• Title/Summary/Keyword: potential maximum

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Redox Reaction on Polarization Curve Variations of Polymer with Enzymes

  • Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.3
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    • pp.165-171
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    • 2000
  • Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

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Investigation on optimum protection potential of Al-Mg alloy for small ship application in sea water solution (소형선박용 Al-Mg 합금의 해양환경 중 최적 방식 전위결정에 관한 연구)

  • Kim, Seong-Jong;Jang, Seok-Ki;Kim, Jeong-Il;Ko, Jae-Yong
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.23-24
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    • 2005
  • This paper investigated the mechanical and electrochemical properties of Al alloys in a slow strain rate test under various potential conditions. In general, Al and Al alloys do not corrode on formation of a film that has resistance to corrosion in neutral solutions. In seawater, however, $Cl^-$ ions lead to the formation and destruction of a passive film. In a potentiostatic experiment, the current density after 1200 sec in the potential range of $-0.68{\sim}-1.5 V$ was low. Comparison of the maximum tensile strength, elongation, and time to fracture indicated that the optimum protection potential range was from -1.5 to -0.7 V(SSCE).

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Influence of Redox Potential Current Density on Polarization Curves with Polypropylene Polymer

  • Park, Chil-Nam;Kim, Myung-Sun
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.4
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    • pp.255-261
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    • 2000
  • Experiments were carried out to measure the corrosion potential and current density variations in the polarization curves of polypropylene. In particular, the results were examined to identify those influences affecting the corrosion potential, such as temperature, pH, salt, and oxygen. The Tafel slope for the anodic dissolution was determined based on the polarization effect under various conditions. Furthermore, the optimum conditions for the most rapid transformation were establish based on a variety of conditions, including temperature, pH, corrosion rate, and resistance of corrosion potential. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity(I(sub)r/I(sub)f). This I(sub)r/I(sub)f value was then used to measure the critical corrosion sensitivity of polypropylene. The potentiodynamic parameters of corrosion were obtained using a Tafel plot.

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A Study on the Zeta-potential of CMP processed Sapphire Wafers (CMP 가공된 사파이어웨이퍼의 웨이퍼내 표면전위에 관한 연구)

  • Hwang Sung Won;Shin Gwisu;Kim Keunjoo
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.2
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    • pp.46-52
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    • 2005
  • The sapphire wafer was polished by the implementation of the surface machining technology based on nano-tribology, The removal process has been performed by grinding, lapping and chemical-mechanical polishing. For the chemical mechanical polishing process, the chemical reaction between the slurry and sapphire wafer was investigated in terms of the change of Zeta-potential between two materials. The Zeta-potential was -4.98 mV without the slurry in deionized water and was -37.05 mV for the slurry solution. By including the slurry into the deionized water the Zeta-potential -29.73 mV, indicating that the surface atoms of sapphire become more repulsive to be easy to separate. The average roughness of the polished surface of sapphire wafer was ranged to 1∼4$\AA$.

VELOCITY ANALYSIS OF M13 BY MAXIMUM LIKELIHOOD METHOD

  • Oh, K.S.;Lin, D. N. C.
    • Journal of The Korean Astronomical Society
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    • v.25 no.1
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    • pp.1-9
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    • 1992
  • We present new approach to analysis of velocity data of globular clusters. Maximum likelihood method is applied to get model parameters such as central potential, anisotropy radius, and total mass fractions in each mass class. This method can avoid problems in conventional binning method of chi-square. We utilize three velocity components, one from line of sight radial velocity and two from proper motion data. In our simplified scheme we adopt 3 mass-component model with unseen high mass stars, intermediate visible stars, and low mass dark remnants. Likelihood values are obtained for 124 stars in M13 for various model parameters. Our preferred model shows central potential of $W_o=7$ and anisotropy radius with 7 core radius. And it suggests non-negligible amount of unseen high mass stars and considerable amount of dark remnants in M13.

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Direct Organogenesis in Geophila reniformis D. Don., an Important Medicinal Herb

  • Nisha, A.;Narasimhan, S.;Manjula, S.;Nair, G.M.
    • Journal of Plant Biotechnology
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    • v.6 no.3
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    • pp.189-192
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    • 2004
  • Adventitious multiple shoots were developed from leaf, petiole and internode explants of Geophila reniformis D. Don. on MS medium supplemented with various concentrations of $N^6$-benzylaminopurine (BAP) or Kinetin (KIN) alone or in combination with indole-3-acetic acid (IAA). Leaf showed maximum organogenetic potential, followed by petiole and internode. Murashige and Skoog (MS) medium supplemented with 22.22 $\mu{M}$ BAP and 4.57 $\mu{M}$ IAA induced maximum shoot buds from leaf explants. Internodal segments showed low potential of direct organogenesis. The regenerated shoots rooted the best in presence of 10.75 - 13.44 $\mu{M}$ $\alpha$-naphthalene acetic acid (NAA) along with 2.22 $\mu{M}$ BAP, and were successfully established in the field with a survival rate of 89.11%.

