• Resources Recycling
• /
• v.19 no.1
• /
• pp.40-48
• /
• 2010

It was investigated that effects of NaOH concentration on synthesis of mesoporous materials using municipal solid waste incinerator ash slag (MSWI-ash slag). In order to increase the purity and maximize the amount of extracted Si content the raw MSWI-ash slag was mechanically activated. Extraction of Si from the MSWI-ash slag was carried out by alkali treatment using concentrated NaOH solution, which varied from 1M to 4M. Physical properties (i.e., pore size, specific surface area and total pore volume) of the synthesized mesoporous silica were also evaluated as a function of NaOH concentration via BET, SEM, TEM and small-angle X-ray scattering analyses. Over the entire range of NaOH concentration investigated (i.e., 1-4M), the synthesized mesoporous materials were determined to be SBA-15, which exhibited a hexagonal structure with the pore size of approximately 7 nm. On the other hand, specific surface area and total pore volume increased with NaOH concentration up to 3M while the values decreased at 4M, indicating that the optimal NaOH concentration for the synthesized mesoporous silica was approximately 3M. Further comparison analysis between two conditions (3M versus 4M) showed that the decrease in two physical properties at 4M NaOH concentration was likely due to the potential inhibition by excess Na ions on the formation of mesophase and the consequent increase of pore wall thickness by remaining Si ions.

• Journal of Environmental Impact Assessment
• /
• v.16 no.1
• /
• pp.69-77
• /
• 2007

This study has been conducted to assess blackish-water phenomena in Dam reservoir. To searching for the reason, we survey physical changes in reservoir and analyze metal and organic content in particulate materials and water. The blackish-water phenomena in lake A are occurred with turbidity increases in turnover season irregularly. It was reported on 6 Jan. 2005 weakly and the water column mixed with 35~40m depth and water temperature shows $7^{\circ}C$. The turbidity of AD and AM site increased up to 20NTU. Especially, AN site shows 27NTU, such a result makes that Dam manager conclude it to blackish-water phenomena. The results of sequential extraction analysis show that over 80% of Al, Cr and Fe is existed in residual form in sediment. On the other hand, the most part of Mn shows exchangeable and carbonates form, which have a good possibility of release to water column. Mn contents in pore waters of the sediment samples are also found to be ~4 times higher than Fe contents. The metal contents in pore water of different dam sites are in order of AN (Fe: 9.98, Mn: 40.6) > AD(8.33, 37.5) > DD(1.91, 2.55). According to the results of extracted organic materials from sediment, humic substances is occupied with over 85% in total organic carbon including 23~45% of humic acid (HA) and 0.9~8.5% of fulvic acid (FA). However, HA content in pore water is not detectable while FA contents, acid-soluble humic fractions is higher than that of sediment(10~15%). which indicating that FA is a main humic components affecting water color. The color unit per DOC of FA in pore waters of different dam sites are found to be higher in lake A than lake D. From the results, it could be suggested that blackish-water phenomena of lake A are mainly arise from higher concentration of Mn and water soluble organic fractions (e.g., FA) released from sediments as well as the strength of turnover in Dam reservoir.

• Analytical Science and Technology
• /
• v.28 no.1
• /
• pp.40-46
• /
• 2015

Hydrochar has been generated from food waste via hydrothermal carbonization (HTC) reaction. As a solid product of HTC reaction, hydrochar has a great potential as an adsorbent of pollutants from the various media. The surface area and pore volumes are very important parameters to be served as an adsorbent. It requires an expensive equipment and consumes time to measure those parameter. Therefore, titration methods including iodine and methylene blue adsorption were evaluated to be correlated with that of BET analysis. Even though the absolute values of the computed surface area and pore volumes were not able to be matched directly, the patterns of change were successfully correlated. Among the reaction conditions, the reaction time and temperature at $230^{\circ}C$ for 4 h was determined as an optimization condition, which confirmed by titration method and BET analysis. Titration method for surface area and pore volumes computed by combination of iodine and methylene blue adsorbing values would be a simple and fast way of determining the optimization condition for hydrochar as an adsorbent produced by HTC reaction.

• Applied Chemistry for Engineering
• /
• v.22 no.5
• /
• pp.501-507
• /
• 2011

To develop environmental-friendly insulating composite materials, natural cellulose and porous ceramic balls were used as core materials and activated Hwangtoh was used as a binder. Various specimens were prepared with different water/binder ratios and core material/binder ratios. The physical properties of these specimens were then investigated through compressive strengths, flexural strengths, absorption test, hot water resistance test, pore analysis, thermal conductivity, and observation of micro-structures using scanning electron microscope. Results showed that the maximum compressive strength varied appreciably with the water/binder ratios and core material/binder ratios, but the flexural strength increased with the core material/binder ratios regardless of water/binder ratios. The compressive strength and the flexural strength measured after the hot water resistance test decreased remarkably compared to those measured before test. The pore analysis measured after the hot water resistance test showed that total pore volume, porosity and average pore diameter decreased, while bulk density increased by the acceleration of hydration reaction of binder in the hot water. The thermal conductivity decreased gradually with an increase of core material/binder ratios. It can be evaluated that the composite insulation materials having good insulating properties and mechanical strengths can be used in the field.

• Proceedings of the Earthquake Engineering Society of Korea Conference
• /
• 2002.03a
• /
• pp.93-100
• /
• 2002

In this paper, new simple model is developed to evaluate the variation of the magnitude and the phase contrast of force components with the development of excess pore pressure in backfill soil. Also, Newmark sliding block analysis is performed inputting the calculated total force from new model. The applicability of new simple model and Newmark sliding block model is verified from the analyses of 1g shaking table test results.

