• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.39 no.2
• /
• pp.125-134
• /
• 2015

This is the third paper on the combustion characteristics of the landfill gas in a constant volume combustion chamber for a large displacement volume commercial engine. It is the first in this series to discuss the effects of the torch device on combustion. The results show that an optimum orifice ratio exists regardless of the torch volume, and a few adverse effects on the combustion are observed for an excessively small orifice ratio. In addition, the torch ignition decreases the initial burn duration, and the decrease in the heat transfer caused by this decreased duration contributes to an increase in the peak combustion pressure. Finally, the torch mostly plays a positive role in shortening the main burn duration when the combustion condition is worsened by a lower methane fraction. Yet, the torch decreases the initial burn duration rather than the main burn as the methane fraction increases.

• Proceedings of the Computational Structural Engineering Institute Conference
• /
• 2004.04a
• /
• pp.1-8
• /
• 2004

For the linearized differential algebraic equation of the nonlinear constrained system, exact initial values of the acceleration are needed to solve itself. It may be very troublesome to perform the inverse operation for obtaining the incremental quantities since the mass matrix contains the zero element in the diagonal. This fact makes the mass matrix impossible to be positive definite. To overcome this singularity phenomenon the mass matrix needs to be modified to allow the feasible application of predictor and corrector in the iterative computation. In this paper the proposed numerical algorithm based on the modified mass matrix combines the conventional implicit algorithm, Newton-Raphson method and Newmark method. The numerical example presents reliabilities for the proposed algorithm via comparisons of the 4th order Runge-kutta method. The proposed algorithm seems to be satisfactory even though the acceleration, Lagrange multiplier, and energy show unstable behaviour. Correspondingly, it provides one important clue to another algorithm for the enhancement of the numerical results.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2004.10a
• /
• pp.1143-1147
• /
• 2004

A mechanical type pulsation dampener for the diaphragm metering pump has been developed. The pulsation pressure is an inevitable phenomenon for the positive displacement pump such as cam operated or solenoid operated metering pump. The pulsation pressure of the metering pump could be the noise source and would be harmful for the piping system which delivers hydraulic fluid. Developed pulsation dampener consists of three coil springs which have different spring constant and height each other. Depending on pressure magnitude of the piping system, total hydraulic pressure on damping diaphragm which compresses coil springs will be varied. Force equilibrium of the pulsation dampener will be set by manual by adjusting the compressed coil spring height. During the discharge stroke, pulsation dampener stores potential energy that is released as the pumping diaphragm back to an initial position during the suction stroke.

• Journal of Korean Society of Water Science and Technology
• /
• v.26 no.6
• /
• pp.143-152
• /
• 2018

The process parameters of ethyl violet from aqueous solution by activated carbon adsorption were carried out as a function of pH, temperature, contact time, initial concentration and temperature. The adsorption equilibrium data can be described well by the Langmuir and Freundlich isotherm models. Base on Langmuir constant ($R_L=0.0343{\sim}0.0523$) and Freundlich constant (1/n=0.1633~0.1974), This process could be employed as effective treatment for adsorption of ethyl violet. The kinetic experimental results showed that the adsorption process can be well described with the pseudo second order model. Based on the positive enthalpy (6.505 kJ/mol), the adsorption of ethyl violet onto granular activated carbon is endothermic. The negative Gibbs free energy (-1.169~-1.681 kJ/mol) obtained indicates that the adsorption process is spontaneous and physisorption.

• Journal of The Korean Society of Agricultural Engineers
• /
• v.56 no.3
• /
• pp.75-81
• /
• 2014

Fossil energy is needed for a whole year greenhouse cropping due to climate in South Korea. Because the most of the fossil energy resources is imported, it is necessary to develop technology to be able to reduce the energy cost in order to manage greenhouse profitably. The greenhouse commonly consume less amount of energy as compared to other industrial sectors. Replacement of fossil fuel with solar thermal storage, therefore, can be an economical as well as environmentally sustainable option for greenhouse heating. The fluid flow, heat storage and radiation characteristic of the gravel bed model were analyzed to provide basic data for design of the experimental solar heated greenhouse with underground thermal storage using gravel. The air flow velocity in the gravel storage bed was proven to be affected from the capacity of circulation fan and the circulation method and the positive pressure method was proven to be the best among the different air circulation methods. The initial air temperature of the thermal storage bed of 1.2 m $wide{\times}9$ m $long{\times}0.9$ m deep was $10^{\circ}C$. After the thermal storage bed is heated by air of the mean temperature $4^{\circ}C$ during 9 hours, the temperature has increased about $20.3^{\circ}C$ and the storage of heat was about 33,000 kcal. The important factors should be taken into consideration for design of the solar heated greenhouse with underground thermal storage using gravel are insulation of rock storage, amount of storing heat, inflow rate and direction of inlet and outlet duct.

• Asian-Australasian Journal of Animal Sciences
• /
• v.16 no.5
• /
• pp.665-671
• /
• 2003

A factorial experiment was conducted to assess nutrient utilization by growing lambs maintained on three levels each of digestible energy (high: HE, medium: ME, low: LE) and protein (high: HP, medium: MP, low: LP) in nine combinations (HEHP, HEMP, HELP, MEHP, MEMP, MELP, LEHP, LEMP, LELP). The experiment was conducted during the hot season in a semiarid location. Daily dry matter intake (DMI) was similar in all the groups in terms of unit body weight or metabolic body size. Digestibility of DM and nitrogen free extract increased (p<0.01) from low to medium and high energy regimen while the CF digestibility followed a reverse trend. The digestibility of crude protein (CP) decreased from high to medium and low protein regimens while it was similar in terms of energy variation. Nitrogen intake was higher in high followed by medium and low protein regime while fecal and urinary nitrogen loss were similar in all the treatment groups. Lambs in all the three levels of protein were in positive N balance and percent N retention was higher (p<0.01) in high followed by medium and low protein levels whereas it was similar in terms of energy variation. Initial body weight was similar in all the groups while final weight, total gain in the experiment and average daily gain (ADG) were higher in high than medium and low energy regimens. It is concluded that crossbred lambs required 75.1 g DM, 9.6 g CP, 6.3 g DCP and 711 KJ DE/kg W $^{0.75}$or 11.0 g CP/MJ DE or 7.2 g DCP/MJ DE for 93 g average daily gain in a hot semiarid environment.

