• 한국세라믹학회지
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• 제34권2호
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• pp.163-170
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• 1997

대표적인 무기계 지연제인 규불하마그네슘(MgSiF6.6H2O)을 시멘트 수화반응시 첨가했을 때의 수화반응의 지연 효과 및 특성과 수용액 이온농도 변화 고찰하기 위하여 규불화마그네슘을 시멘트 질랴의 0.3wt%에서 5wt%까지 변화시키면서 그 영향을 연구 검토하였다. 시멘트 모르타르의 flow는 지연제의 첨가에 따라 감소하는 경향이 있으며 응결 시간은 지연제의 첨가량에 따라 지연되었다. 모르타르의 압축 강도는 지연제의 첨가량에 따라 3일, 7일까지는 지연제를 첨가하지 않은 plain mortar에 비하여 약간 낮은 강도를 나타내나, 시간이 지남에 따라 회복되어 28일이 지나면 plain 모르타르와 같은 강도를 나타낸다. 규불화마그네슘이 첨가되면 수화 초기 단계에서 시멘트로부터 용출된 알카리 이온과 반응하여 K2SiF6의 생성이 일어나며 그와 동시에 Ca++와 F++와의 반응에 따라 CaF2화합물이 생성됨을 확인하였다. 이때 생성된 K2SiF6 및 CaF2생성물의 비표면적은 대단히 컸으며 이들 물질이 수화반응 초기에 미수화 시멘트시 입자 표면에 생성되어 시멘트의 수화가 지연되는 것으로 검토된다. 또한 수화초기의 수화용액의 Ca++ 및 K+이온 농도의 저하 역시 포틀랜드 수화반응속도를 지연시켜 주는 이유가된다.

• 산업기술연구
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• 제33권A호
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• pp.93-99
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• 2013

Shotcrete has been referred to as gunite, pneumatically applied mortar or concrete, sprayed concrete or mortar. There are sound reasons why sprayed mortar is one of the best portland cement based material for repairing old concrete structures. However, it is difficult to find the research results on the latex-modified mortar nevertheless on the impact of air onto the fresh and hardened properties of latex-modified mortar. So, the main experimental program included strength test, slump test, rapid chloride permeability test, image analysis for air void system, and chemical attacks with the main experimental variables of latex content, fine aggregate content, water-cement ratio, and air foamer content.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.542-546
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• 2001

Converter slag has some compositional similarities to portland cement. But it has no hydration properties due to it's quite high concentrations of FeO(20-35%), MnO(4-6.5%). So it is needed to reduce the concentrations of iron and manganese of converter slag to use as cement additives by enhancing it's hydration properties. In this study, converter slag was modified it's composition by mixing of silica, alumina and quenched BF slag and reduced in induction furnace and quenched in running water. The hydraulic properties and structures of modified and quenched converter slag are significantly changed depend on the amount and kinds of additives. The addition of alumina up to 10% and BFQ slag up to 20% by weight on converter slag was effective to enhance the hydraulic properties of modified and quenched slag. The addition of reduced and quenched converter slag up to 20% by weight in replacement of portland cement in mixing of concrete mortar were shown higher compressive strength than 100% cement concrete mortar.

• 한국농공학회지
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• 제24권3호
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• pp.92-99
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• 1982

The objective of this study was to investigate the compressive and bending strength characteristics of epoxy resin mortar, which is still in an early stage of its use and study in Korea. The results obtained are summarized as follows; 1. The compressive strengths of epoxy resin mortar after 1 day, 2 days and 3 days were gained 87%, 91% and 95%, respectively, in view of that of mortar at the age of 7 days. This result showed that the initial compressive strength within 1 day was very high. 2. The highest compressive strength of epoxy resin mortar was 914 kg/cm2 at the point of having the mixing ratio of one to two. It reached up to 3.7 times that of the normal portland cement mortar at the age of 28 days. 3. The bending strengths of epoxy resin mortar after 1 day, 2 days and 3 days came up to 88%, 93% and 97%, respectively, in comparing that of mortar at the age of 7 days. It was expressed to be simielar to the tendency of compressive strength. 4. The highest bending strength of epoxy resin mortar was 384 kg/cm2 at mixing ratio of one to two. It came up to as much as 6.5 times in comparing with that of the normal portland cement mortar at the age of 28 days. Therefore, the epoxy resin mortar would be effective for promoting the bending strength of structural members. 5. The regression equation between compressive and bending strength was obtained as follows; oo~=0.391 oc+27.54 (r=0.99) And the estimated value of bending strength was corresponded to about 44 per cent in comparing with that of the compressive strength.

• International Journal of Concrete Structures and Materials
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• 제8권4호
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• pp.315-326
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• 2014

This study evaluates the dosages of Class F fly ash, lithium nitrate and their combinations to suppress the excessive expansion caused by alkali-silica reactivity (ASR). In order to serve the proposed objective, the mortar bar specimens were prepared from (1) four dosages of Class F fly ash, such as 15, 20, 25 and 30 % as a partial replacement of Portland cement, (2) up to six dosages of lithium nitrate, such as lithium-to-alkali molar ratios of 0.59, 0.74, 0.89, 1.04, 1.19 and 1.33, and (3) the combination of lithium salt (lithium-to-alkali molar ratio of 0.74) and two dosages of Class F fly ash (15 and 20 % as a partial replacement of Portland cement). Percent contribution to ASR-induced expansion due to the fly ash or lithium content, test duration and their interaction was also evaluated. The results showed that the ASR-induced expansion decreased with an increase in the admixtures in the mortar bar. However, the specimens made with the both Class F fly ash and lithium salt produced more effective mitigation approach when compared to those prepared with fly ash or lithium salt alone. The ASR-induced expansions of fly ash or lithium bearing mortar bars by the proposed models generated a good correlation with those obtained by the experimental procedures.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.639-642
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• 2005

