• Title/Summary/Keyword: pozzolanic materials

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The Effect of Seawater on Hydration of Clinker Minerals (I) Effects of SO42- and Cl- ions (시멘트 클린커 광물의 수화에 미치는 해수성분의 영향 (I)SO42- 및 Cl-이온에 의한 영향)

  • 신도철;송태웅;한기성;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.1
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    • pp.77-85
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    • 1987
  • Hardened cement paste is mainly affected by corrosion of sulphate and chlorine ions in sea water. In this investigation, many specimens were made with the cement clinker minerals such as C3S, C3A, C4AF and their mixture according to cement composition added various blending materials. After the specimens were immersed in 4% MgSO4 and MgCl2 solutions, the product of reaction, the microstructure of specimen and Ca+2 ion leached in the solution were studied. The formation of Ca(OH)2 in the specimen of C3S is reduced relatively by adding pozzolanic admixtures. The chlorine ion is easily diffuse into the C3S specimen and produced CaCl2 compound, and it makes the specimen porous by leaching out itself into the solution. The specimen of C3A, C4AF are broken down by expanding reaction of ettringite and gypsum compound produced in the MgSO4 solution. At a later period, the ettringite is transformed into gypsum and 5MgO.2Al2O3·15H2O. The C3A in the MgCl2 solution combines chlorine ion to form Friedel's salt and prevents the diffusion reaction of chlorine ion into the specimen. Granulated slag shows inferior effect on the resistance of the specimen in MgSO4 solution by forming ettringite and gypsum, but good result in MgCl2 solution. Pozzolanic materials, on the whole, offer noticable effect on the resistance of the specimen in both solutions.

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Pozzolanicity of Calcined Sewage Sludge with Calcination and Fineness Conditions (소성조건 및 분말도에 따른 소성하수슬러지(CSS)의 포졸란 특성)

  • So, Hyoung-Seok;So, Seung-Young;Khulgadai, Janchivdorj;Kang, Jae-Hong;Lee, Min-Hi
    • Journal of the Korea Concrete Institute
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    • v.27 no.1
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    • pp.65-73
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    • 2015
  • This study discussed the pozzolanic properties of calcined sewage sludge (CSS) according to calcination and fineness conditions. The chemical and mineralogical analysis of CSS according to calcination temperature and time were carried out and compared with that of the existing pozzolanic materials such as fly-ash, blast furnance slag and meta-kaolin. Various mortars were made by mixing those CSS and $Ca(OH)_2$ (1:1 wt. %), and their compressive strength and hydrates according to experimental factors such as fineness of CSS and curing age were also investigated in detail. The results show clearly the potentiality of calcined sewage sludge (CSS) as an admixture materials in concrete, but the CSS should be controlled by calcination temperature and time, and fineness etc. In this experimental condition, the calcination temperature of $800^{\circ}C$, calcination time of 2 hours and fineness of $5,000cm^2/g$ were optimum conditions in consideration of the mechanical properties and economic efficiency of CSS. The compressive strength of CSS mortars was higher than that of fly-ash mortars and blast furnace slag mortars, especially at the early ages. Then, the utilization of CSS in construction fields was greatly expected.

A Study on the Capability to Use with Admixture Material of Paper Sludge Ash (제지 슬러지 소각회의 시멘트 혼화 재료로서의 이용 가능성에 관한 연구)

  • 김재진;문경주;노병남;문성필;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.89-92
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    • 1999
  • The purpose of this study is to evaluate the capability to use with cement admixture materials because Paper Sludge Ash consists of Si, Ca and Al which are chief content in Pozzolan. For the derivation of Pozzolanic reaction in Paper Sludge Ash, it is measured compressive strength on cement mortar which is replaced mixing of Paper Sludge Ash and inorganic admixture ; ie, gypsum, lime and slaked lime, regularly. In the result of test, the strength decrease remarkably when cement is only replaced with Paper Sludge Ash, but the strength is almost equal when cement is replaced with Paper Sludge Ash is mixed with inorganic admixture material in proportions of 5~15%. Consequently, It is possible to use Paper Sluge Ash with admixture materials of cement.