• Clean Technology
• /
• v.18 no.1
• /
• pp.76-82
• /
• 2012

The paper includes utlization of zeolite as potential adsorbent to remove a hazardous malachite green from waste water. The adsorption studies were carried out at 298, 308 and 318 K and effects of temperature, contact time, initial concentration on the adsorption were measured. On the basis of adsorption data Langmuir and Freundlich adsorption isotherm model were also confirmed. The equilibrium process was described well by Freundlich isotherm model, showing a selective adsorption by irregular energy of zeolite surface. From determined isotherm constants, zeolite could be employed as effective treatment for removal of malachite green. From kinetic experiments, the adsorption process followed the pseudo second order model, and the adsorption rate constant ($k_2$) decreased with increasing initial concentration of malachite green. Thermodynamic parameters like activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption. The activation energy calculated from Arrhenius equation indicated that the adsorption of malachite green on the zeolite was physical process. The negative free energy change (${\Delta}G^{\circ}$ =-6.47~-9.07 kJ/mol) and the positive enthalpy change (${\Delta}H^{\circ}$ = +32.414 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption in the temperature range 298~318 K.

• Applied Chemistry for Engineering
• /
• v.24 no.2
• /
• pp.184-189
• /
• 2013

In the present study, batch experiments were carried out for the utilizatioin of activated carbon as a potential adsorbent to remove a hazardous malachite green from an aqueous solution. The effects of various parameters such as temperature, contact time, initial concentration on the adsorption system were investigated. On the basis of adsorption data Langmuir and Freundlich adsorption isotherm model were also confirmed. The equilibrium process was described well by Langmuir isotherm model. From determined separation factor, the activated carbon could be employed as an effective treatment for removal of malachite green. From kinetic experiments, the adsorption process followed the pseudo second order model, and the adsorption rate constant ($k_2$) decreased with increasing both the initial concentration of malachite green and the adsoprtion temperature. Thermodynamic parameters like that activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the adsorption nature. The activation energy calculated from Arrhenius equation indicated that the adsortpion of malachite green on the zeolite was physical process. The negative Gibbs free energy change ($\Delta$G = -3.68~-7.76 kJ/mol) and the positive enthalpy change ($\Delta$H = +26.34 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption in the temperature range of 298~318 K.

• Applied Chemistry for Engineering
• /
• v.25 no.1
• /
• pp.96-102
• /
• 2014

Adsorption of metanil yellow onto granular activated carbon were studied in a batch system. Various operation parameters such as adsorbent dosage, pH, initial concentration, contact time and temperature were optimized. Experimental equilibrium adsorption data were analyzed by Langmuir and Freundlich adsorption isotherm. The equilibrium process was described well by Freundlich isotherm model. From determined separation factor (1/n), adsorption of metanil yellow by granular activated carbon could be employed as effective treatment method. By analysis of kinetic experimental data, the adsorption process were found to confirm to the pseudo second order model with good correlation and the adsorption rate constant ($k^2$) decreased with increasing initial concentration. Thermodynamic parameters like activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption in the temperature range of 298~318 K. The activation energy was determined as 23.90 kJ/mol. It was found that the adsortpion of metanil yellow on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G=-2.16{\sim}-6.55kJ/mol$) and the positive enthalpy change (${\Delta}H=+23.29kJ/mol$) indicated the spontaneous and endothermic nature of the adsorption process, respectively.

• Clean Technology
• /
• v.25 no.3
• /
• pp.198-205
• /
• 2019

The adsorption equilibrium, kinetic, and thermodynamic parameters of brilliant green adsorbed by coconut based granular activated carbon were determined from various initial concentrations ($300{\sim}500mg\;L^{-1}$), contact time (1 ~ 12 h), and adsorption temperature (303 ~ 323 K) through batch experiments. The equilibrium adsorption data were analyzed by Langmuir, Freundlich, Temkin, Harkins-Jura, and Elovich isotherm models. The estimated Langmuir dimensionless separation factor ($R_L=0.018{\sim}0.040$) and Freundlich constant ($n^{-1}=0.176{\sim}0.206$) show that adsorption of brilliant green by activated carbon is an effective treatment process. Adsorption heat constants ($B=12.43{\sim}17.15J\;mol^{-1}$) estimated by the Temkin equation corresponded to physical adsorption. The isothermal parameter ($A_{HJ}$) by the Harkins-Jura equation showed that the heterogeneous pore distribution increased with increasing temperature. The maximum adsorption capacity by the Elovich equation was found to be much smaller than the experimental value. The adsorption process was best described by the pseudo second order model, and intraparticle diffusion was a rate limiting step in the adsorption process. The intraparticle diffusion rate constant increased because the dye activity increased with increases in the initial concentration. Also, as the initial concentration increased, the influence of the boundary layer also increased. Negative Gibbs free energy ($-10.3{\sim}-11.4kJ\;mol^{-1}$), positive enthalpy change ($18.63kJ\;mol^{-1}$), and activation energy ($26.28kJ\;mol^{-1}$) indicate respectively that the adsorption process is spontaneous, endothermic, and physical adsorption.