• Title/Summary/Keyword: processing properties

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Effect of the Processing History on the Morphology and Properties of the Ternary Blends of Nylon 6, a Thermotropic Liquid Crystalline Polymer, and a Functionalized Polypropylene

  • Yongsok Seo;Kim, Hyong-Jun;Kim, Byeongyeol;Hong, Soon-Man;Hwang, Seung-Sang;Kim, Kwang-Ung
    • Macromolecular Research
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    • v.9 no.4
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    • pp.238-246
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    • 2001
  • Properties of ternary blends of nylon 6 (Ny6), a thermotropic liquid crystalline polymer (TLCP, poly(ester amide), 20 wt%) and a maleic anhydride grafted polypropylene (2 wt%) (MAPP) were studied under various processing conditions. TLCP was pre-blended with MAPP first and then the binary one blended again with Ny6. The processing temperature of the second mixing was varied. Thermal properties show the partial miscibility of the ternary blend. The morphology of the TLCP phase in the first blending shows mostly in the fibril bundle shape, but varies between droplets and oriented fibrils after the second processing. Some of TLCP phase lost the fibril morphology during the second processing stage. The morphology variation invokes the change in tensile properties. Low extrusion temperature (270$\^{C}$) provides more fibril shapes, which are associated with less deformation in the second stage. The processing temperature effect was more evident when the draw ratio was high. High drawing was applicable due to the stabilizing action of tile compatibilizer.

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Predicting the Impact of Food Processing on the Physical Properties of Food

  • Zuo, Li;Lee, Jun-Ho
    • Preventive Nutrition and Food Science
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    • v.8 no.4
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    • pp.419-424
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    • 2003
  • The physical properties of food playa significant role in the modeling and computation of the heat and mass transfers in basic food processing operations. With the advent of improved analytical techniques, statistical experiment design applications, computing ability and knowledge of the food physical properties of food, there have been significant advances in our ability to predict the impact of processing on the physical properties of food. This article briefly reviews our current ability to predict the influence of processing on the physical properties of food, such as water activity, moisture, color, and rheological characteristics.

Facilitation of the Diverse Processing of High Ductile ECC (Engineered Cementitious Composite) Based on Micromechanics and Rheological Control (마이크로 역학과 레올로지 제어에 의한 고인성 섬유복합재료 ECC(Engineered Cementitious Composite)의 다양한 타설 공정 구현)

  • Kim, Yun-Yong;Kim, Jeong-Su
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.5
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    • pp.27-39
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    • 2005
  • In the recent design of high ductile fiber-reinforced ECC (engineered cementitious composite), optimizing both processing and mechanical properties for specific applications is critical. This study presents an innovative method to develop new class ECCs, which possess the different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or shotcrete processing) while maintaining ductile hardened properties. In the material design concept, we employ a parallel control of fresh and hardened properties by using micromechanics and cement rheology. Control of colloidal interaction between the particles is regarded as a key factor to allow the performance of the specific processing. To determine how to control the particle interactions and the viscosity of cement suspension, we first introduce two chemical admixtures including a highly charged polyelectrolyte and a non-ionic polymer. Optimized mixing steps and dosages we, then, obtained within the solid concentration predetermined based on micromechanical principle. Test results indicate that the rheological properties altered by this approach were revealed to be highly effective in obtaining the desired function of the fresh ECC, allowing us to readily achieve hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension.

