• 제목/요약/키워드: polystyrene interface

검색결과 38건 처리시간 0.316초

Solution-Processed Quantum-Dots Light-Emitting Diodes with PVK/PANI:PSS/PEDOT:PSS Hole Transport Layers

  • Park, Young Ran;Shin, Koo;Hong, Young Joon
    • Proceedings of the Korean Vacuum Society Conference
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.146-146
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    • 2015
  • We report the enhanced performance of poly(N-vinylcarbozole) (PVK)/poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS)-based quantum-dot light-emitting diodes by inserting the polyaniline:poly (p-styrenesulfonic acid) (PANI:PSS) interlayer. The QD-LED with PANI:PSS interlayer exhibited a higher luminance and luminous current efficiency than that without PANI:PSS. Ultraviolet photoelectron spectroscopy results exhibited different electronic energy alignments of QD-LEDs with/without the PANI:PSS interlayer. By inserting the PANI:PSS interlayer, the hole-injection barrier at the QD layer/PVK interface was reduced from 1.45 to 1.23 eV via the energy level down-shift of the PVK layer. The reduced barrier height alleviated the interface carrier charging responsible for the deterioration of the current and luminance efficiency. This suggests that the insertion of PANI:PSS interlayer in QD-LEDs contributed to (i) increase the p-type conductivity and (ii) reduce the hole barrier height of QDs/PVK, which are critical factors leading to improve the efficiency of QD-LEDs.

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Activated Physical Properties at Air-Polymer Interface

  • Kajiyama, Tisato;Tanaka, Keiji
    • Proceedings of the Polymer Society of Korea Conference
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.5-6
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    • 2006
  • Molecular motion at the surface of monodisperse polystyrene (PS) films with various chain end groups was studied by scanning probe microscopy. Surface glass transition temperature ($T_{g^s}$) of the PS films was much lower than the corresponding bulk value. And, the magnitude of $T_{g^s}$ was strongly dependent on chain end chemistry. This result can be explained in terms of the chain end concentration at the surface. Time-temperature superposition principle was applied to rheological analysis at the surface. The apparent activation energy of the surface ${\alpha}_{a}$-relaxation process was approximately a half of that for the bulk sample. This result clearly indicates that the cooperativity for the surface segmental motion was reduced in comparison with that in the bulk region.

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Migration of Nanoclay in Immiscible Polymer Blends

  • Kim, Yong-Kyoung;Ahn, Kyung-Hyun;Lee, Seung-Jong;Hong, Joung-Sook
    • Proceedings of the Polymer Society of Korea Conference
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.366-366
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    • 2006
  • Five sandwiched multilayers consisting of PBT(Polybutyleneterephthalate), PS(Polystyrene) and clay were prepared to investigate the migration mechanism of clay in the polymer blend system. Rheometry (RMS800) was used to apply well-defined shear on the above multilayer samples in order to well understand dominant factors controlling the migration. Applied shear force was enough to move clay tactoids to the interface, if either long time or high shear was available, but it was not sufficient to separate into individual platelets of clay. The morphology evolution was subsequently studied in term of scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HR-TEM), respectively.

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Soft-Lithographic Fabrication of Ni Nanodots Using Self-Assembled Surface Micelles

  • Seo, Young-Soo;Lee, Jung-Soo;Lee, Kyung-Il;Kim, Tae-Wan
    • Journal of Magnetics
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    • 제13권2호
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    • pp.53-56
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    • 2008
  • This study proposes a simple nano-patterning process for the fabrication of magnetic nanodot arrays on a large area substrate. Ni nanodots were fabricated on a large area (4 inches in diameter) Si substrate using the soft lithographic technique using self-assembled surface micelles of Polystyrene-block-Poly(methyl methacrylate) (PS-b-PMMA) diblock copolymer formed at the air/water interface as a mask. The hexagonal array of micelles was successfully transferred to a Ni thin film on a Si substrate using the Langmuir-Blodgett technique. After ion-mill dry etching, a magnetic Ni nanodot array with a regular hexagon array structure was obtained. The Ni nanodot array showed in-plane easy axis magnetization and typical soft magnetic properties.

Effects of the Deposition Rate of Pentacene Film on the Electrical Characteristics of Organic Thin-film Transistors

  • Park, Jae-Hoon;Lee, Yong-Soo;Kang, Chang-Heon;Kim, Yeon-Ju;Choi, Jong-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.649-652
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    • 2003
  • Organic thin-film transistors were fabricated using pentacene as an active electronic material. Device characteristics are improved with increasing the deposition rate of pentacene. It is observed that the deposition rate influences on the interface properties between pentacene and polystyrene, and the molecular ordering of pentacene film. In this paper, we report the effects of the deposition rate of pentacene film on the device performance.

