• Proceedings of the Korean Fiber Society Conference
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• 2003.10b
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• pp.275-276
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• 2003

Electrostatic spinning or electrospinning has been recently paid attention to prepare ultrafine fiber mats which are composed of diameters in a range of submicrons to nanoscale size[l]. Due to small diameters and porous structure, electrosun fibers have a high specific surface area and expected to use for broad applications, such as filters, membranes, wound dressing materials, artificial blood vessels. a nonwoven fabric, a reiforcement of nanocomposites[2,3], etc. (omitted)

• Journal of the Korean Applied Science and Technology
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• v.32 no.4
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• pp.607-615
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• 2015

To investigate the adhesion effect of various kinds and contents of polymeric methylene diphenyl diisocyanates (pMDIs) on adhesion performance, wood adhesives (A-1~5) were synthesized and characterized. As results, when the amount of pMDI increased in adhesives, the dry tensile strength was found to be proportionally increased sustaining at around $16.0{\sim}21.6kgf/cm^2$. The polyurethane (PU) resin, which used M11S as a source of pMDI showed the best wet tensile strength at $11.9kgf/cm^2$ and cyclic boil tensile strength at $8.1kgf/cm^2$, which satisfied the requirement of over $7kgf/cm^2$. Thermal properties of the rice powder (RP) based polyurethane resins were characterized by differential scanning calorimetry (DSC) and Thermal gravimetric analysis (TGA). Thermal stability of polyurethane resins increased to $250^{\circ}C$ with adding pMDIs. The more pMDI (M5S) was added to adhesive, the higher thermal stability of the resin was observed by TGA.

• Textile Coloration and Finishing
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• v.5 no.4
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• pp.60-66
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• 1993

Aqueous polyurethane(PU) anionomer dispersions were prepared from isophorone diisocyanate (IPDI), polytetramethylene adipate glycol(PTAd) and dimethylol propionic acid(DMPA) as potential anionic centers. The effects of polyol molecular weight(Mn) on the state of dispersion, thermal, mechanical, and viscoelastic properties and swelling of emulsion cast film were determined. With increasing Mn of PTAd, particle size of emulsion and soft segment T$_{g}$ decreased, and solvent swell, emulsion viscosity, and hard segment $T_{g}$ increased. Tensile strength showed minimum with PTAd 1000, and elongation at break generally increased with the Mn of PTAd. These results were possibly nterpreted in terms of soft segment-hard segment phase separation and crystallization of high molecular weight PTAd.

• Elastomers and Composites
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• v.49 no.3
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• pp.245-252
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• 2014

FT-IR measurement and the physical properties of polyurethane adhesive prepared from the polyol, isocyanate, 2-HEMA and other acrylate monomers were examined. The softening point, viscosity, adhesion strength and mechanical properties of the PU adhesives were reviewed by Ring and Ball method, Brookfield viscometer and universal test machine, respectively. Results revealed that increment of both PPG amount and butyl acrylate content decreased softening point, adhesion strength, tensile strength and 100% modulus. However as 2-HEMA and MDI content increased the mechanical properties including tensile strength, 100% modulus increased, and also the viscosity and NCO content increased.

• Journal of the Korean Applied Science and Technology
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• v.23 no.3
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• pp.264-271
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• 2006

PU type flame-retardant coatings (TBAO/L-75, TBAOL ; TBAO/N-100, TBAON) were prepared by blending bromine-containing modified polyester (TBAO) which was synthesized in our earlier work. with two kinds of isocyanate curing agents, Desmodur L-75 and Desmodur N-100. Physical properties of the prepared flame-retardant coatings were tested. TBAOL shows better hardness than TBAON, while TBAON shows better viscosity, accelerated weathering resistance, yellowness index and lightness index difference than TBAOL. There were no remarkable differences in fineness of grind, $60^{\circ}$ specular gloss, cross-hatch adhesion, and abrasion resistance of TBAOL and TBAON. There was no discernable difference in flame-retardancy between the two flame-retardant coatings, TBAOL and TBAON. When the content of tribromo acetic acid, which is flame-retarding component, was 30wt% the LOI value was in a range of $29{\sim}30%$, which indicates that the two coatings are good flame-retardant coatings.

