• Title/Summary/Keyword: pore analysis

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Effect of hydraulic lining-ground interaction on subsea tunnels (라이닝-지반 수리상호작용이 해저터널에 미치는 영향)

  • Shin, Jong-Ho;Park, Dong-In;Joo, Eun-Jung
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.10 no.1
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    • pp.49-57
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    • 2008
  • One of the most important design concerns for undersea tunnels is to establish design water load and flow rate. These are greatly dependent on the hydraulic factors such as water head, cover depth, hydraulic boundary conditions. In this paper, the influence of the hydraulic design factors on the ground loading and the inflow rate was investigated using the coupled finite element method. A horse shoe-shaped tunnel constructed 30 m below sea bottom was adopted to evaluate the water head effect considering various water depth for varying hydraulic conditions and relative permeability between lining and ground. The effect of cover depth was analysed for varying cover depth with the water depth of 60 m. The results were considered in terms of pore water pressure, ground loading and flow rate. Ground loading increases with an increase in water head and cover depth without depending on hydraulic boundary conditions. This points out that in leaking tunnels an increase in water depth increases seepage force which consequently increases ground loading. Furthermore, it is identified that an increase in water head and cover depth increases the rate of inflow and a decrease in the permeability ratio reduces the rate of inflow considerably.

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Review on the buoyancy effect of the multi purpose double-deck tunnels during operation (운영중 다목적 복층터널의 부력영향 검토)

  • Kim, Ho-jong;Kim, Hyeon-ah;Joo, Eun-jung;Shin, Jong-ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.17 no.6
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    • pp.623-635
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    • 2015
  • Double-deck tunnels beneath the groundwater table have relatively large volume and commonly constructed as watertight tunnels. In this case, it requires to secure stability of the tunnels for buoyant force. Generally the contact force between lining and ground is sufficient to resist the buoyant force. However in the long-term the contact force could be reduced because of structural deterioration. In this study the effect of long-term buoyant force acting on the double-deck tunnel is investigated. The results has shown that the buoyant force has increased invert deformation and stress. It is indicated that the contact resilience between lining and ground needs to be kept during tunnel operation.

Acidic Properties of Mg-Al Mixed Oxides in the Dehydration of iso-Propanol (이소프로판올의 탈수반응에 있어서 Mg-Al 혼합 산화물의 산점 특성)

  • Youn, Hyunki;Ahn, Ji-Hye;Park, Jung-Hyun;Shin, Chae-Ho
    • Clean Technology
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    • v.20 no.3
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    • pp.330-336
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    • 2014
  • Mg-Al mixed oxides with molar ratio of Mg/Al = 1-3 were prepared by co-precipitation and characterized by using X-ray diffraction, scanning electron microscopy, BET surface area and pore volume measured by $N_2$ sorption analysis, and temperature programmed desorption of iso-propanol. As Al content in Mg-Al mixed oxide increased, the acidity and BET surface area proportionally increased. This increase of acidity directly influenced the catalytic activity of iso-propanol conversion and selectivity to propylene.

Shaking Table Test for Comparison of Seismic Performance of Concrete-Face Rockfill Dam and Earth Core Rockfill Dam (표면차수벽형 석괴댐과 락필댐의 내진성능 비교를 위한 진동대시험)

  • Ha, Ik-Soo;Lim, Eun-Sang;Seo, Min-Woo;Kim, Yong-Seung
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2005.03a
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    • pp.3-10
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    • 2005
  • In this study, 1-g shaking table tests on the model of CFR(Concrete-Face Rockfill) type "D" dam in operation and the model of virtual ECRD(Earth Core Rockfill Dam) of which static stability is about the same compared to the model of CFRD were carried out. The purpose of this study is to compare the seismic performance of CFRD and ECRD from the analysis of model test results. Displacement response behavior of the dam was examined through the measurement of vertical and horizontal displacement of model dam crest. Also, amplification characteristics of accelerometers installed with dam height were examined through the measurement of acceleration with dam height. Also, in the case of ECRD, patterns of excess pore pressure generation with dam height were examined. From the test results, it was found that accelerations of dam crest of CFRD and ECRD were amplified about 1.52 times and 2 times compared to the accelerations of dam bottom, respectively. amplification was outstanding at three quarters of dam height from the bottom of dam. This phenomenon was outstanding in case of ECRD. And it was estimated that vertical and horizontal displacement of prototype dam of CFRD were 6.8cm (0.1% of dam height) and 12.3cm (0.2% of dam height), respectively. Also, it was estimated that vertical and horizontal displacement of prototype dam of ECRD were 4.3cm (0.1% of dam height) and 5.5cm (0.11% of dam height), respectively.

