• Title/Summary/Keyword: pore analysis

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Activation and n-butane adsorption characteristics of palm char (야자각탄의 활성화와 n-butane 흡착특성)

  • 김인기;오한준
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.174-184
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    • 1997
  • Activated carbons were prepared from palm chars by steam activation. The effect of the activation temperature and time, steam concentration and flux on the n -butane adsorption properties were investigated on the basis of surface area, pore analysis and n-butane adsorption. The amount of n -butane adsorption increased with steam concentration and steam flux at higher activation temperature to the $900^{\circ}C$, however this tendancy on the activated carbons were not observed at the temperature above $900^{\circ}C$, It was shown that surface area was 978 $\textrm{m}^2$/g, average pore size was 9.3 $\AA$ and n-butane adsorption was 5.9 g /100ml in the activated carbons, prepared at $900^{\circ}C$, 185 minutes.

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The Study of Evaluating The Degree of Consolidation of The Dredged and Reclaimed Soft Ground (준설매립된 연약지반의 압밀도 산정에 관한 연구)

  • Kim, Seung-Tyull;Jung, Hun-Chul;Park, Chi-Myeon;Shin, Kyung-Ha;Jung, Ki-Moon
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.10a
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    • pp.469-478
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    • 2005
  • Understanding of an accurate state of consolidation of underconsolidated clay body, like a recently dredged or reclaimed clay deposits, is one of the most difficult tasks. The estimation of the consolidation status of these clay bodies is often made by laboratory tests of numerical analyses. However these methods demonstrated crucial limitations in the accurate prediction. Therefore, the predicted degree of consolidation from various techniques is verified by actual measured field data. The degree of consolidation of clay body in the East Side Hinterland of Gwangyang Port(2nd Phase) is evaluated in this study by using various techniques such as oedometer test, CPTu, numerical analysis and piezometer tests etc. And the results are compared each other to find the most reliable prediction technique. The merit and reliability of each method is discussed in detail. It is revealed from in this study that the estimation of degree of consolidation by an actual pore water pressure measurements is the most reliable technique.

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Fabrication of 3-dimensional Sn-C Composites Using Microsphere (미소구체를 이용한 3차원 Sn-C 복합체 제조)

  • Park, Bo-Gun;Kim, Seuk-Buom;Park, Yong-Joon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.9
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    • pp.741-746
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    • 2010
  • Three-dimensionally ordered macro-porous Sn-C composites were prepared by using polystyrene microsphere as a template. The Sn-C composites were composed of well-interconnected pore with circular shape and wall structure with wall thickness of a few tens of nano-meters. This porous three-dimensional structure is readily and uniformly accessible to the electrolyte, which facilitates lithium ion diffusion during charge-discharge reactions. The wall thickness of the composites was increased as the increase of Sn content of the composite. From EDS analysis, it is confirmed that the Sn was dispersed uniformly in Sn-C composites. The capacity was increased as the Sn content increased, which is due to Sn anode with high capacity. The Sn-C composites with high Sn content showed superior cyclic performances. Such enhancement is ascribed to the thick wall thickness and small pore size of the sample with high Sn content. The Sn-C composite with Sn 30 wt% showed relatively high capacity and stable cycle life, however, the stability of the 3-dimensional structure should be enhanced by further work.

Increase in Color Depth of Polyester Fiber by Alkali Treatment and Analysis of the Surface Structure (알칼리 감량에 의한 폴리에스테르 섬유의 심색화와 표면구조분석)