Processibility of High Ductile Fiber-Reinforced ECCs (Engineered Cementitious Composites) (고인성 섬유복합재료 ECC (Engineered Cementitious Composite)의 시공성)

  • Kim Yun Yong;Kim Jeong-Su;Kim Jin-Keun;Ha Gee-Joo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.313-316
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    • 2005
  • In the recent design of high ductile fiber-reinforced cementitious composite ECC, which exhibits tensile strain-hardening behavior in the hardened state, optimizing both processing mechanical properties for specific applications is critical. This study introduced a method to develop useful ECCs in field, which possess the different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or spray processing). Control of rheological modulation was regarded as a key factor to allow the performance of the desired processing, while retaining the ductile material properties. To control the rheological properties of the composite, we first determined basic ECC compositon, which is based on micromechanics and steady-state cracking theory. The stability and consequent viscosity of suspensions were, then, mediated by optimizing dosages of chemical and mineral admixtures. The rheological properties altered by this approach were revealed to be effective in obtaining ECC hardened properties, allowing us to readily achieve the desired function of the fresh ECC.

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PZTN Sintered at the Low Temperature by the Glass Phase Transient Processing (글래스 천이 공정에 의해 저온소결된 PZTN)

  • Kim Chan Young
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.3
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    • pp.97-102
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    • 2005
  • This research was a fundamental study for the low temperature sintering of PZTN by glass phase transient processing. To lower the sintering temperature, the glass phase Processing was used. Also to improve the electrical properties, the transient processing was utilized. After characterization, the various analytic techniques, such as Archimedes method for the measuring densification, x-ray diffraction patterns for the quantitative analysis of crystalline phases were utilized. Also the dielectric constant, dissipation factor, and piezoelectric coefficients were measured to evaluate the PZTN sintered at the $950^{\circ}C$ and $1050^{\circ}C$. This was confirmed that the sintering temperature of PZTN was reduced by $950^{\circ}C$ and the electrical properties were improved by the transition processing. Therefore, the glass phase transient processing can be applicable to low the sintering temperature with the dielectric and piezoelectric properties.

The role of extensional rheology in polymer processing

  • Baird, Donald G.
    • Korea-Australia Rheology Journal
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    • v.11 no.4
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    • pp.305-311
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    • 1999
  • The shear behavior of polymers obtained by means of devices such as capillary and cone-and-plate rheo-meters is commonly used to assess their processing performance and as a characterization tool. However, the number of instances when two polymers have the same shear properties but perform differently during certain types of processing operations (e.g. film blowing and sheet extrusion) indicate that shear properties alone may not be sufficient to characterize polymeric fluids. We begin by defining the kinematics of shear-free or extensional flow and the associated material functions. The extensional and shear behavior of three different types of polyethylene (PE) are then compared to illustrate the points that one cannot ascertain the extensional properties of polymer melts from their shear properties and, furthermore, there may not be a simple relation between properties obtained from one type of extensional flow and those of another type. The kinematics of most processing flows are extensional rather than shear in nature, and , hence, the performance of polymers during processes such as fiber spinning, film casting, film blowing, thermoforming, blow molding, and even extrusion is more readily accounted for through extensional viscosity measurements. Methods for carrying out extensional flow measurements are then reviewed including approximate methods. To illustrate the sensitivity of extensional viscosity measurements to subtle changes in the molecular architecture of PEs, results are presented for samples with a narrow molecular weight distribution but with varying numbers of long chain branches. Finally, constitutive equations which allow one to separate shear and extensional flow behavior are discussed as any attempts to simulate the subtle processing differences between two polymers will require constitutive equations of this nature.

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The Effects of Processing Conditions of Belt Texturing Machine on the DTY Physical Properties

  • Kim, Seung-Jin;Lee, Min-Soo
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.39-40
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    • 2003
  • This research surveys the effects of POY physical properties and processing conditions of belt texturing machine to the draw textured yarns. The various textured yarns are made with variation of 1st heater temperature, draw ratio and velocity ratio, and the physical properties of these specimens such as yarn linear density, tensile properties and wet and dry thermal shrinkages are measured and analyzed with POY physical properties and processing conditions of texturing machine. Especially yarn mechanical properties of DTY are analysed with the variation of untwisting tension (T$_2$) on the untwisting part in DTY process and thin and thick DTY yam model are proposed with surging phenomena in DTY process.

