• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.8 no.1
• /
• pp.50-66
• /
• 1998

This study was conducted to estimate crystalline silica contents in airborne respirable dust from various manufacturing industries and to compare analytical performance of two methods of quantifying crystalline silica, X-ray diffraction(XRD) and Fourie transform infrared spectroscopy (FTIR). For this study, various manufacturing industries with a history of having pneumoconiosis cases and also known to generate dusts containing crystalline silica were investigated. These industries include: foundry, brick, potteries, concrete, and abrasive material, etc. Both personal and area respirable dust samples were collected using 10 mm, Dorr-Oliver nylon cyclone equipped with 37mm, $5{\mu}m$ pore size, polyvinylchloride (PVC) filters as collection media. In addition, total dust samples were collected side-by-side to the respirable samples. All samples were weighed before and after sampling and were pretreated according to the NIOSH sampling and analytical methods 0500, 7500, and 7602 for dust collection and quartz analysis. In addition, bulk samples were collected and analyzed by X-ray fluorescence (XRF) for minerals. In this article, only the results obtained from foundry are reported. The results from various other industries will be published in future articles. The respirable dust concentrations from personal samples by cyclone were $0.46-1.06mg/m^3$ and those from area samples were $0.34-0.73mg/m^3$. Dust concentrations of personal samples were significantly higher than those of area samples. The highest dust concentration was obtained from the personal samples of the finishing operation. Total dust concentration ranged $1.24-3.40mg/m^3$. The mean quartz contents estimated by FTIR and XRD in the personal respirable dust samples were 5.12% and 4.41%, respectively, without significant difference between them. For quartz analyses, the two techniques were highly correlated with $r^2$ ranged 0.803-0.920. But the results by FTIR were mostly higher than those by XRD. In addition, cristobalite was not detected by FTIR. Significant correlations between contents of crystalline silica and such minerals as $Al_2O_3$, CaO, $TiO_2$, and $K_2O$ suggest possible interferences from these minerals.

• Geotechnical Engineering
• /
• v.12 no.5
• /
• pp.79-88
• /
• 1996

In this study, prediction of soil behavior under vacuum preloading with vertical drain is explored on the basis of numerical models and toe results were compared with field measurements. Reasonable prediction of the time rate of settlements and pore pressure dissipation under vacuum preloading is the maj or concern. The conventional method for vatsuum preloading is based on modeling vacuum preloading as surcharge loading for the consolidation analysis. However, this modeling may violate the real behavior of soils under vacuum loading since the total stress in the analysis varies due to the modeled surcharge loading whereas in'.situ total stress of soils under vacuum loading is constant. In this study a new method is suggested. Instead of modeling vacuum loading as surcharge loading, negative hydraulic head is applied at the surface drain boundary to simulate the vacuum preloading. Comparisons of predictions and field measurements of soil behavior under vatsuum preloading are presented and the usefulness of the new modeling technique is demonstrated.

• Journal of the Korean Geotechnical Society
• /
• v.19 no.4
• /
• pp.247-256
• /
• 2003

FEM analyses which are based on modified Cam-clay theory have been generally used in such cases as analyses of stability and displacement fur embankment construction on soft clays. However, the Modified Cam Clay Model can generate some problems in anisotropic stress conditions of field because the critical state theory has been developed through many laboratory tests in isotropic conditions. Thus, the applicability on the prediction of undrained shear strength and pore water pressure which was based on the critical state theory was evaluated by triaxial tests and numerical analyses in isotropic and anisotropic conditions. Used samples often come out in domestic area, together with general low plastic clays which are showing dilatant behavior in shearing process. They were evaluated by laboratory tests and FEM based on MCCM. From the results of test and numerical analysis, the predictions of undrained strength in low plastic clays well coincided with each other in both isotropic and anisotropic conditions. However, the generation of porewater pressure was often overestimated during undrained shearing in anisotropic conditions. The results can generate the errors in the prediction of stress path of field sites during loading such as construction of embankment on soft clays because the field is subjected to anisotropic conditions during loading.