  • 김태경;임용진;석정달;조광호
    • Textile Coloration and Finishing
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    • v.11 no.5
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    • pp.22-29
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    • 1999
  • The increase in color depth of polyester fiber dyed with black disperse dyes was investigated with respect to the kinds of resins and alkali treatment. The color depth of the dyed polyester fiber increased continuously according to the concentration of resins coated onto the fabrics. The alkali treatment to polyester fiber before dyeing also enhanced the color depth. It was thought that the polyester fiber was hydrolyzed by alkali resulting micropores on the sample. And the following treatment with a resin, Jet Black T-101, to the polyester fiber increased the color depth much higher. The successive process of alkali treatment, dyeing and Jet Black T-101 treatment could give the best color depth to polyester fiber. Although the alkali treatment reduced the tensile strength of polyester fiber, the color depth of polyester fiber enhanced sufficiently within the range of practically acceptable weight loss and strength. To analyze the micropore on the polyester fiber formed by alkali treatment, nitrogen porosimeter was used. As the weight loss of polyester fiber treated with alkali increased, the BET(Brunauer-Emmett-Teller) surface area, total pore volume, and average pore size of the sample increased.

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A Study of Mechanical Properties and Microstructure of ZrO2-Ag Depending on the Composite Route (ZrO2-Ag의 복합화 공정에 따른 기계적 특성 및 미세조직 평가)

  • Yeo, In-Chul;Han, Jae-Kil;Kang, In-Cheol
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.416-423
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    • 2012
  • This paper introduces an effect of a preparing $ZrO_2$-Ag composite on its mechanical properties and microstructure. In present study, $ZrO_2$-Ag was prepared by reduction-deposition route and wetting dispersive milling method, respectively. Two type of Ag powders (nano Ag and micron Ag size, respectively) were dispersed into $ZrO_2$ powder during wetting dispersive milling in D.I. water. Each sample was sintered at $1450^{\circ}C$ for 2hr in atmosphere, and then several mechanical tests and analysis of microstructure were carried out by bending test, hardness, fracture toughness and fracture surface microstructure. As for microstructure, the Ag coated $ZrO_2$ showed homogeneously dispersed Ag in $ZrO_2$ in where pore defect did not appear. However, $ZrO_2$-nano Ag and $ZrO_2$-micro Ag composite appeared Ag aggregation and its pore defect, which carried out low mechanical property and wide error function value.

Coefficient charts for active earth pressures under combined loadings

  • Zheng, De-Feng;Nian, Ting-Kai;Liu, Bo;Yin, Ping;Song, Lei
    • Geomechanics and Engineering
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    • v.8 no.3
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    • pp.461-476
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    • 2015
  • Rankine's theory of earth pressure cannot be directly employed to c-${\phi}$ soils backfill with a sloping ground subjected to complex loadings. In this paper, an analytical solution for active earth pressures on retaining structures of cohesive backfill with an inclined surface subjected to surcharge, pore water pressure and seismic loadings, are derived on the basis of the lower-bound theorem of limit analysis combined with Rankine's earth pressure theory and the Mohr-Coulomb yield criterion. The generalized active earth pressure coefficients (dimensionless total active thrusts) are presented for use in comprehensive design charts which eliminate the need for tedious and cumbersome graphical diagram process. Charts are developed for rigid earth retaining structures under complex environmental loadings such as the surcharge, pore water pressure and seismic inertia force. An example is presented to illustrate the practical application for the proposed coefficient charts.

The ground response curve of underwater tunnels, excavated in a strain-softening rock mass

  • Fahimifar, Ahmad;Ghadami, Hamed;Ahmadvand, Masoud
    • Geomechanics and Engineering
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    • v.8 no.3
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    • pp.323-359
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    • 2015
  • This paper presents an elasto-plastic model for determination of the ground response curve of a circular underwater tunnel excavated in elastic-strain softening rock mass compatible with a nonlinear Hoek-Brown yield criterion. The finite difference method (FDM) was used to propose a new solution to calculate pore water pressure, stress, and strain distributions on periphery of circular tunnels in axisymmetric and plain strain conditions. In the proposed solution, a modified non-radial flow pattern, for the hydraulic analysis, is utilized. To evaluate the effect of gravitational loads and variations of pore water pressure, the equations concerning different directions around the tunnel (crown, wall, and floor) are derived. Regarding the strain-softening behavior of the rock mass, the stepwise method is executed for the plastic zone in which parameters of strength, dilatancy, stresses, strains, and deformation are different from their elasto-plastic boundary values as compared to the tunnel boundary values. Besides, the analytical equations are developed for the elastic zone. The accuracy and application of the proposed method is demonstrated by a number of examples. The results present the effects of seepage body forces, gravitational loads and dilatancy angle on ground response curve appropriately.

