• Journal of Plant Biotechnology
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• v.34 no.2
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• pp.81-93
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• 2007

Gas hydrates are known to form by physical interactions between host water and guest gas molecules and thus can be treated as a special type of icy materials. The gas hydrates are recently highlighted because of their use to future energy source even though they were discovered naturally in the deep-sea marine sediments a long time ago. However, the present and future urgent task is to develop the efficient and safe production technology for recovering methane from gas hydrates. Here, we propose one of potential recovery processes using swapping phenomenon occurring between gaseous carbon dioxide and methane hydrate deposits. Such a swapping process provide several technological and economical advantages over conventional processes. The carbon dioxide can be directly sequestered into methane hydrate layer and simultaneously methane can be produced with a high recovery rate more than 90%. In addition, the icy powders can be effectively used as a new medium for storing hydrogen. To increase hydrogen storage capacity the icy hydrate networks need to be redesigned to create the more empty cages in which hydrogen gas can be enclathrated. Functionalized icy materials might be used in a variety of energy and environmental fields.

• Clean Technology
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• v.17 no.4
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• pp.329-335
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• 2011

$SF_6$ gas is well known as a global warming gas. Global warming potential of $SF_6$ gas is 22,000 times higher than that of $CO_2$. Recycling of $SF_6$ gas is an essential technology for the sake of the environment and the economy. The recovery processes of $SF_6$ gas studied in this work were liquefaction, distillation, and crystallization processes because these processes were thought to be easily carried to the fields for recycling waste $SF_6$ gas. The processes were simulated and optimized using Aspen plus. The optimization problems were formulated to minimize energy consumption with satisfying product specification and desired recovery. The performance of the processes was compared based on the optimization results. Effects of major process variables on the recovery performance were investigated and optimal operation guide for changing product specification and product recovery was provided.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2019.10a
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• pp.134-134
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• 2019

Utilization of organic waste as a renewable energy source is promising for sustainability and mitigation of climate change. Pyrolysis converts organic waste to gas, oil, and biochar by incomplete biomass combustion. Biochar is widely used as a soil conditioner and adsorbent. Biochar adsorbs/desorbs metals and ions depending on the soil environment and condition to act as a nutrient buffer in soils. Biochar is also regarded as a carbon storage by fixation of organic carbon. Phosphorus (P) and nitrogen (N) are strictly controlled in many wastewater treatment plants because it causes eutrophication in water bodies. P and N is removed by biological and chemical methods in wastewater treatment plants and transferred to sludge for disposal. On the other hand, P is an irreplaceable essential element for all living organisms and its resource (phosphate rock) is estimated about 100 years of economical mining. Therefore, P and N recovery from waste and wastewater is a critical issue for sustainable human society. For the purpose, intensive researches have been carried out to remove and recover P and N from waste and wastewater. Previous studies have shown that biochars can adsorb and desorbed phosphates implying that biochars could be a complementary fertilizer. However, most of the conventional biochar have limited capacity to adsorb phosphates and nitrate. Recent studies have focused on biochar impregnated with metal salts to improve phosphates and nitrate adsorption by synthesizing biochars with novel structures and surface properties. Metal salts and metal oxides have been used for the surface modification of biochars. If P removal is the only concern, P adsorption kinetics and capacity are the only important factors. If both of P and N removal and the application of recovery are concerned, however, P and N desorption characteristics and bioavailability are also critical factors to be considered. Most of the researches on impregnated biochars have focused on P removal efficiency and kinetics. In this study, coffee waste is thermally treated to produce biochar and it was impregnated with Mg/Al to enhance phosphates and nitrate adsorption/desorption and P bioavailability to increase its value as a fertilizer. Kinetics of phosphates and nitrate adsorption/desorption and bioavailability analysis were carried out to estimate its potential as a P and N removal adsorbent in wasewater and a fertilizer in soil.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.2
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• pp.127-137
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• 2019

Zr electrorefining is demonstrated herein using Zirlo tubes in a chloride-fluoride mixed molten salt in the presence of $AlF_3$. Cyclic voltammetry reveals a monotonic shift in the onset of metal reduction kinetics towards positive potential and an increase in intensity of the additional peaks associated with Zr-Al alloy formation with increasing $AlF_3$ concentration. Unlike the galvanostatic deposition mode, a radial plate-type Zr growth is evident at the top surface of the salt during Zr electrorefining at a constant potential of -1.2 V. The diameter of the plate-type Zr deposit gradually increases with increasing $AlF_3$ concentration. Scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDX) and X-ray photoelectron spectroscopy (XPS) analyses for the plate-type Zr deposit show that trace amount of Al is incorporated as Zr-Al alloys with different chemical compositions between the top and bottom surface of the deposit. Addition of $AlF_3$ is effective in lowering the residual salt content in the deposit and in improving the current efficiency for Zr recovery.