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Study on the Pozzolan Reaction Degree of Palm Oil Fuel Ash as a Mineral Admixture for Sustainable Concrete (POFA를 혼입한 시멘트의 포졸란 반응에 관한 연구)

  • Lee, Hyung-Min;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.335-336
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    • 2010
  • This paper presents experimentally investigated the effects of pozzolan made from various by-Product materials on mechanical properties of mortar. Fly ash(FA), slag (BFS), and palm oil fuel ash (POFA) were partially used to replace Portland cement. The results suggest that mortars containing FA, BFS, and POFA can be used as pozzolanic materials in making concrete with 28day compressive strength. After curing, the mortar containing 10-30% FA or POFA, and 30% BFS exhibited compressive strengths that of the original Portland cement (OPC). The use of FA, POFA, and BFS to partially replace Portland cement has evaluation method of the Assessed Pozzolan-activity index.(API)

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A Study on Development of Construction Material using Sewage Sludge Ash (하수슬러지 소각재를 이용한 건설자재 개발에 관한 연구)

  • Jo Byung-Wan;Shin Kyung-Chul;Park Jong-Bin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.687-690
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    • 2004
  • The discharge of sewage sludge ash that is rapidly increasing in Korea. The utilization of sewage sludge ash would contribute to the elimination of an environmental problem and to the development of new high-performance materials. So the paper is focused on an experimental study in order to investigate the utilization of sewage sludge ash as the construction materials. It achieves leaching test, chemical composition and compressive strength test. As a result of tests, the sewage sludge ash has sufficient potential for use of pozzolanic raw material. However. it is judged to be available to construction material if research is continuously gone.

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Hydration Characteristics Analysis of Conductive Grout Materials using XRD (X-선 회절분석을 활용한 전도성 그라우트재의 수화특성)

  • Im, Geon-Woo;Lim, Chang-Min;Kim, Young-Min;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.35-36
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    • 2023
  • In this study, the hydration characteristics of conductive grout materials for each binder were investigated using XRD, and as a result of the experiment, the specimen with UFFA consumed more Ca(OH)2 than the specimen with other binders, which is judged to have activated the pozzolanic reaction of UFFA, a high powder.

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Waste glass powder and its effect on the fresh and mechanical properties of concrete: A state of the art review

  • He, Zhi-hai;Yang, Ying;Zeng, Hao;Chang, Jing-yu;Shi, Jin-yan;Liu, Bao-ju
    • Advances in concrete construction
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    • v.10 no.5
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    • pp.417-429
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    • 2020
  • Waste glass is a global solid waste with huge reserves. The discarded waste glass has caused a series of problems such as resource waste and environmental pollution, so it is urgent to recycle waste glass with high replacement level. Glass powder (GP), as a supplementary cementitious material (SCM), used in cement-based materials has already become one of the important ways to recycle waste glass mainly attributed to its pozzolanic reaction and filling effect, especially to the suppressed ASR expansion. This paper demonstrates an overview of the properties of GP and its effect on the fresh and mechanical properties of cement-based materials. The study found that the influence of GP on the performance of cement-based materials mainly depends on its content, particle size, color and type, curing conditions, and other SCMs. Finally, based on the problems involved in the investigation of concrete containing GP, some corresponding suggestions and efforts are given to further guide the utilization of GP in cement-based materials.