Effects of Gas Composition on the Performance and Emissions of Compressed Natural Gas Engines

  • Min, Byung-Hyouk;Chung, Jin-Taek;Kim, Ho-Young;Park, Simsoo
    • Journal of Mechanical Science and Technology
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    • v.16 no.2
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    • pp.219-226
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    • 2002
  • Natural gas is considered to be a promising alternative fuel for passenger cars, truck transportation and stationary engines providing positive effects both on the environment and energy security. However, since the composition of natural gas fuel varies with location, climate and other factors, it is anticipated that such changes in fuel properties will affect emission characteristics and performance of CNG (Compressed Natural Gas) engines. The purpose of the present study is to investigate the effects of the difference in gas composition on the engine performance and emission characteristics. The results show that THC (Total Hydrocarbon) decreases with increasing Wl (Wobbe Index) and MCP (Maximum Combustion Potential). On the other hand, it is observed that NOx slightly increases as Wl and MCP increase. The TLHV (Total Lower Heating Value of Intake) is proposed in this study as a potential index for compatibility of gas fuels in a CNG engine. There is a variation in power up to 20% depending on the composition of gas when the A/F ratio and spark timing are flexed for a specific gas fuel.

Performance Characteristics of Refrigeration and Air Conditioning System Using Hydrocarbon Refrigerants (탄화수소계 냉동공조 시스템의 성능특성에 관한 실험)

  • 이호생;이근태;김재돌;윤정인
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.5
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    • pp.728-734
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    • 2004
  • Environmentally friendly refrigerants with zero ozone layer depletion potential are required to be used in refrigerators and air conditioners due to the difficulties related to ozone layer depletion and global warming. A rigorous study for the system performance with new refrigerants having zero ozone layer depletion potential is inevitable before adopting that as a new fluid. The HFC(Hydrofluorocarbon) potential has been recommended as alternatives. In this paper. system performance in the heat pump facilities were studied using R-290, R-600a. R-1270 as an environment friendly refrigerant. R-22 as a HCFC's refrigerant. The experimental apparatus has been set-up as a conventional vapor compression type heat Pump system. The test section is a horizontal double pipe heat exchanger. A tube diameter of 12.70mm with 1.315mm wall thickness is used for this investigation. The test results showed that the COP of hydrocarbon refrigerants were superior to that of R-22 and the maximum increasing rate of COP was found in R-1270. The refrigeration capacity of hydrocarbon refrigerants were higher than that of R-22. The compressor work was obtained with the maximum value in R-1270 and the minimum one in R-22.

A Review of Surface Energy of Solid Electrodes with Emphasis on Its Controversial Issues in Interfacial Electrochemistry

  • Go Joo-Young;Pyun Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.211-219
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    • 2004
  • A classical Lippmann equation valid for liquid electrodes can not describe the interfacial properties of solid electrodes due to the elastic surface strain on solid electrodes. Although there have been many attempts to derive the thermodynamic equations for solid electrodes Outing the past few decades, their validity has been still questioned by many researchers. In practice, although there are various experimental techniques to measure surface energy of solid electrodes, the results obtained by each technique are rather inconsistent due to the complexity of the surface strain on solid electrodes. This article covers these controversial issues in surface energy of solid electrodes. After giving brief summaries of the definition of the important thermodynamic parameters and the derivation of the thermodynamic equations for solid electrodes, the several experimental methods were introduced for the measurement of surface energy of solid electrodes. And then we discussed in detail the inconsistent results in the measurement of the potential of zero charge (pac) and the potential of electrocapillary maximum (ecm).

Re-estimation of Model Parameters in Growth Curves When Adjusting Market Potential and Time of Maximum Sales (성장곡선 예측 모형의 특성치 보정에 따른 매개변수의 재추정)

  • Park, Ju-Seok;Ko, Young-Hyun;Jun, Chi-Hyuck;Lee, Jae-Hwan;Hong, Seung-Pyo;Moon, Hyung-Don
    • IE interfaces
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    • v.16 no.1
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    • pp.103-110
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    • 2003
  • Growth curves are widely used in forecasting the market demand. When there are only a few data points available, the estimated model parameters have a low confidence. In this case, if some expert opinions are available, it would be better for predicting future demand to adjust the model parameters using these information. This paper proposes the methodology for re-estimation of model parameters in growth curves when adjusting market potential and/or time of maximum sales. We also provide the detailed procedures for five growth curves including Bass, Logistic, Gompertz, Weibull and Cumulative Lognormal models. Applications to real data are also included.