• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.138.2-138.2
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• 2010

Scandium-doped zirconium, ScSZ-based electrolyte, provides higher oxygen conductivity than YSZ and nano-based electrolyte materials are ideal for fabricating thin film electrolyte membrane of SOFC unit cell. Moreover, it may be applied to anode and cathode as well as electrolyte as ionic conductor. In this report, nano-based ScSZ-based electrolyte powder was prepared by co-precipitation synthesis. The particle size, surface area and morphology of the powder were observed by SEM and BET. Thin film electrolyte of under $10{\mu}m$ was fabricated by tape casting and co-firing using the synthesized ScSZ-based powders, and ionic conductivity and gas permeability of electrolyte film were evaluated. Finally, the SOFC unit cell was fabricated using the anode-supported electrolyte prepared by a tape casting method and co-sintering. Electrochemical evaluations of the SOFC unit cell, including measurements such as power density and impedance, were performed and analyzed.

• Journal of Powder Materials
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• v.18 no.2
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• pp.141-148
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• 2011

Carbon material shows relatively high strength at high temperature in vacuum atmosphere and can be easily removed as CO or $CO_2$ gas in oxidation atmosphere. Using these characteristics, we have investigated the applicability of carbon mold for precision casting of high melting point metal such as nickel. Disc shape carbon mold with cylindrical pores was prepared and Ni-base super alloy (CM247LC) was used as casting material. The effects of electroless Nickel plating on wettability and cast parameters such as temperature and pressure on castability were investigated. Furthermore, the proper condition for removal of carbon mold by evaporation in oxidation atmosphere was also examined. The SEM observation of the interface between carbon mold and casting materials (CM247LC), which was infiltrated at temperature up to $1600^{\circ}C$, revealed that there was no particular product at the interface. Carbon mold was effectively eliminated by exposure in oxygen rich atmosphere at $705^{\circ}C$ for 3 hours and oxidation of casting materials was restrained during raising and lowering the temperature by using inert gas. It means that the carbon can be applicable to precision casting as mold material.

• Journal of Korea Foundry Society
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• v.31 no.2
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• pp.83-86
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• 2011

Ni-Al based intermetallic compounds of self-propagating high-temperature synthesis (SHS) by the heat of molten aluminum and been coated on the aluminum casting alloy. The effects of the pouring temperature in casting and the thickness of casting substrate on SHS of the coating layer have been investigated. The experimental result showed that the reaction of the coating layer was activated with increasing the pouring temperature in casting and the thickness of casting substrate. However, the aluminum substrate was re-melted by the heat of formation for intermetallic compounds. Then, it was considered that some mechanical or thermal treatments for elemental powder mixtures were required to control the heat of formation for intermetallic compounds in advance.

• Journal of the Korean Ceramic Society
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• v.48 no.5
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• pp.348-353
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• 2011

By gel-casting, the silicon-polymer green bodies were prepared for silicon nitride ceramics, sintered by microwave gas phase reaction. Considering the viscosity and the idle time of slurries, we decided the operational conditions of related processes, and the optimum concentrations of raw materials powders, organic monomers, cross-linker, dispersant, initiator, and catalyst. So we could get the machinable green bodies, having about 50 MPa of bending strength without cracks by selecting drying conditions carefully.

• Journal of the Korean Society for Precision Engineering
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• v.16 no.11
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• pp.74-80
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• 1999

In this study, a stereolithography apparatus (SLA) prototype is used as a master model to be transformed into the silicone pattern by vacuum tool forming. The tool for the first prototype is fabricated by using this silicone pattern. Following this procedure, a temporary tool with metal powder and epoxy for wax injection is prepared for the die set of quick change type which consists of upper and lower base die나 and an insert die. The die set of quick change type appears to be very effective in casting operation by changing tools rapidly. The original wax pattern is formed through the die set, and is made of lost-was. Finally the lost-wax pattern is applied to investment casting. The final casting product is checked regarding its dimensional accuracy.

