• Journal of the Korea institute for structural maintenance and inspection
• /
• v.18 no.5
• /
• pp.27-33
• /
• 2014

Electrical resistivity of concrete can be measured in a more rapid and simple way for estimating durability of the concrete, however, carbonation causes a result of misleading for durability testing because carbonation leads to a significant reduction in the permeability and porosity of concrete. The purpose of this study is to estimate and quantify the effect of carbonation of concrete on a surface electrical resistivity measurement. Samples of three mixes with difference w/c were prepared and exposed in a carbonation chamber for 330 days. The results show that carbonation leads high electrical resistivity. The increase is substantial and has been shown to proportional to the extent of the carbonation by some of extent. The relationship between electrical resistivity and carbonation depth is taken in the study. Resistivity ratio of carbonated concrete to air concrete decreased significantly from the specific carbonation depth, however, resistivity ratio of carbonated concrete to air concrete had a linear relation with carbonation depth. From the relationship between electrical resistivity and carbonation depth, it is expected that the result should be subsequently used as a calibration curve for estimating carbonated concrete to overcome the interruption effect of carbonation on regular measurements of the electrical resistivity.

• Journal of the Korean Ceramic Society
• /
• v.41 no.7
• /
• pp.560-566
• /
• 2004

To fabricate the continuously porous alumina bodies by multi-extrusion process, carbon powder and ethylene vinyl acetate were used as a pore forming agent and a binder, respectively. As the change of extrusion pass number, reduction ratio as well as the volume fraction of core and tube, the porous alumina bodies having various kind of pore size and porosity could be obtained. The porous bodies showed continuous pore shape, high specific surface as well as high bending strength, which were compared with those of commercial alumina bodies. In-vitro study was carried out using MG-63 osteoblast cells to investigate of their biocompatibility. As a result, the cells grew well on top and bottom as well as inside surface of pore. From the result of in-vivo study of 3-dimensional porous alumina bodies using rats, it was confirmed that any inflammatory response was not found in the subcutaneous tissue around porous body. Also the porous bodies removed from the rats were fully covered with well-developed fibrous tissues and showed the formation of new capillary blood vessels.

• Journal of Electrochemical Science and Technology
• /
• v.8 no.1
• /
• pp.7-14
• /
• 2017

This study aims to examine the influences of substrates/diffusion layers (DL) and oxygen reduction reaction catalysts ($M_{ORR}$) on the performance of $M_{ORR}/IrO_2$/DL-type bifunctional oxygen electrodes for use in polymer electrolyte membrane (PEM)-type unitized regenerative fuel cells (URFC). The $M_{ORR}/IrO_2$/DL electrodes were prepared via two sequential steps: anodic electrodeposition of $IrO_2$ on various DLs and fabrication of $M_{ORR}$ layers (Pt, Pd, and Pt-Ru) by spraying on $IrO_2/DL$. Experiments using different DLs, with Pt as the $M_{ORR}$, revealed that the roughness factor of the DL mainly determined the electrode performance for both water electrolyzer (WE) and fuel cell (FC) operations, while the contributions of porosity and substrate material were insignificant. When Pt-Ru was utilized as the $M_{ORR}$ instead of Pt, WE performance was enhanced and the electrode performance was assessed by analyzing round-trip efficiencies (${\varepsilon}_{RT}$) at current densities of 0.2 and $0.4A/cm^2$. As a result, using Pt-Ru instead of Pt alone provided better ${\varepsilon}_{RT}$ at both current densities, while Pd resulted in very low ${\varepsilon}_{RT}$. Improved efficiency was related to the additional catalytic action by Ru toward ORR during WE operation.

• Journal of Hydrogen and New Energy
• /
• v.27 no.1
• /
• pp.95-105
• /
• 2016

Spray-dried NiO-based oxygen carriers developed for chemical looping combustion required high calcination temperatures above $1300^{\circ}C$ to obtain high mechanical strength applicable to circulating fluidized-bed process. In this study, the effect of CBB ($CaO{\cdot}BaO{\cdot}B_2O_3$) addition, as a binder, on the physical properties and oxygen transfer reactivity of spray-dried NiO-based oxygen carriers was investigated. CBB addition resulted in several positive effects such as reduction of calcination temperature and increase in oxygen transfer capacity and porosity. However, oxygen transfer rate was considerably decreased. This was more apparent when a higher amount of CBB was added and MgO was added together. From the experimental results, it is concluded that CBB added NiO-based oxygen carriers are not suitable for chemical looping combustion and a new method to reduce calcination temperature while maintaining high oxygen transfer rate of NiO-based oxygen carriers should be found out.

• Membrane and Water Treatment
• /
• v.9 no.2
• /
• pp.69-77
• /
• 2018

The use of membrane as an innovative technology for water treatment process has now widely been accepted and adopted to replace the conventional water treatment process in increasing fresh water production for various domestic and industrial purposes. In this study, ultrafiltration (UF) membranes with different formulation were fabricated via phase inversion method. The membranes were fabricated by varying the polymer concentration (16 wt%, 18 wt%, 20 wt%, and 21 wt%). A series of tests, such as field emission scanning electron microscope (FESEM), pore size and porosity, contact angle, and zeta potential were performed to characterize the membranes. The membrane performance in terms of permeation flux and rejection were evaluated using a laboratory bench-scale test unit with mine water, lake water and tube well as model feed solution. Long hour filtration study of the membranes provides the information on its fouling property. Few pore blocking mechanism models were proposed to examine the behaviour of flux reduction and to estimate the fouling parameters based on different degree of fouling. 21 wt% PVDF membrane with smaller membrane pore size showed an excellent performance for surface water treatment in which the treated water complied with NWQS class II standard.

