• Title/Summary/Keyword: preparation condition

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Preparation and Photocatalyric Properties of Organic-Inorganic Hybrid Abaca Cellulose@Titanium Dioxide Composite (유-무기 하이브리드 형 Abaca 셀룰로오스/이산화 티타늄 복합체의 제조 및 이의 광촉매적 특성)

  • Su-A, Kang;Young-Ho, Kim
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.57-63
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    • 2023
  • In this study, an organic-inorganic hybrid composite of Abaca nanocellulose and titanium dioxide was prepared. Abaca nanocellulose was prepared by oxidizing Abaca cellulose using TEMPO (2,2,6,6-tetramethyl-piperidine-1-oxyl) as a catalyst. Titanium dioxide nanoparticles were prepared by the sol-gel method, and a composite was prepared by hybridizing them with nanocellulose. As a result of comparing the properties of the composite and its physical properties according to the change in manufacturing pH, the effect of pH was very large when combining nanocellulose and titanium dioxide, and the optimal bonding performance was shown at pH 8 in this experimental condition. In addition, the prepared composite showed photocatalytic properties, and the higher the content of titanium dioxide, the higher the hydrophilicity of the composite according to UV light irradiation.

Preparation of rGO-S-CPEs Composite Cathode and Electrochemical Performance of All-Solid-State Lithium-Sulfur Battery

  • Chen, Fei;Zhang, Gang;Zhang, Yiluo;Cao, Shiyu;Li, Jun
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.362-368
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    • 2022
  • The application of polymer composite electrolyte in all-solid-state lithium-sulfur battery (ASSLSBs) can guarantee high energy density and improve the interface contact between electrolyte and electrode, which has a broader application prospect. However, the inherent insulation of the sulfur-cathode leads to a low electron/ion transfer rate. Carbon materials with high electronic conductivity and electrolyte materials with high ionic conductivity are usually selected to improve the electron/ion conduction of the composite cathode. In this work, PEO-LiTFSI-LLZO composite polymer electrolyte (CPE) with high ionic conductivity was prepared. The ionic conductivity was 1.16×10-4 and 7.26×10-4 S cm-1 at 20 and 60℃, respectively. Meanwhile, the composite sulfur cathode was prepared with Sulfur, reduced graphene oxide and composite polymer electrolyte slurry (S-rGO-CPEs). In addition to improving the ion conductivity in the cathode, CPEs also replaces the role of binder. The influence of different contents of CPEs in the cathode material on the performance of the constructed battery was investigated. The results show that the electrochemical performance of the all-solid-state lithium-sulfur battery is the best when the content of the composite electrolyte in the cathode is 40%. Under the condition of 0.2C and 45℃, the charging and discharging capacity of the first cycle is 923 mAh g-1, and the retention capacity is 653 mAh g-1 after 50 cycles.

Design and Development of Management System Standard Software for Aids to Navigation Based on S-201 (S-201 기반 항로표지 관리운영시스템 표준 SW 설계 및 개발)

  • Yeo, Ji-Min;Chae, Jeong-Geun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.25 no.12
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    • pp.1927-1934
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    • 2021
  • The AtoN are installed and operated on the sea in order to help the safe navigation of ships. With the development of maritime ICT, to monitor and control the condition of AtoN from land using multiplex communication network such as AtoN AIS, CDMA, and LTE. Currently, The information of AtoN is difficult to integrated manage because AtoN management systems has been independently developed and operatie according to the operating conditions of the Regional Office of Oceans and Fisheries. In addition, in preparation for the introduction for e-navigation and MASS, systematic and unified information of AtoN is required. In this paper, we study to design and develop standard software for AtoN management system based on the international standard for navigation information(S-201). Through this study, it will be possible to provide continuous AtoN information and effective AtoN management.