Gasification reactivity of Chinese Shinwha Coal Chars with Steam (스팀을 이용한 중국산 신화 석탄 촤 가스화 반응에 관한 연구)

  • Kang, Min-Woong;Seo, Dong-Kyun;Kim, Yong-Tak;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.15 no.1
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    • pp.22-29
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    • 2010
  • In this study, carbon conversion was measured using an electronic mass balance. In a lab scale furnace, each coal sample was pyrolyzed in a nitrogen environment and became coal char, which was then gasified with steam under isothermal conditions. The reactivity of coal char was investigated at various temperatures and steam concentrations. The VRM(volume reaction model), SCM(shrinking core model), and RPM(random pore model) were used to interpret experimental data. For each model the activation energy(Ea), pre-exponential factor (A), and reaction order(n) of the coal char-steam reaction were determined by applying the Arrhenius equation into the data obtained with thermo-gravimetric analysis(TGA). According to this study, it was found that experimental data agreed better with the VRM and SCM for 1,000 and $1,100^{\circ}C$, and the RPM for 1,200 and $1,300^{\circ}C$. The reactivity of chars increased with the increase of gasification temperature. The structure parameter(${\psi}$) of the surface area for the RPM was obtained.

Adsorption capability of activated carbon synthesized from coconut shell

  • Islam, Md Shariful;Ang, Bee Chin;Gharehkhani, Samira;Afifi, Amalina Binti Muhammad
    • Carbon letters
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    • v.20
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    • pp.1-9
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    • 2016
  • Activated carbon was synthesized from coconut shells. The Brunauer, Emmett and Teller surface area of the synthesized activated carbon was found to be 1640 m2/g with a pore volume of 1.032 cm3/g. The average pore diameter of the activated carbon was found to be 2.52 nm. By applying the size-strain plot method to the X-ray diffraction data, the crystallite size and the crystal strain was determined to be 42.46 nm and 0.000489897, respectively, which indicate a perfect crystallite structure. The field emission scanning electron microscopy image showed the presence of well-developed pores on the surface of the activated carbon. The presence of important functional groups was shown by the Fourier transform infrared spectroscopy spectrum. The adsorption of methyl orange onto the activated carbon reached 100% after 12 min. Kinetic analysis indicated that the adsorption of methyl orange solution by the activated carbon followed a pseudo-second-order kinetic mechanism (R2 > 0.995). Therefore, the results show that the produced activated carbon can be used as a proper adsorbent for dye containing effluents.

A New Assessment of Liquefaction Potential Based on the Dynamic Test (진동시험에 기초한 액상화 상세예측법 개발)

  • Kim, Soo-Il;Choi, Jae-Soon;Kang, Han-Soo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.245-252
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    • 2004
  • When some enormous earthquake hazards broke out in the neighboring Japan and Taiwan, many Korean earthquake engineers thought that seismic guidelines must be adjusted safely and economically to consider the moderate earthquake characteristics. In the present aseismic guideline for liquefaction potential assessment, a simplified method using SPT-N value and a detail method based on the dynamic lab-tests were introduced. However, it is said that these methods based on the equivalent stress concept to simplify an irregular earthquake are not reliable to simulate the kaleidoscopical characteristics of earthquake loading correctly. Especially, even though various data from the dynamic lab-test can be obtained, only two data, a maximum cyclic load and a number of cycle at an initial liquefaction are used to determine the soil resistance strength in the detailed method. In this study, a new assessment of liquefaction potential is proposed and verified. In the proposed assessment, various data from dynamic lab-tests are used to determine the unique soil resistance characteristic and a site specific analysis is introduced to analyze the irregular earthquake time history itself. Also, it is found that the proposed assessment is reasonable because it is devised to reflect the changeable soil behavior under dynamic loadings resulted from the generation and development of excess pore water pressure.

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