• Applied Chemistry for Engineering
• /
• v.30 no.5
• /
• pp.633-638
• /
• 2019

Indoor air quality underground facilities are not equipped for the removal of volatile organic compounds (VOCs) and they are usually treated by diffusion methods such as ventilation. In this study, an adsorption filter was prepared using various coating methods such as carbon nano fiber (CNF) and dip coating. As a result, the adsorption performance was improved by 2 to 20 times or more compared to that of using the metal foam support. This is maybe due to the enhancement of pore distribution which was confirmed by SEM. In addition, the adsorption performance was 13.95 mg/g by adding lignin, and also an average adsorption performance of 13.25 mg/g was maintained after washing indicating that a highly durable adsorption filter material was prepared. It can be suggested that the developed adsorption filter material can be a potential solution that can fundamentally control VOCs, not via the concentration reduction of mechanical ventilation in underground facilities.

• Journal of the Korean Geotechnical Society
• /
• v.37 no.10
• /
• pp.27-40
• /
• 2021

The construction method to prevent the frost heave or thaw settlement is called the ground stabilization method, and the thermo-syphon is one of the typical ground stabilization methods. The thermo-syphon has recently been developed with a simple analysis model and thermal analysis has been carried out, but the frost heave of frost susceptible soil was not considered. This study was conducted using ABAQUS internal user subroutine to develop the numerical analysis model (Coupled thermo-mechanical) that can simultaneously perform thermal analysis for the temperature change of the soil according to the thermo-syphon and structural analysis to predict the frost heave of the soil accordingly. As a result of the numerical analysis, the frost heave of the soil decreased as the performance of the thermo-syphon increased. As for the main results, when the thermo-syphon which has contain 25%, 50%, and 100% of refrigerant filling ratio was applied, the reduction ratio of the frost heave was 5.5%, 14.4%, and 21% respectively.

• Korean Journal of Chemical Engineering
• /
• v.35 no.11
• /
• pp.2256-2268
• /
• 2018

Hydrophilic and hydrophobic polyethersulfone (PES)-zinc oxide (ZnO) sublayers were prepared by loading of ZnO nanoparticles into PES matrix. Both porosity and hydrophilicity of the hydrophilic sublayer were increased upon addition of hydrophilic ZnO, while these were decreased for the hydrophobic sublayer. In addition, the results demonstrated that the hydrophilic membrane exhibited smaller structural parameter (S value or S parameter or S), which is beneficial for improving pure water permeability and decreasing mass transfer resistance. In contrast, a higher S parameter was obtained for the hydrophobic membrane. With a 2 M NaCl as DS and DI water as FS, the pure water flux of hydrophilic TFN0.5 membrane was increased from $21.02L/m^2h$ to $30.06L/m^2h$ and decreased for hydrophobic TFN0.5 membrane to $14.98L/m^2h$, while the salt flux of hydrophilic membrane increased from $10.12g/m^2h$ to $17.31g/m^2h$ and decreased for hydrophobic TFN0.5 membrane to $3.12g/m^2h$. The increment in pure water permeability can be ascribed to reduction in S parameter, which resulted in reduced internal concentration polarization (ICP). The current study provides a feasible and low cost procedure to decrease the ICP in FO processes.

• Applied Chemistry for Engineering
• /
• v.32 no.3
• /
• pp.229-236
• /
• 2021

During the last two decades, metal-organic frameworks (MOFs) have been drawn attention due to their high specific surface area, porosity, and catalytic activities that allow to use in many applications such as sensor, catalysis, energy storage, etc. To synthesize MOFs hydrothermal or solvothermal method were generally used. However, these methods require high-cost equipment and long time-spend for the synthesis with multi-step process. In contrast, electrochemical synthesis has been considered as a simple and easy process under the ambient conditions. In this review, we described the mechanism of electrochemical MOFs synthesis by the number of configured electrodes system, with the recent reports of various applications.

• Journal of Powder Materials
• /
• v.28 no.3
• /
• pp.216-220
• /
• 2021

The effect of tert-butyl alcohol (TBA) as a freezing solvent on the pore structure of a porous tungsten body prepared by freeze-drying is analyzed. TBA slurries with a WO3 content of 10 vol% are prepared by mixing with a small amount of dispersant and binder at 30℃. The slurries are frozen at -25℃, and pores are formed in the frozen specimens by the sublimation of TBA during drying in air. After hydrogen reduction at 800℃ and sintering at 1000℃, the green body of WO₃ is completely converted to porous W with various pore structures. Directional pores from the center of the specimen to the outside are observed in the sintered bodies because of the columnar growth of TBA. A decrease in pore directionality and porosity is observed in the specimens prepared by long-duration drying and sintering. The change in pore structure is explained by the growth of the freezing solvent and densification.