• 대한기계학회논문집
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• 제14권5호
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• pp.1200-1210
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• 1990

본 연구에서는 먼저, 단열 압축기 또는 단열압축 과정에 대한 기존의 효율들, 즉 등 엔트로피 효율과 폴리트로픽 효율 및 엑서지 효율에서의 출력에 해당하는 양의 의미를 검토하고, 이들을 엑서지 출력을 일반화 시킨 형태의 일종으로서 설명하며, 기 타의 가능한 효율을 정의하고, 나아가 같은 논리를 압축과정 중 외부와 열교환이 있는 비단열 압축과정에 대하여 확장 적용시켜 비단열 압축과정에서의 열역학 제2법칙적 출 력 및 효율들을 정의하고 그들의 특성을 살펴보려 한다.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1998년도 PROCEEDINGS OF THE 15TH KACG TECHNICAL MEETING-PACIFIC RIM 3 SATELLITE SYMPOSIUM SESSION 4, HOTEL HYUNDAI, KYONGJU, SEPTEMBER 20-23, 1998
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• pp.1-20
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• 1998

Processing of thin films by chemical vapor deposition (CVD) is accompanied by chemical reactions, in which the rigorous kinetic analysis is difficult to achieve. In these conditions, thermodynamic calculation leads to better understanding of the CVD process and helps to optimise the experimental parameters to obtain a desired product. A CVD phase diagram has been used as guide lines for the process. By determining the effect of each process variable on the driving force for deposition, the thermodynamic limit for the substrate temperature that diamond can deposit is calculated in the C-H system by assuming that the limit is defined by the CVD diamond phase diagram. The addition of iso-supersaturation ratio lines to the CVD phase diagram in the Si-Cl-H system provides additional information about the effects of CVD process variables.

• 한국안전학회지
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• 제23권6호
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• pp.91-99
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• 2008

The identification of thermal hazards associated with a process such as heats of reaction and understanding of thermodynamics before any large scale operations are undertaken. The evaluation of thermal behavior with operating conditions such as a reaction temperature, stirrer speed and reactants concentration in neutralization process of pigment plant are described. The experiments were performed by a sort of calorimetry with multimax reactor system The aim of the study was to evaluate the results of heat of reaction in terms of safety reliability to be practical applications. It suggested that we be proposed safe operating conditions and securities for accident prevention on reactor explosion through this study.

• 공업화학
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• 제26권5호
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• pp.581-586
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• 2015

입상 활성탄을 사용하여 수용액으로부터 Safranin의 흡착에 대해 조사하였다. 회분식 실험은 흡착제의 양, 초기농도와 접촉시간과 온도를 흡착변수로 사용하여 수행하였다. 흡착평형자료는 Langmuir, Freundlich 및 Dubinin-Radushkevich식을 사용하여 해석한 결과 Freundlich식이 가장 좋은 일치도를 나타냈다. 평가된 Langmuir 분리계수, $R_L=0.183{\sim}0.254$와 Freundlich 분리계수, 1/n = 0.518~0.547로부터 이 흡착공정이 적절한 처리방법이 될 수 있음을 알았다. 흡착속도실험자료를 유사1차 및 유사2차 반응속도식에 적용해 본 결과는 유사2차반응속도식에 잘 맞는 것으로 나타났다. 음수값의 Gibbs 자유에너지(${\Delta}G=-3.688{\sim}-7.220kJ/mol$)와 양수값의 엔탈피(${\Delta}H=33.126kJ/mol$)는 흡착이 자발적이고 흡열공정으로 진행된다는 것을 나타냈다.

• ETRI Journal
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• 제25권6호
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• pp.503-509
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• 2003

Selective epitaxial growth (SEG) of silicon has attracted considerable attention for its good electrical properties and advantages in building microstructures in high-density devices. However, SEG problems, such as an unclear process window, selectivity loss, and nonuniformity have often made application difficult. In our study, we derived processing diagrams for SEG from thermodynamics on gas-phase reactions so that we could predict the SEG process zone for low pressure chemical vapor deposition. In addition, with the help of both the concept of the effective supersaturation ratio and three kinds of E-beam patterns, we evaluated and controlled selectivity loss and non-uniformity in SEG, which is affected by the loading effect. To optimize the SEG process, we propose two practical methods: One deals with cleaning the wafer, and the other involves inserting dummy active patterns into the wide insulator to prevent the silicon from nucleating.

