• Proceedings of the IEEK Conference
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• 2008.06a
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• pp.487-488
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• 2008

SiOC films containing alkyl groups have a low dielectric constant because of the interaction between the C-H hydrogen bonds and the oxygen of high electro-negative atom. The Si-$CH_3$ in a void is broken by the $O_2$, therefore the strength of CH bond in Si-O-O-$CH_3$ bond increases. The Si-O-O-$CH_3$ bond is broken by nucleophilic attack due to Si atom, again. The elongation of C-H bond causes the red shift, and the compression of C-H bond causes the blue shift. Among these chemical shifts, the blue shift from $1000\;cm^{-1}$ to $1250\;cm^{-1}$ was related with the formation of pores. If the oxygen is deficient condition, the methylradicals of the electron-rich substitution group terminate easily the Si-O-Si cross-link, and the pore is originated from the cross-link breakdown due to much methyl radicals of Si-$CH_3$. The dielectric constant of the films decreases due to pore generation.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.36 no.5
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• pp.509-514
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• 2003

We performed the experiment to determine the effective factors, such as the initial concentration of protein, pore size of air distributor, SAV (superficial air velocity), pH, salts and temperature related to foaming characteristics. The foam height in a foam generator was increased with the increase of the initial protein concentration and the decrease of pore size. As SAV was increased, the foam height was increased, and the optimum SAV was 0.84 cm/sec. The foam height was highest in the acid region and it was increased with the increase of salt concentration of NaCl and $NaHCO_3.$ The removal efficiencies of TSS (total suspended solid) and turbidity decreased with the increase of the initial protein concentration in the batch foam separator.

• Geomechanics and Engineering
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• v.3 no.2
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• pp.83-108
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• 2011

The effect of non-plastic fines (silt) on liquefaction and pore pressure generation characteristics of saturated sands was studied through undrained stress controlled cyclic triaxial tests using cylindrical specimens of size 50 mm diameter and height 100 mm at different cyclic stress ratios and at a frequency of 0.1 Hz. The tests were carried out in the laboratory adopting various measures of sample density through various approaches namely gross void ratio approach, relative density approach, sand skeleton void ratio approach, and interfine void ratio approach. The limiting silt content and the relative density of a specimen were found to influence the undrained cyclic response of sand-silt mixtures to a great extent. Undrained cyclic response was observed to be independent of silt content at very high relative densities. However, the presence of fines significantly influenced this response of loose to medium dense specimens. Combined analyses of cyclic resistance have been done using the entire data collected from all the approaches.

• Journal of the Korean Geotechnical Society
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• v.22 no.12
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• pp.89-98
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• 2006

In this paper the behavior of saturated sand deposits where liquefaction occurred before is studied for successive earthquakes. The relationship between past pore pressure generation and reliquefaction resistance is examined by using cyclic direct simple shear tests. If the soil sample in direct simple shear produced nearly 90% of excess pore pressure during first time loading, its liquefaction resistance increased during following cyclic loading after consolidation. However, a fully liquefied soil during first time loading has a densely packed condition but shows less liquefaction resistance for the following cyclic loading. UBCSAND model that can account for pore pressure change and stiffness loss of soil during shaking is used to analyze the centrifuge test simulating reliquefaction. The pore pressure rise during first time cyclic loading controls liquefaction resistance. The measurements from reliquefaction centrifuge test are compared with numerical predictions. By considering frequent earthquakes having occurred at the Southern Korea near Japan, such effective stress approach is necessary for reliquefaction study.

• Journal of Mechanical Science and Technology
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• v.15 no.7
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• pp.1032-1040
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• 2001

It is widely accepted that the pressure variation of interstitial fluid is one of the most important factors in bone physiology. In order to understand the role of interstitial fluid on porous bony structure, a consideration for the biomechanical interactions between fluid and solid constituents within bone is required. In this study, a poroelastic theory was applied to investigate the elastic behavior of calf vertebral trabecular bone composed of the porous solid trabeculae and the viscous bone marrow. The poroelastic behavior of trabecular bone in a uniaxial stress condition was simulated using a commercial finite difference analysis software (FLAC, Itasca Consulting Group, USA), and tested for 5 different strain rates, i.e., 0.001, 0.01, 0.1, and 10 per second. The material properties of the calf vertebral trabecular bone were utilized from the previous experimental study. Two asymptotic poroelastic responses, the drained and undrained deformations, were predicted. From the predicted results for the simulated five strain rates, it was found that the pore pressure generation has a linearly increasing behavior when the strain rate is the highest at 10 per second, otherwise it showed a nonlinear behavior. The pore pressure generation with respect to the strain was found to be increased as the strain rate increased. The elastic moduli predicted at each strain were 208.3, 212.2, 337.6, 593.1, and 602.2 MPa, respectively. Based on the results of the present study, it was suggested that the calf vertebral trabecular bone could be modeled as a poroelastic material and its strain rate dependent material behavior could be predicted.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.386-401
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• 2011