• Land and Housing Review
• /
• v.2 no.2
• /
• pp.163-170
• /
• 2011

Individual Vacuum Pressure Method (IVPM) is a soft ground improvement technique, in which a vacuum pressure can be directly applied to the vertical drain board to promote consolidation and to strengthen the soft ground. This method does not require surcharge loads, different to embankment or pre-loading method. In this study, the ground improvement efficiency of Individual Vacuum Pressure Method was estimated when suction pressure increases step by step(-20, -40, -60, -80kPa) with different periods. During Individual Vacuum Pressure Method process, surface settlement and pore pressure were monitored, and cone resistance as well as water content were also measured after the completion of Individual Vacuum Pressure Method treatment. From the results, optimum duration of each step of vacuum pressure was determined, and the settlement was calculated using FEM numerical analysis.

• The Journal of Engineering Geology
• /
• v.17 no.4
• /
• pp.601-613
• /
• 2007

It is reported that factors affecting the behavior of reinforced earth retaining walls built on soft ground are not only basic physical properties but also the increase of load by the reinforced earth retaining walls, consolidation period, pore water pressure, etc. This study analyzed the behavior of reinforced earth retaining walls and soft ground using SAGE CRISP, a ground analysis program. First, we examined the effect of the replacement method, which was to prevent the excessive displacement of reinforced earth retaining walls, in improving the behavior of the walls. Second, we compared and analyzed how the behavior of ground is affected by the vertical interval of stiffeners on the back of reinforced earth retaining walls after the application of the replacement method. Lastly, we proposed the optimal replacement width and depth in the application of the replacement method. The results of this study proved that the replacement method is considerably effective in improving the behavior of reinforced earth retaining walls. In addition, the vertical interval of stiffeners on the back of reinforced earth retaining walls appeared effective in improving the horizontal displacement of the top of retaining walls but not much effective in improving the vertical displacement of the back of retaining walls. In addition, improvement in horizontal-vertical displacement resulting from the increase in replacement width was not significant and this suggests that the increase of replacement width is not necessary. With regard to an adequate replacement depth, we proposed the ratio of replacement depth to the height of retaining walls(D/H) according to the ratio of the thickness of the soft layer to the height of retaining walls(H/T).

• Applied Chemistry for Engineering
• /
• v.19 no.4
• /
• pp.407-412
• /
• 2008

As an activation procedure, in this study, the oxidation treatment of needle cokes with a dilute nitric acid and sodium chlorate $(NaClO_3)$, combined with heat treatment, was attempted. The structures of acid-treated and pyrolyzed coke were examined with XRD, FESEM, elemental analyzer, BET, and Raman spectroscopy. The behavior of double layer capacitance was investigated with the analysis of charge and discharge. The structure of needle coke treated with acid was revealed to a single phase of (001) diffraction peak after 24 h. On the other hand, thecoke oxidized by heat treatment was reduced to a graphite structure of (002) at $300^{\circ}C$. The distorted graphene layer structure, derived from the process of oxidation and reduction of the inter-layer, makes the pores by the electric field activation at the first charge, and generates the double layer capacitance from the second charge. The cell using pyrolyzed coke with 24 h acid treatment and $300^{\circ}C$ heat treatment exhibited the maximum capacitance per weight and volume of 33 F/g and 30 F/mL at the two-electrode system in the potential range of 0~2.5 V.

• Journal of the Korean Geotechnical Society
• /
• v.28 no.11
• /
• pp.41-52
• /
• 2012

Suction drain method can directly apply vacuum pressure to the soft ground through vertical drains so it can make hardening zones around them. These hardening zones make steeply lower the discharge efficiency of the pore water with decreasing permeability. This paper considered a stepped vacuum pressure to minimize a hardening zone which is one of the important parameters that can decrease discharge efficiency. A series of laboratory tests were conducted in order to examine the effect of the hardening zones and to evaluate their effects to the ground improvements with varying durations which applied stepped vacuum pressures(-20kPa, -40kPa, -60kPa and -80kPa) with Busan marine clay. According to strength(CPT), water content test and theoretical investigation indicate a size of the hardening zone within 7cm and the decreasing ratio of permeability about 2.0~4.0. Also, the total settlements are larger for the stepped vacuum pressure than the instant vacuum loading. The application time with vacuum pressure is determined considering the geotechnical properties of the interested clays. Results of numerical analysis show that consolidation behavior is appropriate to measurement for considering hardening zones.

