• 제목/요약/키워드: powder method

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고체산화물 연료전지용 나노 YSZ전해질 분말 합성 및 단위셀의 전기화학적 평가 (Electrochemical Studies and Chemical Synthesis of Nanoscale YSZ Electrolyte Powder for Solid Oxide Fuel Cell)

  • 신유철;김영미;김호성
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.299-302
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    • 2009
  • Oxygen ionic conductors of YSZ electrolyte in SOFC unit cell are applied to anode and cathode as well as electrolyte to have triple-phase-boundaries(TPB) of electrochemical reaction, and it is required to decrease the sintering temperature of anode-supported electrolyte by the nanoscale of YSZ powder.In this report, nanoscale YSZ powder was synthesized by the chemical co-precipitation method. The particle size, surface area and morphology of the powder were observed by SEM and BET. Thin film electrolyte of under 10㎛ was fabricated by tape casting using the synthesized YSZ powder, and ionic conductivity and gas permiability of electrolyte film were evaluated. Finally, the SOFC unit cell was fabricated using the anode-supported electrolyte prepared by a tape casting method and co-sintering. Electrochemical evauations of the SOFC unit cell, including measurements such as power density and impedance, were performed and analyzed.

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화학적합성법에 의한 나노 고체 전해질 분말 합성 및 전기화학적 평가 (Electrochemical studies of nano-scale solid electrolyte powder prepared by chemical synthesis process)

  • 김영미;신유철;김호성
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.295-298
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    • 2009
  • Oxygen ionic conductors of CeScSZ electrolyte in SOFC unit cell are applied to anode and cathode as well as electrolyte to have the triple-phase-boundaries of electrochemical reaction, and it is required to decrease the sintering temperature of anode-supported electrolyte by the nanoscale of CeScSZ electrolyte powder. In this report, nanoscale CeScSZ electrolyte powder was synthesized by chemical synthesis method. The particle size, surface area and morphology of the powder were observed by SEM and BET. Thin film electrolyte of under $10{\mu}m$ was fabricated by tape casting using the synthesized CeScSZ electrolyte powder, and ionic conductivity and gas permeability of electrolyte film were evaluated. Finally the SOFC unit cell was fabricated using the anode-supported electrolyte prepared by a tape casting method and co-sintering, in which the active layer, measuring $20{\mu}m$, was introduced in the anode layer to provide a more efficient reaction. Electrochemical evaluations of the SOFC unit cell, including measurements such as power density and impedance, were performed and analyzed.

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Experimental and numerical investigations of the influence of reducing cement by adding waste powder rubber on the impact behavior of concrete

  • Al-Tayeb, Mustafa Maher;Abu Bakar, B.H.;Akil, Hazizan Md.;Ismail, Hanafi
    • Computers and Concrete
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    • 제11권1호
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    • pp.63-73
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    • 2013
  • In this study, the effect of reducing cement by proportional addition of waste powder rubber on the performance of concrete under impact three-point bending loading were investigated experimentally and numerically. Concrete specimens were prepared by adding 5%, 10% and 20 % of rubber powder as filler to the mix and decreasing the same percentage of cement. For each case, three beams of $50mm{\times}100mm{\times}500mm$ were loaded to failure in a drop-weight impact machine by subjecting them to 20 N weight from 300mm height, while another three similar beams were tested under static load. The bending load-displacement behavior was analyzed for the plain and rubberized specimens, under static and impact loads. A three dimensional finite-element method simulation was also performed by using LUSAS V.14 in order to study the impact load-displacement behavior, and the predictions were validated with the experimental results. It was observed that, despite decreasing the cement content, the proportional addition of powder rubber until 10% could yield enhancements in impact tup, inertial load and bending load.

유한요소법을 이용한 등통로각압출 공정의 마그네슘 분말 고형화 거동 해석: 피복재 효과 (Finite Element Analysis of Densification of Mg Powders during Equal Channel Angular Pressing: Effect of Sheath)

  • 윤승채;김택수;김형섭
    • 한국분말재료학회지
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    • 제16권2호
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    • pp.85-90
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    • 2009
  • Magnesium and its alloys are attractive as light weight structural/functional materials for high performance application in automobile and electronics industries due to their superior physical properties. In order to obtain high quality products manufactured by the magnesium powders, it is important to control and understand the densification behavior of the powders. The effect of the sheath surrounding the magnesium powders on the plastic deformation and densification behavior during equal channel angular pressing was investigated in the study by experimental and the finite element methods. A modified version of Lee-Kim's plastic yield criterion, notably known as the critical relative density model, was applied to simulate the densification behavior of magnesium powders. In addition, a new approach that extracts the mechanical characteristics of both the powder and the matrix was developed. The model was implemented into the finite element method, with which powder compaction under equal channel angular pressing was simulated.

직접식 조형법의 금속 분말 적층부 소결에 관한 연구 (Numerical Analysis for Sintering of Metal Powder Layers of the Direct Metal Prototyping)

  • 손현기;양동열
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 1997년도 춘계학술대회 논문집
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    • pp.552-556
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    • 1997
  • The Direct Metal Prototyping(DMP), one of the rapid prototyping technologies, allows the manufacturing of three-dimensional metallic parts using metal powders directly from the CAD data. Laser power and scanning speed are the most important variables of the process. The objective of this study is to obtain the design data for laser power and scanning speed to bond metal powders effectively using the finite element method. To obtain the design values, a numerical analysis considering two-dimensional heat transfer during the sintering of metal powder layers of the process was performed. The laser beam has been modeled to have directionality in its heat flux distribution, i. e., in the scanning direction a Gaussian beam mode distribution has been assumed and in the thickness direction a square beam mode distribution. The three-dimensional irregular distribution of metal powders of the powder layer is idealized as two-dimensional distribution in which metal powders are located regularly and periodically on the plate. In this study the design values of laser power vs scanning speed have been obtained. Temperature distribution and temperature variation of the powder layers with respect to time have been predicted. The commputed dsign data will be useful in determining the initial conditions of the process.

