• The Journal of Engineering Geology
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• v.10 no.1
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• pp.51-62
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• 2000

The $CO_2$-richrich water pumps or springs out at two sites (Sinchon and Kohran) consisting of Cretaceous sedimentary rocks in Kyungpook area. The water has been long known as its soda pop-liketaste and therapeutic effect against calcium deficit, stomach and skin troubles, etc. The water arecharacterized by a high $CO_2$ concentration $(P_{CO2}=0.29~l.01 atm)$ and electrical conductance (1,093~2,810$\mu$S/cm). The $CO_2$-rich water belongs to Ca(Na)-$HCO_3$ type in chemical classification. The contents of Ca, Mg, Na, HCO$_3$ and Fe of $CO_2$-rich water show much higher values than those of general groundwater Environmental isotopic data $(^2H/^1H, ^{18}O/^{16}O and ^3H/^1H)$ indicate that the water is ofmeteoric origin recharged after 1950s. The $CO_2$ in the springs seems to be originated from deep-seatedsource related to acidic porphyry and granite nearby sedimentary rocks. Carbonate minerals and albiteare likely to be the major source minerals of the dissoved inorganic constituents in the $CO_2$-rich water.The equilibrium state between major minerals and $CO_2$-rich water was calculated by a thermodynamicprogram.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.6
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• pp.837-843
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• 2010

This research investigated classification of clay activity degree by different clay mineral components. Based on compositions of different clay and oxide minerals within 390 soil series in Korea, 7 soils were selected to analyze for CEC and specific surface area of clay minerals. As a result, soils were mainly composed with Chlorite originated from sandstone, Smectite originated from Andesite porphyry and combination of Allophane and Ferrihydrite originated from volcanic ash, if the ratio of CEC value to clay content (degree of clay activity) was greater than 0.7. If the degree of clay activity was ranged between 0.3 and 0.7, soils were composed mainly with Kaolin originated from anorthite. Soils with this ratio also was composted with combinations of Kaolin, Illite and Vermiculite originated with river deposits. When the degree of the activity was less than 0.3, soils were commonly red-yellowish color and composed with two different minerals. One type of composition was Kaolin originated from granite and granite gneiss and the soils contained Geothite and Hematite. The other type was composited mainly with Illite and Vermiculite minerals originated from granite. These soils contained Gibbsite, Geothite and Hematite. The degree of clay activity was highly related with CEC and specific surface area. The greater degree of the activity displayed greater values of clay CEC and specific surface area. It is not easy to measure actual quantity and compositions of clay minerals, while the degree of clay activity can be measured from routine soil analyses. As a conclusion, the degree of clay activity may be not just a simple but also powerful tool to estimate physical-chemical properties of soils and to evaluate the soil classification in Korean soils.

• Journal of the Mineralogical Society of Korea
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• v.32 no.3
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• pp.223-234
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• 2019

The geology of the Samdeok Mo deposit consists of Paleozoic Hwajeonri formation, Kowoonri formation, Suchangri formation, Iwonri formation, Hwanggangri formation, Cretaceous, leucocratic porphyritic granite and granitic porphyry. This deposit consists of three quartz veins that filled NS oriented fractured zones in Suchangri formation. Quartz veins vary from 0.05 m to 0.3 m in thickness and extend to about 400 m in strike length. Quartz veins occur as massive, breccia, and cavity textures. Wallrock alteration has silicification, sericitization, argillitization and chloritization. The mineralogy of the quartz veins consists of quartz, fluorite, white mica, biotite, apatite, monazite, rutile, ilmenite, molybdenite, chalcopyrite, Fe-Mg-Mn oxide and Fe oxide. White mica from Samdeok Mo deposit occurs as fine or coarse grains in quartz vein and hostrock and has four mineral assemblages (I type: quartz, molybdenite, Fe oxide and Fe-Mg-Mn oxide, II type: quartz, Fe oxide and Fe-Mg-Mn oxide, III type: quartz and biotite, and IV type: quartz). The structural formular of white mica from quartz vein is $(K_{0.89-0.60}Na_{0.05-0.00}Ca_{0.01-0.00}Sr_{0.02-0.00})_{0.94-0.62}(Al_{1.54-1.12}Mg_{0.36-0.18}Fe_{0.26-0.09}Mn_{0.04-0.00}Ti_{0.02-0.00}Cr_{0.02-0.00}Zn_{0.01-0.00})_{1.91-1.72}(Si_{3.40-3.11}Al_{0.92-0.60})_{4.00}O_{10}(OH_{1.68-1.42}F_{0.58-0.32})_{2.00}$, but white mica of I type has higher FeO content, and lower $SiO_2$ and MgO contents than white micas of other types. Also, compositional variations in white mica from the Samdeok Mo deposit are caused by phengitic or Tschermark substitution ($(Al^{3+})^{VI}+(Al^{3+})^{IV}{\leftrightarrow}(Fe^{2+}{\text{ or }}Mg^{2+})^{VI}+(Si^{4+})^{IV}$) and direct $(Fe^{3+})^{VI}{\leftrightarrow}(Al^{3+})^{VI}$ substitution.

