• Title/Summary/Keyword: pozzolanic properties

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Hydration and mechanical properties of Blended Cement added Bypass dust (By-pass Dust를 첨가한 혼합 시멘트의 수화 및 기계적 특성)

  • 성진욱;나종윤;김창은;이승헌;이봉한;김수룡;류한웅
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.33-39
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    • 1999
  • This study was conducted to confirm the effect of bypass dust on the hydration and mechanical properties of the cement pastes and mortar obtained from ordinary Portland cement (OPC), OPC-slag and OPC-fly ash system. The rate of heat evolution is accelerated with the content of By-pass Dust(BD). total heat evolution increased because alkali-chlorides activated the hydration of blended cement. Compressive strength and bound water content show maximum value at 5wt% By-pass Dust(BD) on each curing time in ordinary Portland cement and slag blended cement. Ca(OH)2 content of Ordinary Portland Cement increased as the content of BD and curing time. In blended cement, the formation of Ca(OH)2 is active at early hydration stage. By pozzolanic reaction, the content of Ca(OH)2 is decreased as curing time goes by. According to the BD content stable chlorides complex of Friedel's salt (C3A·CaCl2·10H2O) is created. Due to the hydration activation effect of chlorides and alkali we observed Type II C-S-H, which developed into densest microstructure.

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The Strength Properties of Concrete according to Curing Method (양생방법에 따른 콘크리트의 강도특성)

  • Jung, Yong-Wook;Lee, Seung-Han;Yun, Yong-Ho;Son, Sang-Hun;Kim, Jeong-Tai
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.545-548
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    • 2006
  • This study has been carried out to examine the properties of concrete according to replacement ratio and curing method of fly ash, in order to increase utilization of it. As the result of experiments, the 7 days of early age strength presented around 20MPa, up to 20% of replacement ratio, which is almost the same strength as non-replacement. However, when the replacement ratio was 30%, the strength was decreased to 16MPa, as 20% reduction compared to the non-replacement condition. In 365 days of long term aging, the strength was 5% higher, up to 20% of the replacement ratio, due to the pozzolanic reaction of fly ash. When the replacement ratio was 30%, it presented similar strength development as the non-replacement condition. Steam curing and autoclave curing increased the short age strength, regardless of the replacement ratio of fly ash; however, they don't have an effect on increasing the 365 days of long term strength. Water curing showed high strength development after 28 days, 51.81MPa, which is around 30% higher than air curing, 38.9MPa, steam curing, 38.6MPa, and autoclave curing, 39MPa. Therefore, water curing was examined as one of the very effective curing methods for developing long term strength of concrete.

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Cavitation resistance of concrete containing different material properties

  • Kumar, G.B. Ramesh;Bhardwaj, Arjit;Sharma, Umesh Kumar
    • Advances in concrete construction
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    • v.6 no.1
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    • pp.15-28
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    • 2018
  • In the present investigation, influence of various material parameters on the cavitation erosion resistance of concrete was investigated on the basis of laboratory experiments. As there is no well-established laboratory test method for evaluating the cavitation resistance of concrete, a test set up called 'cavitation jet' was specially established in the present study in order to simulate the cavitation phenomenon experienced in the hydraulic structures. Various mixtures of concrete were designed by varying the grade of concrete, type and quantity of pozzolana, type of aggregates and cement type to develop good cavitation resistant concrete constructed using marginal aggregates. Three types of aggregates having three different Los Angeles abrasion values (less than 30%, between 30% and 50% and more than 50%) were employed in this study. To evaluate the cavitation resistance a total of 60 cylindrical specimens and 60 companion cubes were tested in the laboratory respectively. The results indicate that cavitation resistance of concrete degrades significantly as the L.A. abrasion value of aggregates goes beyond the 30% value. Incorporation of pozzolanic admixtures was seemed to be beneficial to enhance the cavitation resistance of concrete. Influence of other material parameters on the cavitation resistance of concrete was also noted and important observations have been made in the paper.

Experimental Study on the Chloride Invasion Resistance Properties of Concrete Containing Mineral Admixtures (혼화재 혼입 콘크리트의 염화물 침투저항성에 관한 실험적 연구)

  • Yoo, Jae-Kang;Kim, Dong-Seuk;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.11a
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    • pp.43-48
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    • 2003
  • This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for 3~4 replacement ratios under W/B ratios ranged from 0.40 to 0.55. For the electrical migration test, Tang and Nilsson's method was used to estimate the migration coefficient of chloride ion. As a results, the W/B ratios, kinds of admixture and replacement ratios, water curing periods had a great effect on the migration coefficient of chloride ion, and the optimal replacement ratios of admixture had a limitation for each admixtures. Also, the addition of mineral admixtures by mass(replacement of OPC) enhanced the resistance of the mixture to chloride penetration compared with the plain concrete. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures. The compressive strength was shown related to the migration coefficient of chloride ion, the compressive strength increased with the decreasing migration coefficient of chloride ion. Below the 50MPa, the variation of migration coefficient of concrete added mineral admixtures was bigger than plain concrete.