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홉킨스바 장치를 이용한 분말금속의 동적 특성에 관한 수치해석적 연구 (A Numerical Study on the Dynamic Characteristics of Power Metal using Split Hopkinson Pressure Bar)

  • 황두순;이승우;홍성인
    • 대한기계학회논문집A
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    • 제24권12호
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    • pp.2972-2979
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    • 2000
  • Dynamic characteristics of powder metal is very important to mechanical structures requiring high strength or endurance for impact loading. But owing to distinctive property of powder metal, that is relative, it has been investigated restrictively compared to static characteristics. The objectives of this study is to investigate dynamic characteristics of powder metal and compare it to a fully density material. To find the characteristics, an explicit finite element method is used for simulation of Split Hopkinson Pressure Bar experiment based on the stress wave propagation theory. We obtained a dynamic stress-strain relationship and dynamic behavior of powder metal, as well as the variation of material properties during dynamic deformation.

Investigation of Goats' Milk Adulteration with Cows' Milk by PCR

  • Cheng, Yeong-Hsiang;Chen, Su-Der;Weng, Ching-Feng
    • Asian-Australasian Journal of Animal Sciences
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    • 제19권10호
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    • pp.1503-1507
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    • 2006
  • Goats' milk adulteration with cows' milk is becoming a big problem. In the past, the urea-polyacrylamide gel electrophoresis assay with different motility of ${\alpha}S1$-casein has been applied for the identification of cows' milk adulteration. The detection sensitivity is 1.0%. The aim of this study was to develop a faster and more sensitive method to detect cows' milk which may be present in adulterated goats' milk and goats' milk powder. The published primer was targeted at highly conserved regions in bovine mitochondrial DNA (a 271 bp amplicon). This amplicon was cloned and sequenced to further confirm bovine specific sequence. The chelex-100 was used to separate bovine somatic cells from goats' milk or goats' milk powder samples. Random sampling of different brands of goats' milk powder and tablets from various regions of Taiwan showed the adulterated rate was 20 out of 80 (25%) in goats' milk powders and 12 out of 24 (50%) in goats' milk tablets. With this system, as low as 0.1% cows' milk or cows' milk powder in goat milk or goat milk powder could be identified. This chelex DNA isolation approach provides a fast, highly reproducible and sensitive method for detecting the adulteration of goats' milk products.

분말재료의 복소 유전율 및 투자율 측정 (Measurement of Complex Permittivity and Permeability for Powder-type Materials)

  • 박상복;이장수;정용식;천창율
    • 전기학회논문지
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    • 제56권12호
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    • pp.2196-2201
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    • 2007
  • Materials used at microwave are usually used as a dielectric with a manufacturing purpose of printed circuit boards, etc. Complex permittivity of them can be measured from attenuation constant or propagation constant of a transmission line using a microstrip line with bulk type. But as the technique recently which can manufacture to have complex permittivity and permeability demanded using nonferrous metals for powder-type grows up, we need sensors and methods which can measure characteristics of powder-type materials. So far measuring methods of permittivity and permeability with waveguide or coaxial cable are used but they have faults which have a complex measurement method and are difficult to simultaneously measure permittivity and permeability. In this paper, a simultaneous measuring method of permittivity and permeability with 2-port coaxial cable and a new proposed calculation. The proposed 2-port coaxial cable is designed to be easy to insert materials and to have a wideband. We measure permittivity and permeability of magnetic powder(Ni-Fe-Mo, Ni-Fe) which reveal its characteristic at $0.3{\sim}1.3GHz$ to identify the proposed sensor.

열간등가압소결 공정에서 유한요소법을 이용한 컨테이너 형상의 최적설계 (Optimal Shape Design of a Container Under Hot Isostatic Pressing by a Finite Element Method)

  • 정석환;박환;전경달;김기태;황상무
    • 대한기계학회논문집A
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    • 제24권9호
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    • pp.2211-2219
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    • 2000
  • Near net shape forming of 316L stainless steel powder was investigated under hot isostatic pressing. To simulate densification and deformation of a powder compact in a container during hot isostatic pressing, the constitutive model of Abouaf and co-workers was implemented into a finite element analysis. An optimal design technique based on the design sensitivity was applied to the container design during hot isostatic pressing. The optimal shape of the container was predicted from the desired final shape of a powder compact by iterative calculations. Experimental data of 316L stainless steel powder showed that the optimally designed container allowed precise forming of the desired powder compact during hot isostatic pressing.

분체계 고유동 콘크리트의 재료분리 판정방법 분석 (Segregation Evaluation Method for Powder Based High Fluidity Concrete)

  • 이혁주;한준희;이재진;한동엽;한인덕;한민철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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    • pp.140-141
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    • 2018
  • There are three types of high fluidity concrete: powder based, VMA based, and combined. In the case of the powder based high fluidity concrete mixture, according to the textbook, increased viscosity due to the replaced fly ash can prevent segregation of coarse aggregate. On the other hand, decreased density of the powder due to the fly ash replacement can causes segregation but there is no report on this issue. Therefore, in this research, the segregation resistance and segregation evaluation method for powder based high fluid concrete mixture are evaluated. As a result, with increased replacing ration of supplementary materials, EIS value was decreased and apparently segregation resistance was increased. However, from the compressive strength evaluation depending on height of the cylindrical specimen, it was confirmed that the different of strength difference between top and bottom part of the specimen. Thus, following research regarding vertical segregation should be studied.

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