• Resources Recycling
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• v.22 no.6
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• pp.3-11
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• 2013

This study was carried out to estimate greenhouse gas reduction potentials under treatment methods of combustible wastes excavated from closed landfill. The treatment methods of solid wastes were landfilling, incineration, and production of solid recovery fuel. The greenhouse gas reduction potentials were calculated using the default emission factor presented by IPCC G/L method of IPCC (Intergovernmental Panel on Climate Change). The composition of excavated waste represented that screened soil was the highest (65.96%), followed by vinyl/plastic (19.18%). This means its own component is similar to the other excavated waste from unsanitary landfill sites. Additionally, its bulk density was 0.74 $t/m^3$. In case of landfilling of excavated waste, greenhouse gas emission quantity was 60,542 $tCO_2$. In case of incineration of excavated waste, greenhouse gas emission quantity was 9,933 $tCO_2$. However, solid recovery fuel from excavated waste reduced 33,738 $tCO_2$ of the greenhouse gas emission quantity. Therefore, solid recovery fuel production is helpful to reduce of greenhouse gas emission.

• Clean Technology
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• v.20 no.4
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• pp.439-448
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• 2014

The potential mitigation of greenhouse gas (GHG) is studied in the Pohang steel industrial complex (PHSIC). The total GHG emission in 2010 is estimated to be in the range from 4,174,000 to 4,574,000 $tCO_2-eq$ in PHSIC. To meet the target proposed by the government, it is needed to reduce 552,000 $tCO_2-eq$ at minium by 2020. To estimate the potential amount of GHG reduction, the technologies used in the voluntary carbon reduction projects are applied to 51 companies which are subject to GHG target management. From the viewpoint of technological availability and payback period, the fuel conversion and waste heat recovery have an advantage in the short term with a possibility to reduce 160,000 $tCO_2-eq$. In the mid term, the thermal technologies in steel and iron industry have the potential to cut 229,000 $tCO_2-eq$, while the electrical technologies have the potential of 125,000 $tCO_2-eq$ reduction. The gap between the target GHG mitigation and potential reduction using the short and mid term technologies is about 38,000 $tCO_2-eq$, which should be compensated by the fundamental process innovation and the implementation of the most cutting-edge technologies including renewable energy.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.217-217
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• 2006

The surface energy control capability of electrohydrodynamic force provides electrospraying with various potential advantages such as simple particle size control, mono-dispersity, high recovery, and mild processing conditions. Herein, the one step nano-encapsulation of protein drugs using electrospraying was developed. The major processing parameters such as the conductivity of spraying liquids, flow rate, the distance between electric potentials, etc were examined to obtain the maximum efficiency. The recovery of particles was found relatively high as could be conjectured based on the principle of electrospraying. When organic solvents were employed, the processing windows of electrospraying were relatively narrow than water systems. Efficient nano-encapsulation of BSA with polymers was conveniently achieved using electrospraying at above 12 kV.

• International journal of advanced smart convergence
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• v.5 no.2
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• pp.18-23
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• 2016

Cell walls of microalgae consist of a polysaccharide and glycoprotein matrix providing the cells with a formidable defense against its environment. Anaerobic digestion (AD) of microalgae is primarily inhibited by the chemical composition of their cell walls containing biopolymers able to resist bacterial degradation. Adoption of pre-treatments such as thermal, thermal hydrolysis, ultrasound and enzymatic hydrolysis have the potential to remove these inhibitory compounds and enhance biogas yields by degrading the cell wall, and releasing the intracellular algogenic organic matter (AOM). This paper preproposal stage investigated the effect of different pre-treatments on microalgae cell wall, and their impact on the quantity of soluble biomass released in the media and thus on the digestion process yields. This Paper present optimum approach to degradation of the cell wall by ultra-sonication with practical design specification parameter for ultrasound based pretreatment system. As a result of this paper presents, a microalgae system in a wastewater treatment flowsheet for residual nutrient uptake can be justified by processing the waste biomass for energy recovery. As a conclusion on this result, Low energy harvesting technologies and pre-treatment of the algal biomass are required to improve the overall energy balance of this integrated system.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.1
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• pp.91-97
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• 2013

Recently a novel cycle named organic flash cycle (OFC) has been proposed which has improved potential for power generation from low-temperature heat sources. This study carries out thermodynamic performance analysis of OFC using various working fluids for recovery of low-grade heat sources in the form of sensible energy. Special attention is focused on the optimum flash temperature at which the exergy efficiency has the maximum value. Under the optimal conditions with respect to the flash temperature, the thermodynamic performances of important system variables including mass flow ratio, separation ratio, heat addition, specific volume flow rate at turbine exit, and exergy efficiency are thoroughly investigated. Results show that the exergy efficiency has a peak value with respect to the flash temperature and the optimum working fluid which shows the best exergy efficiency varies with the operating conditions.

• Journal of Korean Society of Water and Wastewater
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• v.27 no.5
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• pp.529-545
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• 2013

With the increasing concern on climate changes and energy shortage, anaerobic membrane bioreactors (AnMBR) become a promising alternative to aerobic processes for domestic wastewater treatment. Two major advantages of AnMBRs are energy production and sludge reduction. Recently, several different configurations of AnMBRs have been proved to produce high quality effluent at reasonable hydraulic retention time and ambient temperature. One of the major problems of the AnMBR is membrane fouling control, and some solutions are already suggested. Other problems to be solved before the full application of the AnMBR are recovery of dissolved methane, management of residual nutrients and sulfide. Considering the potential advantages and future technology development, AnMBR will become major domestic wastewater treatment process in near future.