• Title/Summary/Keyword: post-synthesis

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Photoluminescence Characteristics of Fine-sized Gd2O3:Eu Phosphor Powders Prepared by Spray Pyrolysis (분무열분해 공정에 의해 합성된 미세 Gd2O3:Eu 형광체의 발광 특성)

  • Jung, Dae Soo;Koo, Hye Young;Lee, Sang Ho;Kang, Yun Chan
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1075-1080
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    • 2008
  • Fine-sized $Gd_2O_3:Eu$ phosphor powders were prepared by post-treatment of the precursor powders with hollow shape obtained by spray pyrolysis from the spray solution with citric acid and flux material. Citric acid enabled the synthesis of fine-sized phosphor powders after post-treatment by increasing the hollowness of the precursor powders. The phosphor powders prepared from the spray solution without citric acid had several microns size. Flux materials increased the mean sizes of the phosphor powders. However, flux materials improved the photoluminescence intensities of the phosphor powders under ultraviolet. $Li_2CO_3$ as the flux material was appropriate to prepare the fine-sized $Gd_2O_3:Eu$ phosphor powders with high photoluminescence intensity. The phosphor powders below 3 wt% $Li_2CO_3$ of phosphor had submicron sizes after post-treatment temperatures of $1,050^{\circ}C$ and $1,150^{\circ}C$. The photoluminescence intensity of the phosphor powders post-treated at $1,150^{\circ}C$ was 124% of that of the phosphor powders post-treated at $1,050^{\circ}C$.

Biosynthesis of $17\alpha-hydroxy$, $20\alpha-dihydroprogesterone$ by Ovaries of the Spotted Flounder (Verasper variegatus)

  • Baek Hea-Ja
    • Fisheries and Aquatic Sciences
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    • v.4 no.2
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    • pp.70-74
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    • 2001
  • To examine the production of steroids with potential oocyte maturation-inducing activity in the spotted flounder, Verasper variegatus, we have incubated post-vitellogenic oocytes (0.82­0.95mm in diameters) with radiolabeled pregnenolone and $17\alpha-hydroxyprogesterone$. The resulting metabolites were analyzed by thin layer chromatography (TLC) and high performance liquid chromatography (HPLC). The two main metabolites (progestogens) found in both incubations co-migrated with $17\alpha-hydroxy$, $20\alpha-dihydroprogesterone$ $(17\alpha, 20\alpha OHP)$ and $17\alpha-hydroxy,\;$20\beta-dihydroprogesterone$ (17 a20{30HP). Additional chromatography by HPLC and TLC confirmed the presence of radioactive $17\alpha, 20\alpha OHP$ and a large amount of unknown metabolite. The present study did not reveal in vitro formation of $l7\alpha 20\beta OHP$. Although 1$l7\alpha 20\beta OHP$ was found in a small amount, the synthesis of this steroid suggests that it may play a role in regulating the oocyte maturation process in the spotted flounder.

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Recent trends in advanced flight control

  • Kanai, Kimio
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10a
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    • pp.24.1-24
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    • 1996
  • The development of future aircraft that involves the expanded flight envelop will place increased performance requirements on the design of the flight control system. Maneuvering areas are expanding into flight envelopes characterized by significantly larger levels of modeling uncertainty than encountered in present flight control designs. Conventional flight control techniques that ignore the effects of large parameter variations, modeling uncertainties and nonlinearities, will likely produce designs with poor performance and robustness. Recent advances in modern control theories called advanced control theories, most notably the H$\_$.inf./ synthesis technique, adaptive control and neural network application, offer the promise of a design technique that can produce both high performance and robust controllers for next generation aircraft. This special lecture will survey the recent development in advanced flight control and review the possible application of advanced control theories.

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Interplay between Defect Propagation and Surface Hydrogen in Silicon Nanowire Kinking Superstructures

  • Sin, Nae-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.221.1-221.1
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    • 2015
  • The vapor-liquid-solid (VLS) method, where the "liquid" catalytic droplets collecting atoms from vapor precursors build the solid crystal layers via supersaturation, is a ubiquitous technique to synthesize 1-dimensional nanoscale materials. However, the lack of fundamental understanding of chemical information governing the process inhibits the rational route to the structural programming. By combining the in situ or operando IR spectroscopy with post-growth high resolution electron microscopy, we show the strong correlation between the surface chemical species concentration and nanowire structures. More specifically, the critical role of surface adsorbed hydrogen, generated from the decomposition of Si2H6 precursor on the interplay between nanowire / kinking and the defect propagation is demonstrated. Our results show that adsorbed hydrogen atoms are responsible for selecting -oriented growth and indicate that a twin boundary imparts structural coherence. The twin boundary, only continuous at / kinks, reduces the symmetry of the trijunction and limits the number of degenerate directions available to the nanowire. These findings constitute a general approach for rationally engineering kinking superstructures and also provide important insight into the role of surface chemical bonding during VLS synthesis.