• 한국지구물리탐사학회:학술대회논문집
• /
• 2008.10a
• /
• pp.107-112
• /
• 2008

In the case of the deep reservoirs like the gas reservoirs in the East-sea, it is often difficult to observe AVO responses in CMP gathers. Because the reservoir becomes more consolidated as its depth deepens, P-wave velocity does not decrease significantly when the pore fluid is replaced by the gas. In this study, we analyzed the effects of Poisson's ratio difference on AVO response with a variety of Poisson's ratios for the upper and lower layers. The results show that, as the difference in Poisson's ratio between the upper and lower layers decreases, the change in the reflection amplitude with incidence angle decreases. To consider the limitation of AVO responses shown in the gas reservoir in East-sea, the velocity model was made by simulation Gorae V structure with seismic data and well logs. The results of comparing AVO responses observed from the synthetic data with theoretical AVO responses calculated by using material properties show that the amount of the change in reflection amplitude with increasing incident angle is very small when the difference in Poisson's ratio between the upper and lower layers is small. In addition, the characteristics of AVO responses were concealed by noise or amplitude distortion arisen during preprocessing. To overcome such limitations of AVO analysis of the data from deep reservoirs, we need to acquire precisely reflection amplitudes in data acquisition stage and use processing tools which preserve reflection amplitude in data processing stage.

• Journal of the Korean Chemical Society
• /
• v.33 no.1
• /
• pp.135-142
• /
• 1989

Methyl tert-butyl ether(MTBE) was synthesized from vapor phase reaction of methanol with iso-butylene over HZSM-5 catalysts, and effects of SiO$_2/Al_2O_3$ ratio in the HZSM-5 catalysts and reaction conditions on products distribution have been examined. Acid strength and acid type of each catalyst with different SiO$_2/Al_2O_3$ ratio were measured using pyridine adsorption followed by temperature programmed desorption(TPD) and IR analysis. Reactants and products adsorption characteristics on different acid sites have also been examined. As the SiO$_2/Al_2O_3$ ratio of HZSM-5 catalyst was increased, selectivity to MTBE was improved as a result of decrease in dimethylether(DME) formation at the strong acid sites. Conversion and selectivity to MTBE were also greatly enhanced as $i-C_4H_8/CH_3OH$ reactant ratio was increased, and overall about 80$^{\circ}$C was adequate for the MTBE synthesis. The properties of deposited coke on spent catalysts were examined by TG, DTA and IR spectrum analysis, indicating the amount of the coke deposit in the order of HY > H-Mordenite > HZSM-5. Even if the coke deposited on H-Mordenite was little more in amount than to that on HZSM-5, the former deactivated quickly due to its non-interconnected channel structure. For HY, owing to its lange pore size, significant $i-C_4H_8$ polymerization was occured, and rapid deactivation and severe coke formation has resulted within few hours.

• Journal of the Korean GEO-environmental Society
• /
• v.9 no.2
• /
• pp.39-46
• /
• 2008

Due to the growth in industrialization, potential hazards in subsurface environments are becoming increasingly significant. The extraction of the contaminant from the soil and movement of the water are restricted due to the low permeability and adsorption characteristics of the reclaimed soils. There are a number of approaches to in-situ remediation that are used in contaminated sites for removing contaminants. These include soil flushing, dual phase extraction, and soil vapor extraction. Among these techniques, soil flushing was the focus of the investigation in this paper. Incorporated technique with PVDs has been used for dewatering from fine-grained soils for the purpose of ground improvement by means of prefabricated vertical drain systems. The laboratory model tests were performed by using the flushing tracer solutions for silty soils and recorded the tracer concentration changes with the elapsed time and flow rates. The modeling was intended to predict the effectiveness and time dependence of the remediation process. Modeling has been performed on the extraction, considering tracer concentration and laboratory model test characteristics. The computer model used herein are SEEP/W and CTRAN/W, this 2-D finite element program allows for modeling to determine hydraulic head and pore water pressure distribution, efficiency of remediation for the subsurface environment. It is concluded that the coefficient of permeability of contaminated soil is related with vertical velocity and extracted flow rate. The vertical velocity and extracted flow rate have an effect on dispersivity and finally are played an important role in-situ soil remediation.