Mathematical models for various steps in coal gasification reactions were developed and applied to investigate the effects of operation parameters on dynamic behavior of gasification process. Chemical reactions considered in these models were pyrolysis, volatile combustion, water shift reaction, steam-methane reformation, and char gasification. Kinetics of heterogeneous reactions between char and gaseous agents was based on Random pore model. Momentum balance and Stokes' law were used to estimate the residence time of solid particles (char) in an up-flow reactor. The effects of operation parameters on syngas composition, reaction temperature, carbon conversion were verified. Parameters considered here for this purpose were $O_2$-to-coal mass ratio, pressure of reactor, composition of coal, diameter of char particle. On the basis of these parametric studies some quantitative parameter-response relationships were established from both dynamic and steady-state point of view. Without depending on steady state approximation, the present model can describe both transient and long-time limit behavior of the gasification system and accordingly serve as a proto-type dynamic simulator of coal gasification process. Incorporation of heat transfer through heterogenous boundaries, slag formation and steam generation is under progress and additional refinement of mathematical models to reflect the actual design of commercial gasifiers will be made in the near futureK.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.37 no.3
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• pp.179-185
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• 2004

The characteristics of foam generation were assessed for freshwater and seawater using a foam generator. Both in freshwater and seawater, the height of the foam layer increased with initial protein concentrations. The height of the foam layer also increased with pore size of the air distributor. The optimum superficial air velocities (SAV) in freshwater and seawater were 0.84 cm/sec and 0.6 cm/sec, respectively. The height of the foam layer was the highest in pH 3 in freshwater and in the region of pH 5-7 in seawater. The height of the foam layer increased with $NaHCO_3$ concentration in freshwater, and $NaHCO_3$ concentration had little effect in seawater. Removal efficiencies of total suspended solid (TSS) and turbidity decreased with an increase of initial protein concentrations in a batch foam separator both in freshwater and seawater.

• Geomechanics and Engineering
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• v.8 no.1
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• pp.1-15
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• 2015

This paper presents a series of conventional undrained triaxial compression tests conducted to determine the effect of both tire crumbs and cement addition on Narli sand specimens. The tire crumb contents and cement contents were 3%, 7%, 15%; and 1%, 3%, 5% by dry weight of the sand specimens respectively. Specimens were prepared at about 35% relative density, cured during overnight (about 17 hours) for artificially bonding under a 100 kPa effective stress (confining pressure of 500 kPa with a back pressure of 400 kPa), and then sheared. Deviatoric stress-axial strain, pore water pressure-axial strain behavior, and Young's modulus of the specimens at various mixture ratios of tire crumb/cement/sand were measured. Test results indicated that the addition of tire crumb to sand decreases Young's modulus, deviatoric stress and brittleness, and increase pore water pressure generation. The addition of cement to sand with tire crumbs increases deviatoric stress, Young's modulus, and changes its ductile behavior to a more brittle one. The results suggest that specimen formation in the way used here could reduce the tire disposal problem in not only economically, and environmentally, but also more effectively beneficial way for some geotechnical applications.

• Proceedings of the Korean Geotechical Society Conference
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• 2004.03b
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• pp.245-252
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• 2004

When some enormous earthquake hazards broke out in the neighboring Japan and Taiwan, many Korean earthquake engineers thought that seismic guidelines must be adjusted safely and economically to consider the moderate earthquake characteristics. In the present aseismic guideline for liquefaction potential assessment, a simplified method using SPT-N value and a detail method based on the dynamic lab-tests were introduced. However, it is said that these methods based on the equivalent stress concept to simplify an irregular earthquake are not reliable to simulate the kaleidoscopical characteristics of earthquake loading correctly. Especially, even though various data from the dynamic lab-test can be obtained, only two data, a maximum cyclic load and a number of cycle at an initial liquefaction are used to determine the soil resistance strength in the detailed method. In this study, a new assessment of liquefaction potential is proposed and verified. In the proposed assessment, various data from dynamic lab-tests are used to determine the unique soil resistance characteristic and a site specific analysis is introduced to analyze the irregular earthquake time history itself. Also, it is found that the proposed assessment is reasonable because it is devised to reflect the changeable soil behavior under dynamic loadings resulted from the generation and development of excess pore water pressure.

• Korean Chemical Engineering Research
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• v.56 no.4
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• pp.524-535
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• 2018

In this study, macroporous titania powders were synthesized utilizing the emulsion-assisted self-assembly to apply the removal of B. subtilis under UV irradiation, and the results were compared with the bactericidal effect of commercial titania nanoparticles. By changing the pore size of the porous titania powder, the reduction of B. subtilis by photocatalytic effect was measured, and the bactericidal capacity of the porous particles according to the pore size was compared in order to derive the optimum condition of the sterilization experiment. It was observed that the sterilization effect increased as the pore size became smaller, and it was confirmed that more than 50% of B. subtilis cold be removed for 1 hour of UV irradiation. Also, in order to promote the generation of active chemical species, a diluted solution of hydrogen peroxide was combined with the photocatalytic sterilization method, resulting in the removal of most of the strain after ultraviolet irradiation for 1 hour.