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Synthesis of Ultra-long Hollow Chalcogenide Nanofibers

  • Jwa, Yong-Ho
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.3.1-3.1
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    • 2011
  • Nanoengineered materials with advanced architectures are critical building blocks to modulate conventional material properties or amplify interface behavior for enhanced device performance. While several techniques exist for creating one dimensional heterostructures, electrospinning has emerged as a versatile, scalable, and cost-effective method to synthesize ultra-long nanofibers with controlled diameter (a few nanometres to several micrometres) and composition. In addition, different morphologies (e.g., nano-webs, beaded or smooth cylindrical fibers, and nanoribbons) and structures (e.g., core-.shell, hollow, branched, helical and porous structures) can be readily obtained by controlling different processing parameters. Although various nanofibers including polymers, carbon, ceramics and metals have been synthesized using direct electrospinning or through post-spinning processes, limited works were reported on the compound semiconducting nanofibers because of incompatibility of precursors. In this work, we combined electrospinning and galvanic displacement reaction to demonstrate cost-effective high throughput fabrication of ultra-long hollow semiconducting chalcogen and chalcogenide nanofibers. This procedure exploits electrospinning to fabricate ultra-long sacrificial nanofibers with controlled dimensions, morphology, and crystal structures, providing a large material database to tune electrode potentials, thereby imparting control over the composition and shape of the nanostructures that evolved during galvanic displacement reaction.

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RNA-Protein Interactions and Protein-Protein Interactions during Regulation of Eukaryotic Gene Expression

  • Varani, Luca;Ramos, Andres;Cole, Pual T.;Neuhaus, David;Varani, Gabriele
    • Journal of the Korean Magnetic Resonance Society
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    • v.2 no.2
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    • pp.152-157
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    • 1998
  • The diversity of RNA functions ranges from storage and propagation of genetic information to enzymatic activity during RNA processing and protein synthesis. This diversity of functions requires an equally diverse arrays of structures, and, very often, the formation of functional RNA-protein complexes. Recognition of specific RNA signals by RNA-binding proteins is central to all aspects of post-transcriptional regulation of gene expression. We will describe how NMR is being used to understand at the atomic level how these important biological processes occur.

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Modulation of Branched-Chain Amino Acid Metaolism by Exercise in Rats

  • Kim, Hyun-Sook
    • Journal of Nutrition and Health
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    • v.27 no.9
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    • pp.892-900
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    • 1994
  • A variety of important roles for branched-chain amino acids in metabolic regulation has been suggested. Branched-chain $\alpha$-keto acid dehydrogenase(BCKAD) complex is a rate limiting enzyme in branched-chain amino acid metabolism. The purpose of this study was to examine the effects of exercise on the activity and activity state of branched-chain $\alpha$-keto acid dehydrogenase in rat hert and liver thssues. Forty-eight Sprague-Dawley rats were assigned into three experimental groups : sedentary control, exercised, or exercised-rested. Submaximal exercise(running) for two hours significantly increased basal activity without a change in total activity in both tissues, with a concomitiant increase in activity state of the enzyme complex. At 10 min post-exercise, heart enzyme activity significantly decreased, though not to the control level, while liver enzyme activity remained unchanged. These data suggested that the exercise-induced increase in branched-chain $\alpha$-keto acid decarboxylation in rat tissues may not be the result of enzyme synthesis, but rather is due to increased activity of the BCKAD.

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MLS Inducible Resistance Mechanism in Bacillus licheniformis EMR-1 -Cloning of erm K, a MLS Resistance Determinant- (Bacillus licheniformis EMR-1에서의 MLS 유도내성 기전 -erm K의 크로닝-)

  • Choi, Eung-Chil;Kwak, Jin-Hwan;Weisblum, Bernard
    • YAKHAK HOEJI
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    • v.32 no.4
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    • pp.213-221
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    • 1988
  • Inducible MLS resistance gene of Bacillus licheniformis specified by erm K was subcloned in Bacillus subtilis and the DNA sequence corresponding to its control region was determined. The determinant erm K was in Pvu II=Hind III fragment, which was 1.3 kb. The leader region is capable of forming a complex series of inverted complementary repeat sequences (ICRS) centering on at least six axes of symmetry, some of them mutually exclusive, in a way that resulted ultimately in post-transcriptional unmasking of the ribosome loading site for methylase synthesis.

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THE HI MOSAIC OF THE LARGE MAGELLANIC CLOUD

  • KIM SUNGEUN
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.95-95
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    • 1996
  • We present the recent results of an HI aperture synthesis mosaic of the Large Magellanic Cloud(LMC), made by combining data from 1344 separate pointing centers using the Australia Telescope Compact Array(ATCA). The resolution of the mosaiced images is 1'.0 (15 pc, using a distance to the LMC of 50 kpc). In contrast with its appearance at other wavelengths, the LMC is remarkably symmetric in HI on the largest scales, with the bulk of the HI residing in a disk of diameter 7.3 kpc. Outer spiral structure is clearly seen, though the features appear due to differential rotation, therefore transient in nature. A good correlation is seen between the supershells previously identified in Halpha (e.g. Meaburn 1980) and HI structures.

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Asymmetric Total Synthesis of the Glycosidase Inhibitor, 1,4-dideoxy-l,4-imino-D-arabinitol(DAB1)

  • Kim, In-Su;Hoon, Jung-Young
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 2003.11a
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    • pp.115-115
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    • 2003
  • Naturally occurring sugar mimics with a nitrogen in the ring are classified into five structural classes: polyhydroxylated pyrrolidines, piperidines, indolizidines. pyrrolizidine, and nortropanes. Glycosidase are involved in a wide range of important biological processes, such as intestinal digestion, post-translational processing of glycoproteins and the lysosomal catabolism of glycoconjugate. The realization that alkaloidal sugar mimics might have enormous therapeutic potential in many diseases such as viral infection, cancer and diabetes has led to increasing interest and demand for these compounds. Most of these effects can be shown to result from the direct or indrect inhibition of glycosidases.

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