• 오토저널
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• 제10권4호
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• pp.39-56
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• 1988

In this study, the computer program was developed to predict the engine performances and exhaust emissions of a 4-cylinder 4-stroke cycle ignition engine including intake and exhaust system. The simulation models applied to each process were as follows. For the combustion process, two zone model which requires only one empirical constant was applied, and for the gas exchange process, the method of characteristics that allows the calculations of the time variation and spatial variation of properties along the pipes was used. Constant pressure perfect mixing model was applied to take into account of the interaction at manifold branches. To predict exhaust emissions, twelve chemical species were considered to be present in combustion products. These species were calculated through equilibrium thermodynamics and kinetic theory. The empirical constants reduced to least number as possible were determined through the comparison with the experimental indicator diagram of one particular operating condition and these constants were applied to other operating conditions. The predicted performances and emissions were compared with the experimental results over the wide range of operating conditions.

• 한국유체기계학회 논문집
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• 제18권6호
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• pp.19-26
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• 2015

The present paper presented and applied an exergy analysis method to evaluate the magnitudes and the locations of exergy losses in the conventional desuperheating and depressurizing process of high pressure and temperature steam delivery system. In addition, for the reduction of exergy losses occurred in conventional process, the present study proposed new alternative processes in which the pressure reducing valve and the desuperheater of conventional process are substituted with steam turbine and heat exchanger, and their effects on exergy loss reduction and exergy efficiency improvement are theoretically investigated and compared. From the present analysis results, the total exergy loss caused in conventional desuperheating and depressurizing process accounted for 66.5% of exergy input and 85% of the total exergy loss was due to the mixing between steam and cold water(e.g desuperheating). However, it was shown from the present analysis results that the present alternative processes can additionally reduce exergy loss by maximum 92.7% of the total exergy loss in conventional process, and can also produce additional and useful energy, the electricity of 220.6 kWh and the heat of 54.3 MJ/hr.

• 열처리공학회지
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• 제7권4호
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• pp.233-243
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• 1994

Constitutive relation of thermoelasto-plastic material undergoing phase transformation during quenching process were developed on the basic of continuum thermodynamics. The metallic structure, temperature and residual stresses distributions were numerically calculated by the finite element technique. The metallic structure were defined by transformation from austenite to pearlite and characterized as a fuction of thermal history and mixture rule of phase. On the distribution of thermal stress along the radial direction, axial and tangential stresses are compressive in the surface, and tential in the inner part. Radial stress is tensile in the whole body. The reversion of residual stress takes plase at 11.5~15.5mm from the center.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집A
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• pp.430-434
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• 2001

To perform the integrity evaluation of RPV more realistically, it is necessary to evaluate the metallurgical microstructure and residual stress considering more real phenomena such as multi-pass welding process and PWHT. Accordingly, firstly, this paper proposes the integrated assessment methodology systematically developed for residual stress on weldment of RPV by using thermodynamics, diffusion theory, finite element method and validation experiment. Also, the residual stress on circumferential weldment of reactor pressure vessel is calculated considering multi-pass welding process by the commercial finite element package, ABAQUS.

• 한국수소및신에너지학회논문집
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• 제13권3호
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• pp.204-213
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• 2002

In this work, hydrogen production by a 2-step water-spritting thermochemical cycle based on metal oxides redox pairs was investigated on the bases of the thermodynamics and technical feasibility. Also, a 2nd-law analysis performed on the closed cyclic process indicates a maximum exergy conversion efficiency of 7.1% when using a solar cavity-receiver operated at 2300K and air/Fe3O4 molar ratio = 10.