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Study properties of soft subgrade soil stabilized by sewage sludge/lime and nano-SiO2

  • Lin, Deng-Fong;Luo, Huan-Lin;Chen, Chien-Ta;Cai, Ming-Du
    • Geomechanics and Engineering
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    • v.10 no.6
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    • pp.793-806
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    • 2016
  • The pozzolanic characteristics of a sludge incinerated into ash were determined in this study. Lime is commonly used as a stabilizer for the treatment of soils, whereas sewage sludge ash (SSA) is often applied with lime to improve soft subgrade soil. In this study, a cohesive soil categorized as A-4 (low-plasticity clay) by AASHTO classifications was mixed with SSA/lime with a 3:1 ratio. Nano-$SiO_2$ was also added to the soil. To identify changes in the workability, strength, permeability, and shear strength of the soft subgrade soil, basic soil tests were conducted, and the microstructure of the treated soil was analyzed. The results indicate that SSA/lime mixtures improve the properties of soft subgrade soil and transform the soil from "poor subgrade soil" to "good to excellent subgrade soil" with a CBR > 8. Additionally, the addition of 2% nano-$SiO_2$ increases the unconfined compressive strength of soft subgrade soil treated with SSA/lime mixture by approximately 17 kPa. However, the swelling of the treated soil increased by approximately 0.1% after the addition of nano-$SiO_2$ and lime. Thus, soil swelling should be considered before lime and nano-$SiO_2$ are applied to soft subgrade soil.

Copper or ferrous slag as substitutes for fine aggregates in concrete

  • Thomas, Job;Thaickavil, Nassif N.;Abraham, Mathews P.
    • Advances in concrete construction
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    • v.6 no.5
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    • pp.545-560
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    • 2018
  • The ever-increasing cost of natural sand and the environmental impacts of extracting manufactured sand (quarry sand) calls for exploring the potential to use alternative materials as fine aggregates in concrete. Copper slag and ferrous slag are industrial by products obtained from the smelting process of copper and iron respectively. A large quantity of copper slag and ferrous slag end up being disposed as waste in landfills and this poses a serious threat to the environment. Copper slag and ferrous slag have similar physical and chemical properties as natural sand and also exhibit pozzolanic activity. This paper studies the technical feasibility of industrial by-products such as copper slag and ferrous slag to replace the fine aggregate in concrete by evaluating the workability, strength and durability characteristics of concrete. The test results indicate that the strength properties are not affected by 40% or 100% replacement of quarry sand with iron slag or copper slag. However, 40% replacement of quarry sand with iron slag or copper slag in concrete is recommended considering the durability aspects of concrete.

Mechanical properties and microstructures of stabilised dredged expansive soil from coal mine

  • Chompoorat, Thanakorn;Likitlersuang, Suched;Sitthiawiruth, Suwijuck;Komolvilas, Veerayut;Jamsawang, Pitthaya;Jongpradist, Pornkasem
    • Geomechanics and Engineering
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    • v.25 no.2
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    • pp.143-157
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    • 2021
  • Expansive soil is the most predominant geologic hazard which shows a large amount of shrinkage and swelling with changes in their moisture content. This study investigates the macro-mechanical and micro-structural behaviours of dredged natural expansive clay from coal mining treated with ordinary Portland cement or hydrated lime addition. The stabilised expansive soil aims for possible reuse as pavement materials. Mechanical testing determined geotechnical engineering properties, including free swelling potential, California bearing ratio, unconfined compressive strength, resilient modulus, and shear wave velocity. The microstructures of treated soils are observed by scanning electron microscopy, x-ray diffraction, and energy dispersive spectroscopy to understand the behaviour of the expansive clay blended with cement and lime. Test results confirmed that cement and lime are effective agents for improving the swelling behaviour and other engineering properties of natural expansive clay. In general, chemical treatments reduce the swelling and increase the strength and modulus of expansive clay, subjected to chemical content and curing time. Scanning electron microscopy analysis can observe the increase in formation of particle clusters with curing period, and x-ray diffraction patterns display hydration and pozzolanic products from chemical particles. The correlations of mechanical properties and microstructures for chemical stabilised expansive clay are recommended.

Sustainable controlled low-strength material: Plastic properties and strength optimization

