• Title/Summary/Keyword: pore development

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Development and Application of Micromodel for Visualization of Supercritical CO2 Migration in Pore-scale (공극 규모에서의 초임계상 이산화탄소 거동 가시화를 위한 마이크로모델의 개발과 적용)

  • Park, Bogyeong;Lee, Minhee;Wang, Sookyun
    • Journal of Soil and Groundwater Environment
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    • v.20 no.4
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    • pp.73-82
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    • 2015
  • Despite significant effects on macroscopic migration and distribution of CO2 injected during geological sequestration, only limited information is available on wettability in microscopic scCO2-brine-mineral systems due to difficulties in pore-scale observation. In this study, a micromodel had been developed to improve our understanding of how scCO2 flooding and residual characteristics of porewater are affected by the wettability in scCO2-water-glass bead systems. The micromodel (a transparent pore structure made of glass beads and glass plates) in a pressurized chamber provided the opportunity to visualize scCO2 spreading and porewater displacement. CO2 flooding followed by fingering migration and dewatering followed by formation of residual water were observed through an imaging system. Measurement of contact angles of residual porewater in micromodels were conducted to estimate wettability in a scCO2-water-glass bead system. The measurement revealed that the brine-3M NaCl solution-is a wetting fluid and the surface of glass beads is water-wet. It is also found that the contact angle at equilibrium decreases as the pressure decreases, whereas it increases as the salinity increases. Such changes in wettability may significantly affect the patterns of scCO2 migration and porewater residence during the process of CO2 injection into a saline aquifer at high pressures.

Preparation of Adsorbent from Sewage Sludge by Steam Activation and Adsorption Characteristic (하수슬러지의 수증기 활성화법을 이용한 흡착제 제조와 흡착특성)

  • Jung, Dong-Hyun;Chun, Young-Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.515-520
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    • 2007
  • Recently, the treat of sludge is usually progressed by ocean disposal. But it will be totally banned by content of its heavy metal according to London Dumping Convention, gradually. The stable way of treat of sewage sludge should be examined urgently. To solve the problem, recently, there are efficient and environment-oriented method. One of them is to produce absorbent through the activation. This study produces absorbent through steam activation. As basic experiment, optimum activation condition for preparation of good absorbent is researched through study of the fellowing variables : steam flow rate, activated temperature, activation time. As the result of this with standard on iodine adsorptivity, it is chosen, that steam flow rate "30 mL/hr", activation temperature $"500^{\circ}C"$, activation time "60 minutes". At the time, iodine adsorptivity and yield shown that 228.4 mg/g, 77.23%. And also, by using nitrogen adsorption, SEM and EDS are confirmed that pore development, specific surface area, mean pore size, chemical component and content. Pore developed by steam activation is also confirmed that it is micropore.

Development of Pore-filled Polymer Electrolyte Membranes for Flexible Electrochromic Devices (유연한 전기변색 소자를 위한 세공충진 고분자 전해질 멤브레인의 개발)

  • Park, Hyeon-Jung;Lee, Ji-Hyeon;Kang, Moon-Sung
    • Membrane Journal
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    • v.31 no.5
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    • pp.333-342
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    • 2021
  • A flexible electrochromic device (ECD) is a promising technology that is expected to be applied in various fields such as smart windows. Polymer electrolyte is an important component that determines the bleaching-coloration performance and physical stability of flexible ECDs. In this study, a pore-filled polymer electrolyte membrane (PFPEM) with excellent dimensional stability was developed to effectively fabricate flexible ECDs and improve durability. Polyvinyl acetate, which has excellent adhesion, and polyethylene glycol, which can improve ionic conductivity, were filled in the pores of a porous substrate made of polyethylene, which is inexpensive and has excellent physical and chemical stability. The optimal lithium salt (LiTFSI) content of the prepared PFPEM was determined at about 27 wt%, and it was confirmed to possess excellent dimensional stability, adhesive strength, and ion conductivity close to that of conventional polymer electrolytes. Although the visible light transmittance was lowered by the use of the porous substrate, it was expected to act as an advantage in the colored state.

Development of Pore-Filled Anion-Exchange Membranes for High Performance Reverse Electrodialysis (고성능 역전기투석을 위한 세공충진 음이온교환막의 개발)

  • Kim, Do-Hyeong;Song, Hyeon-Bee;Yoon, Kyungseok;Kang, Moon-Sung
    • Membrane Journal
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    • v.32 no.5
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    • pp.336-347
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    • 2022
  • Reverse electrodialysis (RED) is one of the promising eco-friendly renewable energy technologies which can generate electricity from the concentration difference between seawater and freshwater by using ion-exchange membranes as a diaphragm. The ion-exchange membrane is a key component that determines the performance of RED, and must satisfy requirements such as low electrical resistance, high permselectivity, excellent durability, and low manufacturing cost. In this study, pore-filled anion-exchange membranes were fabricated using porous polymer substrates having various thicknesses and porosity, and the effects of ion-exchange polymer composition and membrane thickness on the power generation performance of RED were investigated. When the electrical resistance of the ion-exchange membrane is sufficiently low, it can be confirmed that the RED power generation performance is mainly influenced by the apparent permselectivity of the membrane. In addition, it was confirmed that the apparent permselectivity of the membranes can be improved through IEC, crosslinking degree, membrane thickness, surface modification, etc., and the optimum condition must be found in consideration of the trade-off relationship with electrical resistance.