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Catalytic Pyrolysis of Waste Paper Cup Containing Coffee Residuals (커피 잔류물을 함유한 폐종이컵의 촉매 열분해)

  • Shin, Dongik;Jeong, Seokmin;Kim, Young-Min;Lee, Hyung Won;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.248-251
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    • 2018
  • Catalytic pyrolysis of the waste paper cup containing coffee residual (WPCCCR) was performed using a fixed bed reactor and pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS). Non-catalytic pyrolysis of WPCCCR produced a large amount of oil together with gas and char. The use of both HZSM-5 and HY decreased the yields of oil and increased the yield of gas due to the additional catalytic cracking. Owing to the acidic catalytic properties of HZSM-5 and HY, catalytic Py-GC/MS analysis of WPCCCR increased the selectivity to aromatic hydrocarbons in product oil. Owing to properties of HZSM-5 having a stronger acidity and medium pore size, the catalytic pyrolysis of WPCCR over HZSM-5 produced much larger amounts of aromatic hydrocarbons than that of using HY.

Impact of Air Convection on H3PO4-Activated Biomass for Sequestration of Cu (II) and Cd (II) Ions

  • Girgis, Badie S.;Elkady, Ahmed A.;Attia, Amina A.;Fathy, Nady A.;Abdel Wahhab, M. A.
    • Carbon letters
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    • v.10 no.2
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    • pp.114-122
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    • 2009
  • Crushed, depitted peach stones were impregnated activated with 50% $H_3PO_4$ followed by pyrolysis at $500^{\circ}C$. Two activated carbons were produced, one under its own evolved gases during pyrolysis, and the second conducted with air flow throughout the carbonization stage. Physicochemical properties were investigated by several procedures; carbon yield, ash content, elemental chemical analysis, TG/DTG and FTIR spectra. Porosity characteristics were determined by the conventional $N_2$ adsorption at 77 K, and data analyzed to get the major texture parameters of surface area and pore volume. Highly developed activated carbons were obtained, essentially microporous, with slight effect of air on the porous structure. Oxygen was observed to be markedly incorporated in the carbon matrix during the air treatment process. Cation exchange capacity towards Cu (II) and Cd (II) was tested in batch single ion experimental mode, which proved to be slow and a function of carbon dose, time and initial ion concentration. Copper was up taken more favorably than cadmium, under same conditions, and adsorption of both cations was remarkably enhanced as a consequence of the air treatment procedure. Sequestration of the metal ions was explained on basis of the combined effect of the oxygen functional groups and the phosphorous-containing compounds; both contributing to the total surface acidity character.

A Study on the Infrared Emission Properties and Freeze-thaw Resistance for Calcined Clay by Carburization Treatment (소성 점토의 침탄에 따른 동결융해 저항성 및 적외선 방사특성 연구)

  • Kim, Ki-Ho;Kim, Sang-Myoung;Kang, Byung-Chul
    • Journal of the Korean Ceramic Society
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    • v.45 no.7
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    • pp.387-394
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    • 2008
  • The Physical property changes of calcined clay by carburization were investigated studied. The carburization mechanism is the penetration of carbon which occurred during incomplete fuel combustion into crevice of clay structure. The experiments for elasticity and freeze-thaw resistance were conducted, and the results can be summarized as follows: Dynamic modulus of elasticity and also freeze-thaw resistance of calcined clay by carburization treatment increased more than 92% after testing 300 cycle, which was more improved than 88% of calcined clay. Therefore, it can decrease the possibility of winter-sowing, which is one the weakness of calcined clay. It is on the basis of the fact that the porosity of calcined clay by carburization treatment is about 12%, which indicates smaller pore spaces comparing with the 14% of porosity of calcined clay and those values were calculated by apparent porosity show and also supported by SEM images. Infrared emissivity of calcined clay by carburization treatment and calcined clay were respectively 0.92 and 0.9l at $80^{\circ}C$. However, those values were 0.91 and 0.88 at $200^{\circ}C$, which means infrared emissivity of calcined clay by carburization treatment shows 3.6% higher than the calcined clay. Moreover, within the wavelength range from 3 to $7\;{\mu}m$, while the calcined clay had low infrared emissivity, the calcined clay by carburization treatment had increased infrared emissivity. It is inferred that it was affected by carbon element that has high infrared absorptivity within this wavelength range.