Contribution to the development of tiles made of paper board sludge

  • Velumani, P.;Manikandan, P.
    • Advances in environmental research
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    • v.9 no.4
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    • pp.285-294
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    • 2020
  • Growth of any country rest in the consumption of industrial wastes for its infrastructure amenities. Countries like India positively desires a vital utilization of industrial waste resembling paper sludge in the construction industry to make various building materials. Also, it is the duty of all civil engineers or researchers to attach them in mounting new materials from the waste dumped as land fillings. In every construction project, about 70% of cost accounts for the procurement of materials. If this, can be minimized consequently the cost of construction will certainly be condensed. Research has established that the waste paper sludge can be reused in the construction field for a probable scope. The construction diligences munch through a massive quantity of non-renewable resources. On the additional dispense, more waste paper board sludge ends up in landfills or dumpsites than those recycled. Consequently, waste paper sludge for use as a construction material composes a step towards sustainable development. Keeping this in mind an endeavor has been made to utilize paper board sludge acquired from the paper board industry and used with several pozzolanic and cementitious materials for a specific purpose. The addition of paper sludge has been varied from 0% to 20% by weight of cement. The tests done with the samples expose that four samples showed significant outcomes with remarkable strength and durability properties which guide to move for the next phase of research for producing lightweight tiles.

Effects of using silica fume and lime in the treatment of kaolin soft clay

  • Alrubaye, Ali Jamal;Hasan, Muzamir;Fattah, Mohammed Y.
    • Geomechanics and Engineering
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    • v.14 no.3
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    • pp.247-255
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    • 2018
  • Soil stabilization can make the soils becoming more stable by using an admixture to the soil. Lime stabilization enhances the engineering properties of soil, which includes reducing soil plasticity, increasing optimum moisture content, decreasing maximum dry density and improving soil compaction. Silica fume is utilized as a pozzolanic material in the application of soil stabilization. Silica fume was once considered non-environmental friendly. In this paper, the materials required are kaolin grade S300, lime and silica fume. The focus of the study is on the determination of the physical properties of the soils tested and the consolidation of kaolin mixed with 6% silica fume and different percentages (3%, 5%, 7% and 9%) of lime. Consolidation test is carried out on the kaolin and the mixtures of soil-lime-silica fume to investigate the effect of lime stabilization with silica fume additives on the consolidation of the mixtures. Based on the results obtained, all soil samples are indicated as soils with medium plasticity. For mixtures with 0% to 9% of lime with 6% SF, the decrease in the maximum dry density is about 15.9% and the increase in the optimum moisture content is about 23.5%. Decreases in the coefficient of permeability of the mixtures occur if compared to the coefficient of permeability of kaolin soft clay itself reduce the compression index (Cc) more than L-SF soil mix due to pozzolanic reaction between lime and silica fume and the optimum percent of lime-silica fume was found to be (5%+6%) mix. The average coefficient of volume compressibility decreases with increasing the stabilizer content due to pozzolanic reaction happening within the soil which results in changes in the soil matrix. Lime content +6% silica fume mix can reduce the coefficient of consolidation from at 3%L+6%SF, thereafter there is an increase from 9%L+6%SF mix. The optimal percentage of lime silica fume combination is attained at 5.0% lime and 6.0% silica fume in order to improve the shear strength of kaolin soft clay. Microstructural development took place in the stabilized soil due to increase in lime content of tertiary clay stabilized with 7% lime and 4% silica fume together.

Fluidity of Cement Paste and Fluidity and Compressive Strength of Cement Mortar Substituted by Pozzolanic fine Powders and II-Anhydrite (포졸란계 미분말과 ∥ 형 무수석고 치환 시멘트 페이스트 유동성과 시멘트 모르타르의 유동성 및 압축강도)

  • 노재성;이범재;김도수;이병기
    • Magazine of the Korea Concrete Institute
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    • v.9 no.3
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    • pp.149-156
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    • 1997
  • In order to improve compressive strength of cement mortar, powder admixture(FAS) was mmufactured by mixing fly ash. Il-anhydite and silica hume, and superplasticizer was used for the control of fluidity reduction with the use of this admixture. Cement was substituted by 10, 20wt% of FAS respectively. At W/S = 0.40, the fluidity of' cement paste substituted by PAS was decreased. NSF and NT-2 were very effective fbr the control of fluidity reduction. As the particle size of U -anhydrite was fine, the fluidity of cement mortar was increased. The fluidity reduction of cement mortar substituted by 10wt% of FAS was controlled. The compressive strength of cement mortar substituted by 10wt% of FAS showed higher. value than that of 20wt%, expecially specimen(C1) substituted by 10wt% of $\gamma$ had the highest compressive strength value.