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Influence of Loading Procedure of Liquid Butadiene Rubber on Properties of Silica-filled Tire Tread Compounds

  • Jinwoo Seo;Woong Kim;Seongguk Bae;Jungsoo Kim
    • Elastomers and Composites
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    • v.57 no.4
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    • pp.129-137
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    • 2022
  • Low molecular weight liquid butadiene rubber (LqBR) is a processing aid that can resolve the migration problem of tire tread compounds. Various studies are being conducted to replace the petroleum-based processing oil with LqBR. However, the effect of the loading time of LqBR in the compounding process on silica dispersion and vulcanizate properties is not well known. In this study, we analyzed silica dispersion, vulcanizate properties, and viscoelastic properties of silica-filled tire tread compound according to the processing aid type (TDAE oil, non-functional LqBR) and, silane terminated LqBR) and input timing. In the non-functional LqBR compounds, the 'with TESPT' mixing procedure showed excellent dynamic viscoelastic properties while silane-terminated LqBR compounds showed that the 'after TESPT' mixing procedure was good for 300% modulus and abrasion resistance.

Differences in Physicochemical and Nutritional Properties of Breast and Thigh Meat from Crossbred Chickens, Commercial Broilers, and Spent Hens

  • Chen, Yulian;Qiao, Yan;Xiao, Yu;Chen, Haochun;Zhao, Liang;Huang, Ming;Zhou, Guanghong
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.6
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    • pp.855-864
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    • 2016
  • The objective of this study was to compare the physicochemical and nutritional properties of breast and thigh meat from commercial Chinese crossbred chickens (817 Crossbred chicken, 817C), imported commercial broilers (Arbor Acres broiler, AAB), and commercial spent hens (Hyline Brown, HLB). The crossbred chickens, commercial broilers and spent hens were slaughtered at their typical market ages of 45 d, 40 d, and 560 d, respectively. The results revealed that several different characteristic features for the three breeds. The meat of the 817C was darker than that of the other two genotypes. The 817C were also characterized by higher protein, lower intramuscular fat, and better texture attributes (cooking loss, pressing loss and Warner-Bratzler shear force [WBSF]) compared with AAB and HLB. The meat of the spent hens (i.e. HLB) was higher in WBSF and total collagen content than meat of the crossbred chickens and imported broilers. Furthermore, correlation analysis and principal component analysis revealed that there was a clear relationship among physicochemical properties of chicken meats. With regard to nutritional properties, it was found that 817C and HLB exhibited higher contents of essential amino acids and essential/non-essential amino acid ratios. In addition, 817C were noted to have highest content of microelements whereas AAB have highest content of potassium. Besides, 817C birds had particularly higher proportions of desirable fatty acids, essential fatty acids, polyunsaturated/saturated and (18:0+18:1)/16:0 ratios. The present study also revealed that there were significant differences on breast meat and thigh meat for the physicochemical and nutritional properties, regardless of chicken breeds. In conclusion, meat of crossbred chickens has some unique features and exhibited more advantages over commercial broilers and spent hens. Therefore, the current investigation would provide valuable information for the chicken meat product processing, and influence the consumption of different chicken meat.

Study on Processing Properties of Chestnut Resources (밤 자원의 가공적성 연구)

  • Oh, Seon-Min;Baik, Moo-Yeol
    • Food Science and Industry
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    • v.49 no.2
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    • pp.56-62
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    • 2016
  • Although the production of chestnut in Korea is the second largest in the world, domestic consumption of chestnut is very limited. Furthermore, consumption of chestnut in Korea is highly dependent on export to Japan and China. Large amount of chestnut in Korea have been deteriorated and discarded during storage. In order to increase the consumption of chestnut in Korea, it is necessary to know the processing properties of chestnut and its starch. Additionally, through the various investigations such as modification treatment, it will be extended to utilization of chestnut. So far, there is a little information on the processing properties of chestnut; therefore, the expansion of research will bring results to increase the consumption of chestnut.