• Economic and Environmental Geology
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• v.43 no.5
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• pp.477-490
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• 2010

The Gagok stratabound skarn deposit is the result of the intrusion of the Cretaceous granitic pluton into the Paleozoic calcareous rocks. The subvolcanic intrusion ranges in composition from quartz monzonite to granite porphyry with I-type, calc-alkaline and weakly peraluminous characteristics. Both endoskarn and exoskarn are developed at the Gagok Zn-(Pb) deposit, with more exoskarn than endoskarn. Geochemical and mineralogical characteristics in the Seongok and Wolgok orebodies can be treated in terms of self-organization. Sphalerites in the Gagok ore can also incorporate minor amounts of Mn, Cd, Cu and In. Trace element concentrations in different orebodies vary because fractionation of a given element into sphalerite is influenced by formation temperature and the amount of sphalerite in the ore. A group of high In/Zn and Cd/Zn ratios in ores, and low Mn/Fe ratios in sphalerites are correlated with proximal processes of a magmatic source. The pattern of minor/trace element variations in ores and sphalcrites can be used for petrogenetic interprctation, e.g., orebody zonation related to crystallization temperature and fluid d sources.

• Tunnel and Underground Space
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• v.26 no.5
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• pp.384-395
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• 2016

Both the roughness measurement tests and the multi-stage shear tests were carried out on the 110 rock joint samples in order to investigate the influences of rock type, joint roughness and normal stress on the shear behaviour of rock joints. Test samples were composed of quartz porphyry, dacite, granite and gneiss, which were classified into three detailed groups according to their JRC values. Roughness parameters of rock joints were analyzed by roughness measurement tests, and shear characteristics were also investigated by multi-stage shear tests. Both peak shear strength and shear stiffness were increased as both joint roughness and normal stress were increased, whereas dilation angles showed lower values at the lower roughness and higher normal stress conditions. Besides, shear characteristics obtained from all tests of four different rock types with different rock strengths showed irrelevant details, therefore the influences of both joint roughness and normal stress on shear behaviors were found to be more considerable than the strength of intact rock. The results obtained from both multi-stage shear tests and direct shear tests were finally compared, where the dilation angles obtained from multi-stage shear tests were found to be valid only for the first normal stress conditions.

• 한국지구물리탐사학회:학술대회논문집
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• 2009.05a
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• pp.57-65
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• 2009

Selection of good mineralized area is a combination of the integration of all the available geo-scientific (i.e., geological, geochemical, and geophysical) information, extrapolation of likely features from known mineralized terrenes and the ability to be predictive. The time-space relationships of the hydrothermal deposits in the East Asia are closely related to the changing plate motions. Also, two distinctive hydrothermal systems during Mesozoic occurred in Korea: the Jurassic/Early Cretaceous deep-level ones during the Daebo orogeny and the Late Cretaceous/Tertiary shallow geothermal ones during the Bulguksa event. Both the Mesozoic geothermal system and the mineralization document a close spatial and temporal relationship with syn- to post-tectonic magmatism. The Jurassic mineral deposits were formed at the relatively high temperature and deep-crustal level from the mineralizing fluids characterized by the relatively homogeneous and similar ranges of ${\delta}^{18}O$ values, suggesting that ore-forming fluids were principally derived from spatially associated Jurassic granitoid and related pegmatite. Most of the Jurassic auriferous deposits (ca. 165-145 Ma) show fluid characteristics typical of an orogenic-type gold deposits, and were probably generated in a compressional to transpressional regime caused by an orthogonal to oblique convergence of the Izanagi Plate into the East Asian continental margin. On the other hand, Late Cretaceous ferroalloy, base-metal and precious-metal deposits in the Taebaeksan, Okcheon and Gyeongsang basins occurred as vein, replacement, breccia-pipe, porphyry-style and skarn deposits. Diverse mineralization styles represent a spatial and temporal distinction between the proximal environment of sub-volcanic activity and the distal to transitional condition derived from volcanic environments. However, Cu (-Au) or Fe-Mo-W deposits are proximal to a magmatic source, whereas polymetallic or precious-metal deposits are more distal to transitional. Strike-slip faults and caldera-related fractures together with sub-volcanic activity are associated with major faults reactivated by a northward (oblique) to northwestward (orthogonal) convergence, and have played an important role in the formation of the Cretaceous Au-Ag lode deposits (ca. 110-45 Ma) under a continental arc setting. The temporal and spatial distinctions between the two typical Mesozoic deposit styles in Korea reflect a different thermal episodes (i.e., late orogenic and post-orogenic) and ore-forming fluids related to different depths of emplacement of magma (i.e., plutonic and sub-volcanic) due to regional changes in tectonic settings.