• Journal of the Korean Applied Science and Technology
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• v.25 no.3
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• pp.332-340
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• 2008

Two component polyurethane (PU) flame retardant coatings were prepared by blending trichloro modified polyesters (TCMPs) and isophorone diisocyanate isocyanurate. TCMPs were synthesized by polycondensation of trichlorobenzoic acid (TCBA), a flame retardant component, with adipic acid, 1,4 butanediol, and trimethylolpropane. The content of TCBA was varied in 10, 20, and 30 wt% for the reaction. Theses new flame retardant coatings showed various properties comparable to other non flame retardant coatings. Moreover, we carried out the combustion test and the flammability test for our flame retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TCBA were determined as no burn. The results of flammability test for the coatings with 20 wt% and 30 wt% of TCBA contents indicated the limiting oxygen index (LOI) values of 26% and 29% respectively, which implied relatively good flame retardancy.

• Bulletin of the Korean Chemical Society
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• v.24 no.1
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• pp.37-44
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• 2003

We examined the effect of polyether-type nonionic surfactants (Brij 35, Triton X-100, Tween 20 and Tween 80) on the potentiometric properties of sodium-, potassium- and calcium-selective membranes which are prepared with widely used ionophores and four kinds of polymer matrices [poly(vinyl chloride) (PVC), polyurethane (PU), PVC/PU blend, and silicone rubber (SR)]. It was found that the PVC-based membranes, which provide the best performance among all other matrix-based membranes in the absence of nonionic surfactants, exhibited larger change in their potentiometric properties when nonionic surfactants are added to the sample solution. On the other hand, the sodium-selective SR-based membrane with calix[4]arene, potassium-selective PVC/PU- or SR-based membrane with valinomycin, and the calcium-selective SR-based membrane with ETH 1001 provide almost identical analytical performance in the presence and absence of Tween 20 or Tween 80 surfactants. The origin of nonionic surfactants effect was also investigated by interpreting the experimental results obtained with various matrices and ionophores. The results suggest that the nonionic surfactant extracted into the membrane phase unselectively form complexes with the primary and interfering ions, resulting in increased background potential and lower binding ability for the ionophore. Such effects should result in deteriorated detection limits, reduced response slopes and lower selectivity for the primary ions.

• Fashion & Textile Research Journal
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• v.5 no.3
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• pp.267-272
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• 2003

Tactel(Nylon66) union fabrics were woven with the specification of 70d/34f nylon as warp for sport wear jacket. Weft yarn has three types; 100% cotton yarn, nylon core-spun yarn and nylon-polyurethane covering yarn as weft. Fabric structers were plain, twill and satin weave structure with the air jet loom. The mechanical properties of 8 fabrics were measured with KES-F and primary Hand Values and Total Hand Values were calculated. The results of the study were as follows: 1) There was little difference among LTs of N/CM fabric groups. RT of the fabrics with CM100's was bigger than that of fabrics with CM80's, resulting that the fabrics with CM100's have better formability. In terms of weaving structure, twill fabrics have shape deformation. 2) In comparison of RTs with weft yarn type, RT of N-PU covering yarn was the highest, followed by Nylon core-spun yarn and cotton yarn. Thus, the fabric with N-PU covering yarn has better stability of shape deformation. 3) Stretch yarn could express an excellent silhouette formation and twill and satin structures were better structure to make curvature on human form. 4) 2HG/G value of nylon core-spun fabrics was larger than that of N/C fabrics, but the silhouette formation of N/C fabrics was excellent. 5) The RC of N/PU was the highest, followed by N/P, and N/CM. 6) Koski of N/PU fabrics was the highest, Numeri of N/PU and N/Co-I were relatively higher than the others. THVs of N/CM-IV and N/CO-II were lower than the others, resulting that, twill structure was better than plain structure for a sport wear uses.

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.466-469
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• 2002

Polyurethane(PU)은 segmented 블록공중합체로써 상온보다 높은 유리전이온도(glass transition temperature, Tg)를 갖는 hard segment(H.S)와 상온보다 낮은 Tg를 갖는 soft segment (S.S)로 구성되어 있다. 이들 두 segment간의 열역학적 불친화성으로 인해 미세 상분리 구조를 갖는다$^1$. 그 결과 hard segment-rich hard domain과 soft segment-rich soft matrix의 구조를 이룬다. 이중 hard domain(HD)은 상온에서 glassy한 성격을 띄므로 물리적 가교점과 충진제의 역할을 하며 soft domain(SD)은 rubbery한 성질을 가지므로 polurethane에 탄성을 부여하는 역할을 한다. (중략)

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2008.10a
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• pp.149-150
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• 2008

인체에 무해한 친환경 소재인 TPU수지를 인조합성피혁에 채용하여 기존에는 없던 통기성을 부여하였으며 PU 소재의 제품보다 내가수분해성이 뛰어나면서 기본물성이 우수한 고감성 인조합성 피혁 제품을 개발하였다.