• Journal of the Korean Ceramic Society
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• v.52 no.6
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• pp.449-454
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• 2015

The fabrication process of zirconia gel-casting was studied to obtain dense zirconia on a large scale or with complicated shapes. As an experimental parameter, two different particle sizes ($0.1{\mu}m$ and $0.7{\mu}m$) of zirconia powder were applied to the gel-casting process. The viscosity behavior of slurries incorporating 40 vol% of zirconia powder was examined as a function of the dispersant content and the solid load to determine the optimum dispersion conditions. In addition, the gelation time with an initiator, the de-binding behavior, and the main factors affecting densification were examined. The densification of the gel-casted zirconia green body depended on the mixing ratio between the monomer and the dimer and on the zirconia particle size. A green body with a small particle size of $0.1{\mu}m$ showed less densification, with a relative density of 93%. This may be due to the excess number of bubbles created through interactions between the larger particle surface and polymer additives during the ball-milling process.

• Journal of the Korean Ceramic Society
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• v.43 no.9 s.292
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• pp.519-526
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• 2006

A full-factorial design of experiments with three input factors and two levels for each factor including center points was utilized for the preparation and characterization of twelve types of $BaTiO_3$ slips for tape casting. Ceramic powders with different particle sizes, different milling methods such as high energy milling and conventional ball milling, and two types of dispersant with different polymeric species were chosen as input factors in order to investigate their effects on slip and on green tape properties. Tape casting, a small rectangular-shaped K-square preparation, characterization and quantitative data analysis using statistical software were followed. Ceramic powder was the most significant among three input factors for the output responses of slip viscosity and green tape density, showing more favorable results with large particles than with very fine ones. In addition, high energy milling for only 30 min was more efficient than 24h of conventional ball milling in terms of powder dispersion and milling. The optimum condition based on the experimental results was a slip exposed to high energy milling with large ceramic particles along with a methylethyl acetate dispersant.

• Journal of Technologic Dentistry
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• v.34 no.4
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• pp.361-368
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• 2012

Purpose: The aim of this study was to analysis the composition on the centrifugal casting and the oxide on the casting temperature. Methods: The nickel based alloy were used in this study. Wax pattern specimens (10*10*2) were invested with phosphate-bonded investment in metal rings, the liquid/powder ratio and overall burn-out schedules for these investments were followed in accordance with the manufacturer's instructions. After casting, the alloy specimens were evaluated as regards composition(EPMA). The casting temperatures were as follows: $1400^{\circ}C$ and $1700^{\circ}C$. The quantitative analysis of oxides were scanning electron microscope(SEM), energy dispersive spectroscopy(EDS) and line scanning. Results: Nearer the injection lines showed that there is a large amount of nickel. Quantitative of oxides of Ni-Cr alloy cast from $1400^{\circ}C$ is lager than Ni-Cr alloy cast from $1700^{\circ}C$. Conclusion: Casting when using a centrifugal casting machine centrifugal force affects the composition of the alloy. The higher the temperature, the amount of oxide that is generated many.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2000.11a
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• pp.902-905
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• 2000

As the manufacturing processes of automotive engine piston, gravity die-casting, squeeze casting, hot forging and powder forging process are generally used for the various specifications. As the semi-solid forming(SSF) is compared with conventional casting such as gravity die-casting and squeeze casting for the characteristics of its process, the product without inner defects such as gas porosity and segregation can be obtained and its microstructure is globular grain. In SSF process, the materials are heated up to the temperature between the solvus and liquidus line at which the materials exists in the form of liquid-solid mixture. In this time, Discussion is given about reheating process of row material and results are presented regarding accurate temperature and process variables controlling for right solid fractions.

• Journal of the Korean Ceramic Society
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• v.50 no.6
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• pp.396-401
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• 2013

The size of various alumina ceramics used in the semiconductor and display industries must be increased to increase the size of wafers and panels. In this research, large alumina ceramics were fabricated by pressure-vacuum hybrid slip casting (PVHSC) employing a commercial powder, followed by sintering in a furnace. In the framework of the PVHSC method, the consolidation occurs not only by compression of the slip in the casting room but also by suction of the dispersion medium from the casting room. When sintered at $1650^{\circ}C$ for 4 h, the fabricated large-size alumina ($1,550{\times}300{\times}30mm^3$) exhibited a dense microstructure corresponding to more than 99.2% of the theoretical density and a high purity of 99.79%. The flexural and compressive strengths of the alumina plate were greater than 340 MPa and 2,600 MPa, respectively.