Analysis of a Two-Phases System of Mass Transfer and Electro-Reduction of Uranium(VI) in Nitric Acid-Hydrazine Media (질산-하이드라이진 매질에서 우라늄(VI)의 물질전달과 전기적 환원을 갖는 이 상계의 해석)

  • Kim, K.W.;Yoo, J.H.;Park, H.S.;Kim, J.D.;Aoyagi, H.;Yoshida, Z.
    • Nuclear Engineering and Technology
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    • v.27 no.2
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    • pp.216-225
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    • 1995
  • Simulation for a dynamic analysis of the electrolytic preparation of U(IV) in two-phases system, which consisted of mass transfer of U(VI) from TBP phase into HNO$_3$ solution and electrolytic re-duction of U(VI) to U(IV) at a cathode in aqueous phase, was carried out in order to establish the most suitable operating condition and best electrode area as basic design data for the system. It was found that maintaining an appropriate mass transfer rate was more significant rather than enlarging the surface area of the cathode for more effective production yield of U(IV). The electrode area and the operation time affected deeply the production composition of U(IV) in the resulting aqueous phase. And optimal electrode areas ore evaluated to meet production criteria of U(IV) of resulting solution in several system conditions. Though about 0.37M HNO$_3$ was preferable to prepare the solution of U(IV), nitric acid concentration should be higher than 0.5M to prevent a hydrolysis of U(IV) in the aqueous phase.

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Preparation and Characteristics of Soda Lime for Carbon Dioxide Absorption (이산화탄소 흡수를 위한 소다라임 제조 및 특성)

  • Young-Jin Kim;Seok-Je Kwon;Jun-Hyung Seo;Yang-Soo Kim;Kye-Hong Cho;Jin-Sang Cho
    • Resources Recycling
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    • v.32 no.2
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    • pp.52-58
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    • 2023
  • In this study, soda lime was prepared from slaked lime to expand the scope of limestone use. To evaluate carbon dioxide absorption, an extruder-type and disc-type pelletizers were used to make the soda lime using bentonite as an additive. Regardless of the pelletizing process, the peak of CaCO3 was confirmed in soda lime due to its reaction with carbon dioxide. Furthermore, it was confirmed that both calcite and aragonite were present together. The soda lime prepared using the disc-type pelletizer showed a larger specific surface area than that prepared using the extruder-type pelletizer did, and the specific surface area improved on adding bentonite. The carbon dioxide absorption rate increased under the sample condition with an enhanced specific surface area.

The coating of vitamin C on the surface of polymethylmethacrylate microsphere (Polymethylmethacrylate 입자에 표면에 비타민 C의 코팅)

  • Kim, Kyung-Hee;Choi, Seong-Ho
    • Analytical Science and Technology
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    • v.19 no.6
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    • pp.468-472
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    • 2006
  • This paper was described that the preparation of polymetylmethacrylate (PMMA) microsphere and coating of vitamin C onto surface of the prepared PMMA microsphere for application of cosmetic materials. The PMMA microsphere with various sizes can be obtained by change of reaction condition such as reaction temperature and reaction time. The coating of vitamin C on the surface of PMMA microsphere by using cyclodextrin as binder can be achieved to 30 wt-% in water/ethanol mixture. The vitamin C coated with cyclodextrin was stabilized during 56 days at $40^{\circ}C$. The color of the coated Vitamin C was changed from white to dark yellow after 14 days at $40^{\circ}C$. The vitamin C coated with cyclodextrin on the surface of PMMA microsphere can be sufficiently used for cosmetic materials.

Preparation and identification of U(IV) for the investigation of behaviors of uranium in a disposal repository (처분장에서 우라늄 거동 규명을 위한 U(IV)의 제조 및 확인)

  • Kim, Seung Soo;Kang, Kwang Chul;Kim, Jung Suck;Jung, Euo Chang;Baik, Min Hoon
    • Analytical Science and Technology
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    • v.21 no.2
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    • pp.143-147
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    • 2008
  • U(IV) ion, the valance state of uranium presumed at in a deep-depth disposal of a spent fuel, was prepared and separated from U(VI) ion. In order to prepare U(IV) ion, tests were performed by adding several reducing agents into a uranyl solution or by dissolution of uranium oxide in a mixed acid added with a reducing agent. The valance states of the uranium in the prepared solutions were identified by separating two ions with a Dowex AG 50W-X8 cation exchange resins and measuring the solutions using a laser-induced fluorescence spectroscopy. However, U(IV) and U(VI) were not separated by a Lichroprep Si60 exchange resin in the same separation condition of Pu(IV) and Pu(VI).

