• Journal of Korean Society on Water Environment
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• v.20 no.3
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• pp.241-244
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• 2004

Radiation treatment with gamma-rays and electron-beams was used to remove polyvinyl alcohol(PVA), one of the main components of dyeing wastewater. PVA was effectively decomposed by radiation treatment, thus the removal was near 100 % at an initial PVA concentration of 44 mg/L. However, total organic carbon(TOC) removal was less than 5 % due to lower transformation of PVA to $CO_2$. This directly indicates the radiation treatment alone is not appropriate for the complete decomposition of PVA. In this sense, the improvement of biodegradability($BOD_5/COD$) of PVA by radiation treatment was studied. Both gamma-ray and electron-beam treatments significantly increased the biodegradability of PVA by transforming non-biodegradable PVA to biodegradable by-products. This suggests radiation treatment, especially electron-beam treatment that showed better improvement of biodegradability, can be used as a pre-treatment of biological degradation process of PVA.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2013.05a
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• pp.387-388
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• 2013

• Journal of Environmental Science International
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• v.10 no.3
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• pp.233-237
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• 2001

Immobilized nitrifier bead in airlift bioreactor were used to remove high levels of ammonia nitrogen from synthetic wastewater. Polyvinylalcohol(PVA) bead for immmobilization of nitrifier consortium were prepared by PVA-boric acid method by varying concentration of PVA and nitrifier consortium. By determining viscosity, sphercity and tailing, the characteristics of prepared beads were investigated and the continous immobilization process was developed. Synthetic wastewater containg 25g/$\textrm{m}^3$ of ammonia nitrogen could be treated within 0.5 hour and the highest removal rate of ammonia nitrogen was 934.2g/$\textrm{m}^3{\cdot}$ day.

• Applied Chemistry for Engineering
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• v.16 no.3
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• pp.354-360
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• 2005

Polyvinyl alcohol (PVA) hydrogels were prepared by the irradiation and heating. Irradiation and heating processes were carried out to improve the heat resistance of PVA hydrogels at high temperature. The physical properties such as gel content, degree of swelling and gel strength for the synthesized hydrogels were examined. The structure variations were investigated using the following techniques: differential scanning calorimetry (DSC) and X-ray diffraction (XRD). Gel content and gel strength of the hydrogels were higher when the two steps of irradiation followed by heat treatment were used rather than only with the irradiation. The hydrogels prepared by the irradiation and the two steps had good heat resistance at high temperature.

• The Journal of the Acoustical Society of Korea
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• v.39 no.6
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• pp.576-584
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• 2020

In order to obtain basic information for using polyvinyl alcohol (PVA) gel as a tissue mimicking phantom for temperature visualization, the temperature change characteristics due to the focused ultrasound were examined for different concentration of PVA. To obtain the basic acoustic characteristics, the speed of sound, the attenuation coefficient, and the density depending on the PVA concentration were measured, and the thermodynamic characteristics, such as thermal conductivity and heat capacity, were measured. The range of temperature rising in the vicinity of the focal point due to the focused ultrasound was observed using a thermochromic film that changes color at 30 degree or more, and the discolored area was obtained by image processing of the recorded image. As the concentration of PVA increases in the given range of 2 wt% ~ 16 wt%, the area that rises above 30 degree inside the gel increases linearly. It is confirmed that the discolored area increases as the power applied to the focused ultrasonic transducer increases. These results showed good agreement with the simulation results using the finite element method.

• Journal of IKEEE
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• v.13 no.2
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• pp.216-219
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• 2009

$V_2O_5$ nanowire / polyvinyl alcohol (PVA) polymer composite fibers were fabricated by a new simple method. The reaction of PVA and acetone facilitates the formation of the polymer membrane which can be used to make the fiber. Composite fiber is percolative in the conductance because of the low percolation threshold in $V_2O_5$ nanowire networks. The fiber composite can be applied to the electromagnetic shielding originating from the conductive nature.