• Economic and Environmental Geology
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• v.9 no.1
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• pp.27-43
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• 1976

The flourite in Hwacheon, Hwanggangri and Keumsan district are major fluorite producing areas in Korea. The fluorite deposits of Hwacheon district are wholly fissure filling hydrothermal veins embedded in Precambrian gneiss and schists and Jurassic granites. Also some fluorite deposits are emplaced in felsite whose age is unknown. Emplacement of most fluorite veins of the district are controlled by EW fracture system. Fluorites are generally accompanied to chalcedonic quartz and also kaolinite, montmorillonite, dickite and calcite in parts. Vertical and lateral mineral zonings are not distinct. The fluorite deposits in the Hwanggangri district are wholly embedded in limestone and other calcareous sediments of Paleozoic Yeongweol Group. Most of the fluorite deposits belong to one of two categories which are steeply. dipping veins and gently dipping replacement deposits adjacent to Late Cretaceous(83-90mys) granite bodies. The strikes of fluorite veins of Hwanggangri district mostly occupy the fractures of $N30^{\circ}-40^{\circ}E$ and $N30^{\circ}-40^{\circ}W$ system. Fluorites are accompanied to calcite, milky quartz, chalcedonic quartz, and also montmorillonite, kaolinite in parts. But in some deposits, scheelite, various sulfide minerals and barite are accompanied. Emplacement of fluorite deposits are largely controlled by lithology and structures of this district. In some deposits fluorite veins gradate to scheelite veins and also telescoping of the mineral zones are found in this district. In the Keumsan district, fissure-filled fluorite veins and replacement deposits are mostly emplaced in limestone of Paleozoic Yeongweol Group, late Cretaceous quartz-porphyry, granite and sandstone. Some deposits are emplaced in Precambrian metasediments. Mineralogy and other characteristics of the deposits in this district is similar to those of Hwanggangri district. Fluid inclusion studies reveal the difference of salinities, $CO_2$ contents of ore fluid and temperatures during fluorite mineral deposition in the these districts. In Hwacheon district, ore-fluids were comparatively dilute brine and low $CO_2$ content. Filling temperatures ranges $104^{\circ}C$ to $170^{\circ}C$. In the Chuncheonshinpo mine, most deeply exploited one in this district, salinitles range 0.5-2. 2wt. % NaCl and filling temperatures range from $116^{\circ}C$ to $143^{\circ}C$. In the Hwanggangri district, ore fluids were complex and filling temperature ranges very widly. In the contact metasomatic fluorite deposits, ore fluid were NaCl rich brines with moderate $CO_2$ content and filling temperatures range from $285^{\circ}C$ to above $360^{\circ}C$. Fluids inclusions in tungsten and sulfide minerals bearing fluorite veins show high $CO_2$ content up to 31wt. %. Filling temperature ranges from $101^{\circ}C$ to $310^{\circ}C$. Fluids inclusions In mainly fluorite bearing veins were more dilute brine and low $CO_2$ contents. Filling temperatures range from $95^{\circ}C$ to $312^{\circ}C$. Filling temperature of fluid inclusions of Keumsan district are between $95^{\circ}C$ and $237^{\circ}C$. Data gathered from geologic, mineralogic and fluid inclusion studies reveal that fluorite mineralization in H wacheon district proceeded at low temperature with dilute brine and low $CO_2$ content. In Hwangganri district, fluorite mineralization proceeded by several pulse of chemically distinct ore fluids and formed the mineralogically different type of deposits around cooling granite pluton which emplaced comparatively shallow depth.