• Korean Journal of Agricultural Science
• /
• v.38 no.3
• /
• pp.493-504
• /
• 2011

This study was carried out to safety evaluation, the practical application and improvement of design method of the agricultural reservoir due to raising embankments. Also, it was to compare and analyze the pore water pressure (PWP), seepage (leakage) quantity and piping phenomenon according to high water table and rapid drawdown. The seepage analysis by finite element analysis was used for steady state and transient condition. The pore water pressure distribution for steady state and transient condition showed positive(+) PWP on the upstream slope, it was gradually changed negative(-) PWP on the downstream slope. The PWP in the core ranged from 100 ~ -33 kPa, the seepage line in the incline-type core suddenly decreased towards the lower levels from the higher levels. The PWP according to rapid drawdown is remained in the vicinity of the upstream slope, therefore, it is investigated to be in an unstable state by the slope stability analysis. The PWP after raising embankments showed smaller than in the before raising embankments. It was likely to be the piping phenomenon because the gradients in the before raising embankments showed largely at downstream slope, and the stability for piping in the after raising embankments increased stable state. The seepage quantity per 1 day and the leakage per 100m for the steady state and transient condition appeared to be safe against the piping. It reduced slightly regardless of the transient condition before the raising embankments and it decreased largely about 2.4 times in the early days after the raising embankments.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.39 no.2
• /
• pp.317-325
• /
• 2019

A suction caisson has been widely used for anchor and foundation of offshore structures due to its broad application, simple installation, and rapid construction. In design of suction caisson foundation, the bearing capacity and the stability of soil are mainly dealt with and analysis methods for them are presented in design codes related to the foundation. On the other hand, the method for structural safety analysis of the suction caisson is not generalized, in particular for load modeling of the caisson under suction. Consequently, there are difficulties in design of the caisson cross section. For this reason, this study analyzed the magnitude and distribution of pore water pressure on inner and outer surface of the caisson using theoretical and numerical seepage analyse, and an approach to reasonably estimate the load applied to the structural analysis of the caisson was presented. Furthermore, effects of penetration depth, anisotropy of permeability, and suction pressure on the pore water pressure were analyzed.

• Journal of the Korean GEO-environmental Society
• /
• v.24 no.8
• /
• pp.5-11
• /
• 2023

Due to frequent occurrences of concentrated heavy rainfall caused by abnormal climate conditions in recent years, collapses of steep slopes have been occurring frequently due to surface erosion and increased pore water pressure. Various methods are being applied to prevent slope collapses, such as increasing the resistance to movement and reducing pore water pressure. Research on these methods has been consistently conducted as they provide an efficient response to slope collapses by satisfying both the conditions of resistance to movement and pore water pressure simultaneously. Therefore, in this study, we propose an upward slope reinforcement method by burying drainage materials with an upward slope inclination, instead of the conventional horizontal application. This approach aims to satisfy both slope reinforcement and drainage functions effectively, offering a comprehensive solution for slope stabilization. Furthermore, to determine the optimal burial angle that exhibits the most effective reinforcement and drainage effects of the proposed method, we investigated the reinforcement and drainage effects under conditions where the horizontal drainage materials were set at angles ranging from 0° to 60° in increments of 10° on a representative cross-section. Additionally, indoor model experiments were conducted under the conditions of 40°, which showed the most outstanding drainage effect, and 20°, which exhibited the highest safety factor, to validate the numerical analysis results. The results showed that the burial angle of 40° exhibits a relatively higher drainage effect as with the numerical analysis results, while the angle of 20° results in inadequate drainage and observed slope collapse.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.13 no.6 s.58
• /
• pp.192-203
• /
• 2009

In the new Seoul-Busan high speed railroad construction specially in area of city center passage the roadbed establishment is recommended the staibility for the existing subway tunnel segments of Busan subway 1st and 2nd lines regarding the appearance condition, a quality condition and the durability of the objective facility, and it evaluates the numerical analysis using MIDAS/GTS which leads the stability of the objective facility and investigatesd tunnels. Fundamental issues in tunneling under high groundwater table are discussed and the effect of groundwater on tunnel excavation was examined using a 3D stress-pore pressure coupled Finite-Element Method. Based on the results the interaction mechanism between the tunnelling and groundwater is identified. In the both of 1st and 2nd Line the maximum sinkage, unequal sinkage and the lining stress from numerical analysis are within permission and the damage degree is appearing to be disregarded. But it enforces necessary Pre-grouting in order to minimize an actual tunnel face conduct and when the tunnel is excavated it is also necessary to minimize the outflow possibility.

• Journal of the Korean GEO-environmental Society
• /
• v.7 no.6
• /
• pp.89-100
• /
• 2006

Recently, lots of lives and properties have been lost because comparatively large magnitude earthquakes were occurred in relatively safe regions and nations. It has been reported that number of earthquakes was increased rapidly in Korea. Hence, recently civil constructions were ensured against risks about earthquake not only large-scale structures but also comparative small-scale structures such as reservoir dams and life line by systematic aseismic design. Therefore, in this study, the seismic stability was ensured to evaluate aseismic performance for major planned reservoir dams in Korea. The seismic response analyses were conducted using SHAKE program on new reservoir dams under short-period, long-period and artificial seismic wave. The liquefaction potential for reservoir dams was assessed by using results from seismic response analysis (simplified assessment method for liquefaction potential). Also, fully coupled analysis--interaction of pore-pressure and soil--was performed to investigate both the development of excess pore water pressure and the characteristic of dynamic shear strain.