• Journal of the Korean Chemical Society
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• v.37 no.3
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• pp.287-293
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• 1993

Ultraviolet spectrophotometric investigation has been carried out on the system of charge-transfer(CT) complex with iodine and tetramethyltin in n-hexane and acetone. From these results, the transient CT absorption spectrum can be observed and the subsequent disappearance of CT absorption spectrum is accompained by the cleavage of tetramethyltin with iodine (iododestannylation). Therefore, the rate constants for the iododestannylation were determined at 10, 25 and 35$^{\circ}C$ up to 1600 bar and the rates of reaction were increased with increasing temperature and pressure. From these rate constants, the values of the activation parameters (${\Delta}V^{\neq}$, ${\Delta}{\beta}^{\neq}$, ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$) were obtained and discussed in terms of solvent structure variation of transition state and mechanism from these values. It could postulated that the reaction is followed with S$_F$2 mechanism and weakened S$_F$2 mechanism nature by increasing pressure.

• Journal of the Korean Chemical Society
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• v.37 no.6
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• pp.555-561
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• 1993

Ultraviolet spectrophotometric investigation has been carried out on the system of iododestannylation iodine and tetramethyltin in methanol. The transient CT absorption spectrum can be observed and the subsequent disappearance of CT absorption spectrum was accompained by the cleavage of tetramethyltin with iodine. From there, the rate constants for the iododestannylation were determined at 10, 25 and 35$^{\circ}C$ up to 1600 bar and the reaction rates were increased with increasing temperature and pressure. From these rate constants, the values of the activation parameters (${\Delta}V^\neq,\;{\Delta}{\beta}^{\neq},\;{\Delta}H^{\neq},\;{\Delta}S^{\neq}\;and\;{\Delta}G^{\neq}$) were obtained. The activation volumes and activation compressibility coefficients were both negativity. The activation enthalpies were positive and activation entropies had large negative values. From these values discussed in terms of solvent structure variation of transition state and mechanism. From these results, it was found that the reaction is followed with $S_E2$ mechaenism and weakened $S_E2$ mechanism nature by increasing pressure.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.20 no.6
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• pp.75-80
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• 2006

The disastrous accident happens and the economic loss comes into being at the power facilities that used a industry site, if the fault comes into being. This paper experiments the partial discharge in the GIS used a $SF_6$ insulation gas by the pressure change. We studied the influence of particles at the partial discharge in a $SF_6$ gas. We use UHF method and measure the partial discharge signal radiation electromagnetic waves and to be happened at the $SF_6$. And we analyzed the influence on the $SF_6$ gas to have the particles which the partial discharge analyzes a spectrum of the radiated electromagnetic waves and comes out. The paper results aided the prevention of breakdown accident that happened by particles when an inside pressure changes at the GIS & the power facilities used $SF_6$ gas.

• Journal of Industrial Convergence
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• v.21 no.7
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• pp.83-92
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• 2023

The bullet shape of the plasma jet using the atmospheric-pressure dielectric barrier discharge method changes depending on the applied fluid rate and the intensity of the electric field. This changes appear as a difference in spectral distribution due to a difference in density of the DBD plasma jet. It is an important factor in utilizing the plasma device that difference between the occurrence of active species and the intensity through the analysis of the spectrum of the generated plasma jet. In this paper, a plasma jet generator of the atmospheric pressure volume DBD method using Ar gas was make a prototype in accordance with the proposed design method. The characteristics jet fluid rate analysis of Ar gas was accomplished through simulation to determine the dependence of flow rate for the generation of plasma jets, and the characteristics of plasma jets using spectrometers were analyzed in the prototype system to generate optimal plasma jet bullet shapes through MFC flow control. Through the design method of the proposed system, the method of establishing the optimal plasma jet characteristics in the device and the results of active species on the EOS were verified.

• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.956-958
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• 1998

In this study, a relationship between partial discharge and the radiated electromagnetic waves is investigated by measuring electromagnetic waves using a biconical antenna and a spectrum analyzer. The patterns of frequency spectrum of radiated electromagnetic waves measured at the atmospheric pressure in Liquid Nitrogen($LN_2$) during the partial discharges in nonuniform electric field depend on positive DC power. From these points of view. it is considered that these results obtained from this investigation may be used as fundamental data for diagnosis and prediction of insulation on the equipments of superconducting and cryogenic applications.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.26 no.4
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• pp.294-297
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• 2013

ZnO crystals with octahedral shape were synthesized by thermal evaporation technique. $ZnF_2$ powder was used as the source material. The thermal evaporation and oxidation of $ZnF_2$ powder was carried out for 1 hr at $1,000^{\circ}C$ in air under atmospheric pressure. SEM images showed that the ZnO crystals produced by oxidizing $ZnF_2$ vapor possessed a characteristic octahedral shape. XRD spectrum revealed that the ZnO octahedron had hexagonal wurtzite structure. In the room temperature photoluminescence spectrum, a strong green emission peak at around 510 nm was observed.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.11b
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• pp.279-284
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• 2002

In this study, it has been developed the program for predicting the noise spectrum of axial flow fan. The radiated acoustic pressure is expressed the discrete frequency noise peaks at BPF(Blade passage frequency) and its harmonics by Wu's method and the line spectrum at the broad band by Wright's method. And this paper presents the characteristics of a fan noise due to modify the design parameters. Accordingly, it is obtained the design parameter values for noise reduction of fan.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.11a
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• pp.333.1-333
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• 2002

This paper suggests the noise reduction method of the engine cooling fan. It was estimated the fannoise contribution at the engine room and identified the noise source at the rotating fan by sound intensity method, first. And it has been developed the program for predicting the noise spectrum of axial flow fan. The radiated acoustic pressure is expressed the discrete frequency noise peaks at BPF and its harmonics and the line spectrum at the broad band by the noise generation mechanisms. In this paper it is shown that the comparison of the measuted and calculaed noise spectra of fn for the validation of the noise predictiong program. And this paper presents the characteristics of a fan noise due to modify the design parameters. Accordingly, it was obtained the design parameter values for noise reduction of fan.

• Journal of ILASS-Korea
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• v.9 no.3
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• pp.29-34
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• 2004

To investigate characteristics and micro-explosion of single-droplets of emulsified fuel, water is mixed with diesel oil by using ultrasonic energy fuel feeding system. The fuel characteristics is analysed through H-NMR spectrum and micro-explosion phenomena of the emulsified fuel is also investigated. The life times of droplets of conventional diesel fuel, ultrasonic energy added diesel fuel and emulsified fuel we obtained additionally. According to this study, the micro-explosion phenomena of single-droplets happen in atmospheric pressure condition, a curve form of emulsified fuel's life tim is different from diesel fuel's one and the change of chemical structures is a cause of ultrasonic-energy-added diesel fuel effect.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.05a
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• pp.1189-1194
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• 2002

Acoustic intensity is usually estimated by the cross-spectrum of acoustic pressure at two adjacent micrphones. The cross-spectrum calculated by digital Fourier transform technique will unavoidally have leakage error since the period of signal will not be usually coincident with record length. Therefore, the acoustic intensity estimated by the conventional r]n analyzer will show distorted value. In this paper the expression of the Fourier transformed data of a harmonic signal is formulated when there is leakage error. The method to elimate the effect of leakage error from the contaminated data is also proposed. Some numerical examples show the validation of the proposed method.