Main components of metakaolin(MK) were $SiO_2\;and\;Al_2O_3$. and specific surface was 2.2 times larger than that of ordinary portland cement(OPC). MK indicated the fine particle and fiber texture. Flow value of mortar with MK was decreased linearly each $13\%$ as the replacement ratio of MK was increased each $5\%$. Compressive strength of mortar with MK was increased more than that of mortar with OPC by 3days. Compressive strength of mortar with $10\%$ MK was about 83MPa at 28 days. When MK was replaced with $10\%$ of cement volume, flexural strength and modulus of elasticity of mortar was indicated the maximum value at 28 days.

• International Journal of Concrete Structures and Materials
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• 제8권3호
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• pp.259-268
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• 2014

This paper presents results of an experimental study which investigates the effect of industrial pozzolan made from calcined silt of dam at $750^{\circ}C$ for 5 h, on mechanical properties and durability of ordinary mortar, compared to the silica fume. Mortar specimens prepared with 5, 10 and 15 % of calcined silt to substitute cement were evaluated for their compressive and flexural strength, sulfate, acid and penetration of chloride ions resistance. The results were compared with ordinary mortar (without addition) and mortar containing 10 % of silica fume. The results obtained showed that the calcined silt of dam has a high potential to be used as a pozzolanic material, it improves the strength and the durability of mortar and compete the silica fume.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.297-298
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• 2023

In the concrete industry, efforts are being made to reduce CO₂ emissions, and technologies that collect, store, and utilize CO₂ have recently been studied. This study analyzed the change in compressive strength after the accelerated carbonation test of Non-Sintered Cement(NSC) mortar. Type C Fly Ash and Type F Fly Ash were mixed in a 1:1 ratio and then mixed with Blast Furnace Slag fine powder to produce NSC. The mortar produced was cured underwater until the target age. In addition, an accelerated carbonation test was conducted under the condition of a concentration of 5 (±1.0%) of CO₂ gas for 14 days. The mortar compressive strength was measured before and after 14 days of accelerated carbonation test based on the 7th and 28th days of age. As a result of the experiment, the compressive strength was improved in all binder. In general, the compressive strength of NSC mortar subjected to the accelerated carbonation test was similar to that of Ordinary Portland Cement(OPC) mortar not subjected to the accelerated carbonation test.

• Advances in materials Research
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• 제11권2호
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• pp.121-146
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• 2022

In the recent years, the use of agricultural waste in green cement mortar and concrete production has attracted considerable attention because of potential saving in the large areas of landfills and potential enhancement on the performance of mortar. In this research, microparticles of palm oil fuel ash (POFA) obtained from a multistage thermal and mechanical treatment processes of raw POFA originating from palm oil mill was utilized as a pozzolanic material to produce high-performance cement mortar (HPCM). POFA was used as a partial replacement material to ordinary Portland cement (OPC) at replacement levels of 0, 5, 10, 15, 20, 25, 30, 35, 40% by volume. Sand with particle size smaller than 300 ㎛ was used to enhance the performance of the HPCM. The HPCM mixes were tested for workability, compressive strength, ultrasonic pulse velocity (UPV), porosity and absorption. The results portray that the incorporation of micro POFA in HPCMs led to a slight reduction in the compressive strength. At 40% replacement level, the compressive strength was 87.4 MPa at 28 days which is suitable for many high strength applications. Although adding POFA to the cement mixtures harmed the absorption and porosity, those properties were very low at 3.4% and 11.5% respectively at a 40% POFA replacement ratio and after 28 days of curing. The HPCM mixtures containing POFA exhibited greater increase in strength and UPV as well as greater reduction in absorption and porosity than the control OPC mortar from 7 to 28 days of curing age, as a result of the pozzolanic reaction of POFA. Micro POFA with finely graded sand resulted in a dense and high strength cement mortar due to the pozzolanic reaction and increased packing effect. Therefore, it is demonstrated that the POFA could be used with high replacement ratios as a pozzolanic material to produce HPCM.

• 한국세라믹학회지
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• 제40권7호
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• pp.702-708
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• 2003

포틀랜드 시멘트 양(중량)을 플라이 애쉬로 50 wt%까지 치환한 페이스트, 모르터 내지 콘크리트 시편을 만들어 플라이 애쉬가 모르터/콘크리트의 온도, 자유석회량 및 강도 등에 미치는 영향을 조사하였다. 페이스트의 수화열을 측정하여 환산식에 따라 일반 포틀랜드 시멘트 콘크리트의 경우와 비교할 때, 플라이 애쉬를 50 wt% 함유한 콘크리트의 양생 7일 온도(상승)는 약 45% 저하되었다. 전자의 경우 온도 상승은 33.4$^{\circ}C$이며 후자의 경우는 18.7$^{\circ}C$였다. 한편 철근 콘크리트의 제조에 사용되는 시멘트의 플라이 애쉬 함유량은 철근부식의 방지를 위하여 30 wt%를 초과하지 않는 게 바람직하다. 플라이 애쉬를 혼합한 콘크리트의 강도가 순수 포틀랜드 시멘트 콘크리트의 강도보다 양호하기 위해서는 양생기간이 28일 이상 되어야 한다. 그리고 플라이 애쉬 50 wt%를 함유한 시멘트를 가지고도 360 kg/$\textrm{cm}^2$ 이상의 28일 강도를 얻을 수 있었다.