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중성자 산란을 이용한 생체물질의 구조 연구 : 단백질의 생체유사막의 흡착

  • Sin, Gwan-U;Rafailovich, M.H.;Sokolov, J.;Pernodet, N.;Satija, S.K.
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2002년도 생물공학의 동향 (X)
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    • pp.30-33
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    • 2002
  • We have shown that it is possible to form a fibrilar network of fibronectin on a polyelectrolyte polymer film whose dimensions are similar to those reported on the extra cellular matrix. The fibronectin network was observed to form only when the charge density of the polymer was in excess of the natural charge density of the cell wall. Furthermore, the self-organized fibronectin layer was much thicker than the polymer film, indicating that long ranged interaction may playa key role in the assembly process. It is therefore important to understand the structure of the polymer layer/protein interface. Here we report on a neutron reflectivity study where we explore the structure of the polyelectrolyte layer, in this case sulfonated polystyrene (PSSx,), with varying degree of sulfonation (x<30%), as a function of sulfur content and counter ion concentration. These results are then correlated with systemic study of the adsorption and the multilayer formation of fibronectin as a function of incubation time for various sulfonation levels of $PSSx.^1$

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Measurement of Brownian motion of nanoparticles in suspension using a network-based PTV technique

  • Banerjee A.;Choi C. K.;Kihm K. D.;Takagi T.
    • 한국가시화정보학회:학술대회논문집
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    • 한국가시화정보학회 2004년도 Proceedings of 2004 Korea-Japan Joint Seminar on Particle Image Velocimetry
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    • pp.91-110
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    • 2004
  • A comprehensive three-dimensional nano-particle tracking technique in micro- and nano-scale spatial resolution using the Total Internal Reflection Fluorescence Microscope (TIRFM) is discussed. Evanescent waves from the total internal reflection of a 488nm argon-ion laser are used to measure the hindered Brownian diffusion within few hundred nanometers of a glass-water interface. 200-nm fluorescence-coated polystyrene spheres are used as tracers to achieve three-dimensional tracking within the near-wall penetration depth. A novel ratiometric imaging technique coupled with a neural network model is used to tag and track the tracer particles. This technique allows for the determination of the relative depth wise locations of the particles. This analysis, to our knowledge is the first such three-dimensional ratiometric nano-particle tracking velocimetry technique to be applied for measuring Brownian diffusion close to the wall.

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Manufacturing Micrometer Scale Structures by an Optical Tweezers System Controlled by CyberGlove (가상장갑으로 제어되는 광핀셋 시스템을 이용한 마이크로 구조물의 제작)

  • Park, I.Y.;Lee, J.H.;Lee, Y.G.
    • Korean Journal of Computational Design and Engineering
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    • 제12권4호
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    • pp.298-307
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    • 2007
  • In recent years, researchers are actively investigating new methods that are applicable for manufacturing micrometer to nanometer scale structures. Among them, optical tweezers that can manipulate microscopic objects using a laser is receiving one of the key attentions. Optical tweezers have been used actively in the field of science. For example, for measuring mechanical characteristics in the scale of piconewtons or for manipulating and sorting large numbers of particles, bacteria, cells. etc. However, little works have been reported for "manufacturing" objects. In this paper, we present a new method for manufacturing micrometer scale structures using micrometer scale biotin coated polystyrene particles. Particles will be controlled with a user interface that utilizes a CyberGlove and glued together by the bonding force between biotin and streptavidin.

Development of Highly Stable Organic Nonvolatile Memory

  • Baeg, Kang-Jun;Kim, Dong-Yu;You, In-Kyu;Noh, Yong-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.904-906
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    • 2009
  • Organic field-effect transistor (OFET) memory is an emerging device for its potential to realize light-weight, low cost flexible charge storage media. Here we report on a solution-processed poly[9,9-dioctylfluorenyl-2,7-diyl]-co-(bithiophene)] (F8T2) nano floating-gate memory (NFGM) with top-gate/bottom-contact device configuration. A reversible shift in the threshold voltage ($V_{Th}$) and the reliable memory characteristics were achieved by incorporation of thin Au nanoparticles (NPs) as charge storage sites for negative electrons at the interface between polystyrene and cross-linked poly(4-vinylphenol).

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Construction of a Dynamic Laser Light Scattering System Using a Personal Computer$^\dag$

  • Kim, Myung-Joong;Lee, Sang-Yong;Chung, Koo-Soon;Lee, Hoo-Sung
    • Bulletin of the Korean Chemical Society
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    • 제8권5호
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    • pp.403-405
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    • 1987
  • A dynamic laser light scattering system has been constructed using a personal computer. The intensity of the scattered light was detected with a photomultiplier tube and a photon counter. The BCD output of the photon counter which is proportional to the intensity of scattered light is fed into a personal computer via an interface card. The personal computer was programmed as an autocorrelator in machine language. The data acquisition rate of the system was about 600 samples/s which is adequate for studies on the molecular dynamics of concentrated polymer solutions, polymer latices with large particle size, and polymer glass systems. The constructed system was tested with polystyrene latex and the measured diameter of the latex particle agrees well with the supplier's value.