Simulation and Analysis of Wildfire for Disaster Planning and Management

  • Yang, Fan;Zhang, Jiansong
    • International conference on construction engineering and project management
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    • 2022.06a
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    • pp.443-449
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    • 2022
  • With climate change and the global population growth, the frequency and scope of wildfires are constantly increasing, which threatened people's lives and property. For example, according to California Department of Forestry and Fire Protection, in 2020, a total of 9,917 incidents related to wildfires were reported in California, with an estimated burned area of 4,257,863 acres, resulting in 33 fatalities and 10,488 structures damaged or destroyed. At the same time, the ongoing development of technology provides new tools to simulate and analyze the spread of wildfires. How to use new technology to reduce the losses caused by wildfire is an important research topic. A potentially feasible strategy is to simulate and analyze the spread of wildfires through computing technology to explore the impact of different factors (such as weather, terrain, etc.) on the spread of wildfires, figure out how to take preemptive/responsive measures to minimize potential losses caused by wildfires, and as a result achieve better management support of wildfires. In preparation for pursuing these goals, the authors used a powerful computing framework, Spark, developed by the Commonwealth Scientific and Industrial Research Organization (CSIRO), to study the effects of different weather factors (wind speed, wind direction, air temperature, and relative humidity) on the spread of wildfires. The test results showed that wind is a key factor in determining the spread of wildfires. A stable weather condition (stable wind and air conditions) is beneficial to limit the spread of wildfires. Joint consideration of weather factors and environmental obstacles can help limit the threat of wildfires.

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Optimization for Preparation of Malic acid-catalyzed Ginsenoside Rg3 by Response Surface Methodology (반응 표면 분석법을 이용한 홍삼 사포닌으로부터의 사과산 활용 진세노사이드 Rg3 전환 최적화)

  • Ki Seong Kim;Junseong Park
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.49 no.4
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    • pp.375-383
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    • 2023
  • Malic acid-catalyzed transformation has been developed to produce ginsenoside Rg3 which is increasingly in demand as a functional ingredient. The optimization of the conversion of red ginseng saponin (RGS) to ginsenoside Rg3 by acid catalyzed transformation was carried out using Box-Behnken design (BBD) based on Response Surface Analysis (RSM). The main independent variables were malic acid concentration, temperature, and reaction time. Conversion of ginsenoside Rg3 was performed according to BBD model and optimization conditions were analyzed. The concentration of the converted ginsenoside Rg3 ranged from 1.548 mg/L to 4.558 mg/L, and the highest production was obtained under the condition of reacting 1% malic acid, 50 ℃ and 9h. Consequently, The independent variables affecting the production of ginsenoside Rg3 were identified in the following order: malic acid concentration, reaction time and temperature. In addition, it was confirmed that the interaction between malic acid concentration and reaction time had a greater influence than the temperature.

Preparation of Flower-Like Al2O3 Nanostructures by Hydrothermal Synthesis and Study of Thermal Properties of BN/Al2O3 Composites (수열합성법을 이용한 Flower-Like 형상의 Al2O3 Nanostructure 제조 및 BN/Al2O3 복합체의 방열 특성 연구)

  • Noh Geon Song;Yong Jin Jeong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.6
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    • pp.633-637
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    • 2023
  • Recently, with the development of the smart device market, the integration of high-functional devices has increased the heat density, causing overload of the device, and resulting in various problems such as shortened lifespan, performance degradation, and failure. Therefore, research on heat dissipation materials is being actively conducted to realize next-generation electronic products. The heat dissipation material is characterized in that it is easy to dissipate heat due to its high thermal conductivity and minimizes leakage current flowing through the heat dissipation material due to its low electrical conductivity. In this study, flower-shaped Al2O3 and BN composites were engineered with a simple hydrothermal synthesis approach, and their thermal conductivity characteristics were compared and evaluated for each synthesis condition for the application to a heat dissipation material. Spherical BN and flower-shaped Al2O3 were easily obtained, and SEM/EDS analyses confirmed the uniform presence of BN between the Al2O3, and it can be expected that these shapes can affect the thermal conductivity.