  • Mohd Azrizal, Fauzi;Mohd Fadzil, Arshad;Noorsuhada Md, Nor;Ezliana, Ghazali
    • Computers and Concrete
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    • v.30 no.6
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    • pp.393-407
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    • 2022
  • Due to the enormous cement content, pozzolanic materials, and the use of different aggregates, sustainable controlled low-strength material (CLSM) has a higher material cost than conventional concrete and sustainable construction issues. However, by selecting appropriate materials and formulations, as well as cement and aggregate content, whitethorn costs can be reduced while having a positive environmental impact. This research explores the desire to optimize plastic properties and 28-day unconfined compressive strength (UCS) of CLSM containing powder content from unprocessed-fly ash (u-FA) and recycled fine aggregate (RFA). The mixtures' input parameters consist of water-to-cementitious material ratio (W/CM), fly ash-to-cementitious materials (FA/CM), and paste volume percentage (PV%), while flowability, bleeding, segregation index, and 28-day UCS were the desired responses. The central composite design (CCD) notion was used to produce twenty CLSM mixes and was experimentally validated using MATLAB by an Artificial Neural Network (ANN). Variance analysis (ANOVA) was used for the determination of statistical models. Results revealed that the plastic properties of CLSM improve with the FA/CM rise when the strength declines for 28 days-with an increase in FA/CM, the diameter of the flowability and bleeding decreased. Meanwhile, the u-FA's rise strengthens the CLSM's segregation resistance and raises its strength over 28 days. Using calcareous powder as a substitute for cement has a detrimental effect on bleeding, and 28-day UCS increases segregation resistance. The response surface method (RSM) can establish high correlations between responses and the constituent materials of sustainable CLSM, and the optimal values of variables can be measured to achieve the desired response properties.

Effects of Limestone Powder and Silica Fume on the Hydration and Pozzolanic Reaction of High-Strength High-Volume GGBFS Blended Cement Mortars (고강도 고함량 고로슬래그 혼합 시멘트 모르터의 수화 및 포졸란 반응에 미치는 석회석 미분말과 실리카퓸의 영향)

  • Jeong, Ji-Yong;Jang, Seung-Yup;Choi, Young-Cheol;Jung, Sang-Hwa;Kim, Sung-Il
    • Journal of the Korea Concrete Institute
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    • v.27 no.2
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    • pp.127-136
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    • 2015
  • To evaluate the effects of limestone powder and silica fume on the properties of high-strength high-volume ground granulated blast-furnace slag (GGBFS) blended cement concrete, this study investigated the rheology, strength development, hydration and pozzolanic reaction characteristics, porosity and pore size distribution of high-strength mortars with the water-to-binder ratio of 20, 50 to 80% GGBFS, up to 20% limestone powder, and up to 10% silica fume. According to test results, compared with the Portland cement mixture, the high-volume GGBFS mixture had much higher flow due to the low surface friction of GGBFS particles and higher strength in the early age due to the accelerated cement hydration by increase of free water; however, because of too low water-to-binder ratio and cement content, and lack of calcium hydroxide content, the pozzolanic reactio cannot be activated and the long-term strength development was limited. Limestone powder did not affect the flowability, and also accelerate the early cement hydration. However, because its effect on the acceleration of cement hydration is not greater than that of GGBFS, and it does not have hydraulic reactivity unlikely to GGBFS, compressive strength was reduced proportional to the replacement ratio of limestone powder. Also, silica fume and very fine GGBFS lowered flow and strength by absorbing more free water required for cement hydration. Capillary porosities of GGBFS blended mortars were smaller than that of OPC mortar, but the effect of limestone powder on porosity was not noticeable, and silica fume increased porosity due to low degree of hydration. Nevertheless, it is confirmed that the addition of GGBFS and silica fume increases fine pores.

The effects of limestone powder and fly ash as an addition on fresh, elastic, inelastic and strength properties of self-compacting concrete

  • Hilmioglu, Hayati;Sengul, Cengiz;Ozkul, M. Hulusi
    • Advances in concrete construction
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    • v.14 no.2
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    • pp.93-102
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    • 2022
  • In this study, limestone powder (LS) and fly ash (FA) were used as powder materials in self-compacting concrete (SCC) in increasing quantities in addition to cement, so that the two powders commonly used in the production of SCC could be compared in the same study. Considering the reduction of the maximum aggregate size in SCC, 10 mm or 16 mm was selected as the coarse aggregate size. The properties of fresh concrete were determined by slump flow (including T500 time), V-funnel and J-ring experiments. The experimental results showed that as the amount of both LS and FA increased, the slump flow also increased. The increase in powder material had a negative effect on V-funnel flow times, causing it to increase; however, the increase in FA concretes was smaller compared to LS ones. The increase in the powder content reduced the amount of blockage in the J-ring test for both aggregate sizes. As the hardened concrete properties, the compressive and splitting strengths as well as the modulus of elasticity were determined. Longitudinal and transverse deformations were measured by attaching a special frame to the cylindrical specimens and the values of Poisson's ratio, initiation and critical stresses were obtained. Despite having a similar W/C ratio, all SCC exhibited higher compressive strength than NVC. Compressive strength increased with increasing powder content for both LS and FA; however, the increase of the FA was higher than the LS due to the pozzolanic effect. SCC with a coarse aggregate size of 16 mm showed higher strength than 10 mm for both powders. Similarly, the modulus of elasticity increased with the amount of powder material. Inelastic properties, which are rarely found in the literature for SCC, were determined by measuring the initial and critical stresses. Crack formation in SCC begins under lower stresses (corresponding to lower initial stresses) than in normal concretes, while critical stresses indicate a more brittle behavior by taking higher values.