Evaluation of Force Components and Newmark Sliding Block Analysis of Quay Walls during Earthquake (지진동을 받는 중력식 안벽에 작용하는 하중산정 및 Newmark 변위해석)

  • 김성렬;하익수;권오순;김명모
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2002.03a
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    • pp.93-100
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    • 2002
  • In this paper, new simple model is developed to evaluate the variation of the magnitude and the phase contrast of force components with the development of excess pore pressure in backfill soil. Also, Newmark sliding block analysis is performed inputting the calculated total force from new model. The applicability of new simple model and Newmark sliding block model is verified from the analyses of 1g shaking table test results.

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Method for high temperature curing and strength development of high strength concrete micropores Relationship (고온 양생방법을 이용한 고강도 콘크리트의 미세공극과 강도발현 관계에 대한 연구)

  • Lee, Han Yong;Kim, Seong Deok;Lee, young Do;Myung, Ro Oun;Jung, Sang Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.58-59
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    • 2013
  • In this study, the standard specimen heated to curing experiments and simulation experiments the absence of porosity distribution and the effect on the compressive strength has been investigated.

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Rejection of DNA, Protein-DNA Complexes and Chromatin by Hollow Fiber Membranes

  • Higuchi, Akon;Hara, Mariko;Sato, Tetsuo;Ishikawa, Gen;Nakano, Hiroo;Satoh, Sakae
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.18-21
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    • 1996
  • Virus and DNA removal in bio-drug manufacturing processes has received a great deal of attention in recent years. Removing of a virus using a membrane process is a promising method, because inactivated virus can be removed from the bio-drug and the process can be used as an additional and security inactivation after the method of general heat-inactivation of the virus in the bio-drug. The FDA and the biopharmaceutical industry have recently announced strict guidelines for impurities of virus and DNA contamination. The regulatory guidelines on residual amounts of DNA in mammalian cell culture products require DNA contamination of less than 100 pg/dose. Therefore, permeation and rejection of DNA through the porous membranes have become important in the application of DNA removal in bio-drug manufacturing using membrane technology. In this study, the permeation of DNA and chromatin through regenerated cellulose hollow fibers that have a mean pore diameter of 15 nm was investigated.

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Preparation of Activated Carbon Fibers from Cost Effective Commercial Textile Grade Acrylic Fibers

  • Bikshapathi, Mekala;Verma, Nishith;Singh, Rohitashaw Kumar;Joshi, Harish Chandra;Srivastava, Anurag
    • Carbon letters
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    • v.12 no.1
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    • pp.44-47
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    • 2011
  • Activated carbon fibers (ACFs) were prepared from cost effective commercial textiles through stabilization, carbonization, and subsequently activation by carbon dioxide. ACFs were characterized for surface area and pore size distribution by physical adsorption of nitrogen at 77 K. ACFs were also examined for various surface characteristics by scanning electron microscopy, Fourier transform infrared spectroscopy, and CHNO elemental analyzer. The prepared ACFs exhibited good surface textural properties with well developed micro porous structure. With improvement in physical strength, the commercial textile grade acrylic precursor based ACFs developed in this study may have great utility as cost effective adsorbents in environmental remediation applications.

Effects of Three-dimensional Scaffolds on Cell Organization and Tissue Development

  • Yan Li;Yang, Shang-Tian
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.6 no.5
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    • pp.311-325
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    • 2001
  • Tissue engineering scaffolds play a critical role in regulating the reconstructed human tissue development. Various types of scaffolds have been developed in recent years, including fibrous matrix and foam-like scaffolds. The design of scaffold materials has been investigated extensively. However, the design of physical structure of the scaffold, especially fibrous matrices, has not received much attention. This paper compares the different characteristics of fibrous and foam-like scaffolds, and reviews regulatory roles of important scaffold properties, including surface geometry, scaffold configuration, pore structure, mechanical property and bioactivity. Tissue regeneration, cell organization, proliferation and differentiation under different microstructures were evaluated. The importance of proper scaffold selection and design is further discussed with the examples of bone tissue engineering and stem cell tissue engineering. This review addresses the importance of scaffold microstructure and provides insights in designing appropriate scaffold structure for different applications of tissue engineering.

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Rejection Properties of Silica Nanoparticles from Ultrafiltration Membranes

  • Hiromitsu Takaba;Yoshiaki Ito;Nakao, Shin-ichi
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.54-60
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    • 2003
  • The rejection properties and flux rates of silica nanoparticles in ultrafiltration membranes has been investigated. Cross-flow permeation experiments were conducted using polycarbonate track-etch flat membranes with pore sizes of 30 and 50 nm, and a silica nanoparticle solute with particle sizes of 5 and 18 nm with narrow size distributions. The fluxes and rejection factors were investigated at various particle concentrations, cross-flow velocities, pH, and ionic strengths of solution. Even though the size of the silica nanoparticles was much smaller than that of the membrane pores, the observed rejection rates were very high compared with those for a similar-sized polymer (dextran). The observed rejection rate decreased with increasing ionic strength, which implies that the transport mechanism of the silica nanoparticles is significantly influenced by electrostatic repulsion between particles and membranes.