Study on Anisotropy of Normally Consolidated Clay Soils (정규압밀점성토의 이방성에 관한 연구)

  • 권오순;정충기
    • Geotechnical Engineering
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    • v.11 no.1
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    • pp.41-50
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    • 1995
  • In situ clay soils with Ko condition have anisotropic characteristics, varying the response according to the principal stress direction upon loading. But because of their practicality and simplicity, consolidated isotropic undrained compression tests are commonly used in practice to determine the behavior of cohesive soils. In this study to investigate the anisotropic characteristics and the effects of consolidation stress states on the response of normally consolidated clay soils during shearing, triaxial compression and extension tests after consolidating the undisturbed clay soil samples, which are obtained as a block sample to normalized consolidation states under isotropic or Ko state, were carried out. As a result of tests, the anisotropy of the undrained strength was confirmed. Comparing the soil responses between isotropic and Ko consolidation, the undrained strength by isotropic consolidation is overestimated because of its higher mean consolidation pressure. And isotropic consolidation reduces the anisotropy of soil response and influences on the stress-strain behavior and pore pressure response because the animotropic soil structure is partially collapsed during isotropic consolidation process. Also, OCR in overconsolidated soils is decreased by isotropic consolidatiorL Friction angle in eztension is higher than that in compression, but regression analysis shows that friction angle with cohesion in extension is almost the same as that without cohesion in compresslon.

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Assessment of The Priority Order of Monitoring Devices on Maintenance for The Long-Term Safety of Existing Fill Dam (기존 필댐 장기간 안전관리를 위한 계측항목 유지보수 우선순위 산정)

  • Lee, Jongwook;Jeon, Jaesung;Lim, Heuidae
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.7
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    • pp.67-79
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    • 2009
  • Although readjustment of monitoring system for existing fill dam maintenance is needed by the sustainable increasing of the abandonment rate of monitoring devices by malfunction through the life-cycle of dam, monitoring plans for long-term dam safety has relied on the experience and the opinion of minor expert group without systematic and quantitative analysis on the failure modes and the priority order of monitoring devices on maintenance. In this study the priority order of monitoring devices of existing 5 fill dams was evaluated quantitatively based on the preceding study (Andersen et al, 1999) and the result recommended the establishment of real-time monitoring system for seepage, pore pressure and crest settlement as the readjustment plan for existing fill dam monitoring system. This readjustment plan matches well with the recommendation of PWRI (1984), JCOLD (1986) and the results from Bagherzadeh-Khakkahali and Mirghasemi (2005).

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Effects of subsequent curing on chloride resistance and microstructure of steam-cured mortar

  • Hu, Yuquan;Hu, Shaowei;Yang, Bokai;Wang, Siyao
    • Advances in concrete construction
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    • v.9 no.5
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    • pp.449-457
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    • 2020
  • The influence of subsequent curing on the performance of fly ash contained mortar under steam curing was studied. Mortar samples incorporated with different content (0%, 20%, 50% and 70%) of Class F fly ash under five typical subsequent curing conditions, including standard curing (ZS), water curing(ZW) under 25℃, oven-dry curing (ZD) under 60℃, frozen curing (ZF) under -10℃, and nature curing (ZN) exposed to outdoor environment were implemented. The unsteady chloride diffusion coefficient was measured by rapid chloride migration test (RCM) to analyze the influence of subsequent curing condition on the resistance to chloride penetration of fly ash contained mortar under steam curing. The compressive strength was measured to analyze the mechanical properties. Furthermore, the open porosity, mercury intrusion porosimetry (MIP), x-ray diffraction (XRD) and thermogravimetric analysis (TGA) were examined to investigate the pore characteristics and phase composition of mortar. The results indicate that the resistance to chloride ingress and compressive strength of steam-cured mortar decline with the increase of fly ash incorporated, regardless of the subsequent curing condition. Compared to ZS, ZD and ZF lead to poor resistance to chloride penetration, while ZW and ZN show better performance. Interestingly, under different fly ash contents, the declining order of compressive strength remains ZS>ZW>ZN>ZD>ZF. When the fly ash content is blow 50%, the open porosity grows with increase of fly ash, regardless of the curing conditions are diverse. However, if the replacement amount of fly ash exceeds a certain high proportion (70%), the value of open porosity tends to decrease. Moreover, the main phase composition of the mortar hydration products is similar under different curing conditions, but the declining order of the C-S-H gels and ettringite content is ZS>ZD>ZF. The addition of fly ash could increase the amount of harmless pores at early age.