermal aging in this experiment. From X-ray photoelectron spectroscopy (XPS) analysis, we could observe carbon (285 eV), fluoro (688 eV), and oxygen (531 eV) peaks. Before thermal aging, the concentration of fluoro atoms was 51.23%, which decreased to 8.29% after thermal aging. The concentration of oxygen atoms increased from 3.16% to 20.39%. Under thermal aging, the FKM O-ring exhibited debonding of the fluoro-bond by oxidation. Analysis of the C1s, O1s, and F1s peaks revealed that the degradation reaction usually occurred at the C-F, C-F2, and C-F3 bonds, and generated a carboxyl group (-COOH) by oxidation. Due to the debonding reaction and decreasing mobility, the glass transition temperature of the FKM O-ring increased from $-15.91^{\circ}C$ to $-13.79^{\circ}C$. From the intermittent CSR test, the initial sealing force was 2,149.6 N, which decreased to 1,156.2 N after thermal aging. Thus, under thermal aging, the sealing force decreased to 46.2%, compared with its initial state. This phenomenon was caused by the debonding reaction and decreasing mobility of the FKM O-ring. The S-S curve exhibited a 50% increase in modulus, with break at a low strain and stress state. This was also attributed to the decreasing mobility due to thermal aging degradation.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.6A
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• pp.943-953
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• 2006

We investigated experimentally the static behavior of an orthotropic bridge deck which is made from glass fiber reinforced polymer (GFRP) and polyurethane foam. The bridge deck consists of many unit cells with rectangular holes which are filled with the foam to improve its structural behavior in its weak axis. It is found that although the elastic modulus of the foam compared to that of the GFRP is about the order of, the structural behaviors in the weak axis such as nominal strength, stiffness, etc. are greatly improved. Owing to the low mass density of the foam used in this study, the bridge deck is still light enough with the improved structural properties. Webs of the cells filled with the foam did not significantly contribute to the strength development of the deck. However, the propagation of a crack initiated in a cell is caught by the webs and limited to the inside of that cell only, which makes the load-displacement behavior of the foam-filled GFRP deck less brittle.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.1
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• pp.1-12
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• 1994

This paper deals with the time-dependent analysis of reinforced and prestressed concrete beams. Based on the age-adjusted effective modulus method, the structural behavior in accordance with time is analyzed using the force equilibrium and strain compatibility condition within a typical section. Unlike most of presented approaches adopting some assumptions, such as non-cracking of concrete and consideration of steel effect as a transformed concrete area only, more accurate results can be obtained at all loading conditions since all materials are considered together so as to be maintained their given properties and the cracking effect is included at the same time. Several parameter studies are conducted with the objective to identify the significance of various effects on the time-dependent response of concrete members, i.e., stress re-distribution of each material and occurrance of long-term deflection, etc. Moreover, the obtained results can be used at design and/or construction stage for the purpose of more accurate prediction of structural response with time.

• Journal of Sericultural and Entomological Science
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• v.36 no.2
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• pp.147-151
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• 1994

This study was carried out investigate the characteristics of Habutae and Chiffon woven with silk and polyester(S/P) compound yarn. The S/P compound yarn could be produced by the automatic reeling machine with attachment of air jetting device, polyester yarn guider and tension control apparatus. The surface structure, tensile property and dyeing fastness of S/P compound fabric were examined for the fabric properties. Electron microscopy revealed that most part of S/P compound yarn was well interlaced and some silk part of compound yarn were hidden by polyester on an examination of surface of chiffon fabric. By the one bath and two step dyeing of disperse and acidic dyes, the colour fastness of S/P compound fabrics were 4 grade above. The tenacity and initial modulus of the finished S/P compound fabric were lower than those of grey and degummed fabrics, but reversed in elongation.

• Journal of the Korea Concrete Institute
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• v.14 no.6
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• pp.1032-1039
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• 2002

Since recycling waste glass as a material for concrete has a great advantage environmentally and economically, the US, Japan and other countries have started recycling waste glass widely and accumulating the technology of manufacturing equipment and its construction. However, there is no practical data on the mechanical property of concrete using waste glass. In this study, the mechanical property of the steel fiber reinforced concrete using waste glass was analyzed in terms of waste glass content(20vo1. ％, 40vo1. ％ as a part of fine aggregate) and steel fiber content(0.5~ 1.5vol.％). The results of this study are as follows : The workability of the concrete including steel fiber and waste glass decreases, as the inclusion rate of waste glass and steel fiber increases. The tensile strength, flexural strength and flexural toughness of the concrete including waste glass increase considerably, as the inclusion rate of steel fiber increases. From the results, the appropriate inclusion rate of steel fiber and waste glass is thought to be 1.0vol. % and 20vo1. ％, respectively.

• Composites Research
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• v.30 no.6
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• pp.371-378
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• 2017

In this study, hygroelastic behavior of thermosetting epoxy is predicted by molecular dynamics simulations. Since consistent exposures to humid environments lead to macroscopic degradation of polymer composite, computational simulation study of the hygroscopically aged epoxy cell is essential for long-time durability. Therefore, we modeled amorphous epoxy molecular unit cell structures at a crosslinking ratio of 30, 90% and with the moisture weight fraction of 0, 4 wt% respectively. Diglycidyl ether of bisphenol F (EPON862) and triethylenetetramine (TETA) are chosen as resin and curing agent respectively. Incorporating equilibrium and non-equilibrium ensemble simulation with a classical interatomic potential, various hygroelastic properties including diffusion coefficient of water, coefficient of moisture expansion (CME), stress-strain curve and elastic modulus are predicted. To establish the structural property relationship of pure epoxy, free volume and internal non-bond potential energy of epoxy are examined.