• Economic and Environmental Geology
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• v.39 no.5 s.180
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• pp.567-581
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• 2006

The Au-Ag lode deposits in South Korea are closely associated with the Mesozoic granitoids. Namely, the Jurassic deposits formed in mesozonal environments related to deep-seated granitoids, whereas the Cretaceous ones were developed in porphyry-related environments related to subvolcanic granitoids. The time-space relationships of the Au-Ag lode deposits in South Korea are closely related to the changing plate motions during the Mesozoic. Most of the Jurassic auriferous deposits (about $165{\sim}145$ Ma) show fluid characteristics typical of an orogenic-type gold deposits, and were probably generated in a compressional to transpressional regime caused by an orthogonal to oblique convergence of the Izanagi Plate into the East Asian continental margin. On the other hand, strike-slip faults and caldera-related fractures together with subvolcanic activity are associated with major strike-slip faults reactivated by a northward (oblique) to northwestward (orthogonal) convergence, and probably have played an important role in the formation of the Cretaceous Au-Ag lode deposits (about $110{\sim}45$ Ma) under a continental arc setting. The temporal and spatial distinctions between the two typical Mesozoic deposit styles in South Korea probably reflect a different thermal episodes (i.e., late orogenic and post-orogenic) and ore-forming fluids related to different depths of emplacement of magma due to regional changes in tectonic environment.

• Journal of the Mineralogical Society of Korea
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• v.21 no.1
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• pp.1-15
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• 2008

The Cretaceous Gajok gold-silver deposit within porphyry granite is located nearby the Cretaceous Pungam basin at the northeastern area in Republic of Korea. The Gajok gold-silver deposit is distinctively composed of a multiple-complex hydrothermal veins with comb, crustiform chalcedony quartz and vug textures, implying it was formed relatively shallower depth. The hypogene open-space filling veins could be divided into 5 paragenetic sequences, increasing tendency of Ag-rich electrum and Ag-phases with increasing paragenetic time. Electrum with high gold contents (${\sim}50$ atomic % Au) as well as sphalerite with high FeS contents (${\sim}6$ mole % FeS) are representative ore minerals in the middle stage. The late stage is characterized by silver-phase such like native silver and/or argentite, coexisting with Ag-rich electrum ($10{\sim}30$ atomic % Au) and Fe-poor sphalerite (< 1 mole % FeS). The ore-forming fluids evolution started at relatively high temperature and salinity (${\sim}360^{\circ}C$, ${\sim}7\;wt.%$ eq. NaCl) and were evolved by dilution and mixing mechanisms on the basis of fluid inclusion study. The gold-silver mineralization proceeded from ore-forming fluids containing greater amounts of less-evolved meteoric waters(${\delta}^{18}O$; $-0.6{\sim}-6.7\;%o$). These results imply that gold-silver mineralization of the Cretaceous Gaiok deposit formed at shallow-crustal level and could be categorized into low-sulfidation epithermal type, related to Cretaceous igneous activity.

• Economic and Environmental Geology
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• v.41 no.6
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• pp.773-795
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• 2008

The major import minerals of South Korea are copper ore, lead-zinc ore, iron ore, manganese ore and molybdenum ore. Oversea resources development of South Korea have 92 projects in 14 nations of Asia, 29 projects in 10 nations of America and Europe, and 14 projects in 9 nations of Middle Asia and Africa. But, most projects of them are found in Australia, China, Mongolia and Indonesia. The most projects of the Australia, China and Indonesia are interested in coal and a little projects of them have manganese, iron, lead-zinc, nickel, copper, gold, molybdenum, rare earth elements and uranium. The most projects of the Mongolia are interested in gold and rare earth elements. Representative ore deposits models of metal resources are Orogenic lode deposits, Volcanogenic massive sulphide deposits, Porphyry deposits, Sedimentary exhalative deposits, Mississippi valley type deposits, Iron oxide copper-gold deposits and Magmatic nickel-copper-platinum group element deposits based on global distribution, reverses and grades of their deposits models. If oversea mineral resources will be examined the mineral reserves, mineral mine production and ore deposits models of nations and then survey and investigate of mineral resources, we may be maintained ore body of high grade at survey area and decrease the investment risk.