• The Korean Journal of Ceramics
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• v.5 no.3
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• pp.278-283
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• 1999

Formaldehyde has widely been used for the cross-linking of polyvinyl alcohol polyvinyl alcohol polymer. The effects of formaldehyde on the water resistance of MDF cement composites were investigated as a function of types of catalyst, base or acid, and the amount of formaldehyde. The acetalization, reaction of OH group of PVA with aldehyde, was ended incompletely under base atmosphere. However, by addition of citric acid, the cross-linking of PVA polymer could be acheved through acetalization of PVA and formaldehyde. The effects of these different patterne according to the types of catalyst on the water resistance of MDF cement were studied by the preparation of PVA films and MDF composites. Thanks to the cross-linking reaction of PVA polymer chains by formaldehyde, the modified PVA films and MDF composites showed a good water-resistant propety. The modified MDF cement composite to which 3 wt% formaldehyde and 1 wt% cirtic acid were added showed 80% of initial flexural strength and good interfacial state between cement grain and polymer matrix. However, 4 wt% formaldehyde deteriorted the processing conditions, microstructures and eventually the flexural strength, causing sharp increase in the viscosity of sample dough during the mixing process. To study the relatins of flexural strength and interface of cement grain and polymer matrix, SEM and MIP measurement were performed.

• Advances in Computational Design
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• v.8 no.2
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• pp.113-131
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• 2023

The use of fibers has been commonly considered in engineered cementitious composites, but their behavior with coarse aggregate in concrete has not been studied significantly, which is needed to meet structural performance objectives for design, such as ductility. This research analyzes the behavior of fiber-reinforced concrete with coarse aggregate with 0.62%, 1.23%, and 2% PVA (Polyvinyl-alcohol) content, varying the maximum aggregate size. Tensile (direct and indirect) and compressive concrete tests were performed. The PVA fiber addition in coarse aggregate concrete increased the ductility in compression, especially for the fiber with a larger aspect ratio, with a minor impact on strength. In addition, the tensile tests showed that the PVA fiber increased the tensile strength of concrete with coarse aggregate and, more significantly, improved the ductility. A selected mixture was used to build short and slender reinforced concrete beams to assess the behavior of structural members. PVA fiber addition in short beams changed the failure mode from shear to flexure, increasing the deflection capacity. On the other hand, the slender beam tests revealed negligible impact with the use of PVA.

• Journal of Soil and Groundwater Environment
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• v.24 no.6
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• pp.9-15
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• 2019

Soil dust emitted from large scale construction sites in urban areas has posed a significant health threats to local residents by exacerbating air quality. Water-spraying (moistening) is commonly practiced to lower the dust emission in construction sites, but its long term effectiveness is highly questionable. In this study, the utility of starch and PVA(polyvinyl alcohol) was investigated in suppression of the soil dust emissions in construction sites in Seoul areas. The efficiency of the two suppressants was tested with test soil sample in a lab-scale wind tunnel box under different concentrations of suppressants and soil textures. Starch and PVA showed the superior ability to suppress soil dust emission as compared to moistening, resulting in PM₁₀ and PM_2.5 lower than the daily limit values of 30 and 15 ㎍/㎥ respectively. PVA showed higher suppression capability than starch for all conditions. The test soils mixed with suppressants also showed dramatically enhanced aggregate stability compared to the non-treated soil.

• Journal of the Korea Concrete Institute
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• v.23 no.4
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• pp.461-469
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• 2011

In this study, the effect of polyvinyl alcohol (PVA) fiber volume fraction on the pullout behavior of structural synthetic fiber in hybrid structural synthetic fiber and PVA fiber cement composites are presented. Pullout behavior of the hybrid fiber cement composites and structural synthetic fiber were determined by dog-bone bond tests. Test results found that the addition of PVA fiber can effectively enhance the structural synthetic fiber cement based composites pullout behavior, especially in fiber interface toughness. Pullout test results of the structural synthetic fiber showed the interface toughness between structural synthetic fiber and PVA fiber reinforced cement composites increases with the volume fraction of PVA fiber. The microstructural observation confirms the incorporation of PVA fiber can effectively enhance the interface toughness mechanism of structural synthetic fiber and PVA fiber reinforced cement composites.